Tn t· p.a,p r We hae reported it;vestigations O:U the· effeot of
simtHtaneous s·ubs'tituti9n of :Pb . a;t tbe,1'1-based .IJPercqndl,lctor was·
prepar.d by adcling; an .amoun· 0f Pb t. the TIJ-PbxBa;iCa2CuaOo'ti cor:npound. The: usu;d solid'7state teactin meJ;}Jo.d haS be:eu. applied t:mdr optimum co_nditjon..· auJk po.lycrys.talline sari;lples. hf!ve -been
p.reparQ by the tWo step .soli_d tate re.ctip:n proeess; It has bee 1
- ohsewedthat the gj'own Il1-xPh.x.BaiGa2Cu30:6(with x = <.tbo,· O.'l 0 •
0_:49 'Q.$Q. atld . Q.40) CO(Ie$pQnds to the t 2J phase. Thl X"' ay da:ta ·of:
the Sa.mple showe4 tetragonal >Stmciture ith high ratio .afTI.-1223
SQpeFCO!lductiti,g ph e. r·e §aptpls .show.ed a transitjort tertljn.etatutes
Ti?<\\'IIJSCI)W ic.h were ti6 .K.. 12'3 K,_ 1"29. J<_, 131 ' L34 K at {x = 0.,0,.
O.JO, .0.20. .0, 30' <tn · .4-0.) tespectivdy, and the ttansiti:on:
temperatures at zero resistance Tc(otn were lOl , HIS,. H)112 a,n-d
ns K_, r.es_p.cl,'.tiv ly;. R.esistivitie's. were m asure4 at cliffetr¢.nt
. tempeta:tures unde11 zero magn tic .fields and 'the data w t hl erp:tetea.
Alrthe S41TIPleS pr.eparation wi;;o2 f19w' we fCtun-d Jhat the 0:;! fl9W in
our:sanipi.e.S prgdQcd high-: Pha;se s.uperco"nducto.r .
X-Tay di:ftract1oh aQaly$is, showed an ·incr.ease .of :the c-'axis. lat!iioe
eorutlli)t fQr tile :san1p.hS' doped with ph as c.ompared with. fu s<Z have
:no t;Jb contentIt was found · that be chan.g. of the pb concentrations
of all our s:amp'le.s . Produeed · a ¢hangNil the density Pilh ·Cfa a;nd
volume 'fractiPJi V t'il(1 22-3>.