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jih-1381
Equilibrium, Kinetic and Mechanistic Studies of Formation of Cis- mono (AA)bis (oxaJato) Chromate (III) C,omplex (where AA is · glycine, alanine and histidine)In Monderately Aqueous Acidic Solution
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Equilrium, kinetic  and mechanistic studies  for  thcoordination of

 

;

 

some amino acids  "'AA'1

 

glycine,  alanine, .a:ncl  histidine, to  Cr  (Ill)

 

center  of trans .[Cr(ox}2(B.2 0hr   {TJ'} cornplein monderarely  acidic

range ofpH=4.8-6-.7 ( p =Q.4M NaN03) are  reported.  The equili rium

c.onsta:nts   at  25°C   .were  found   logKequ.=4.95J ,5.206and5.128for glycine, alap.ine, md histidine, ligation. reactions  respectively..  The substitution reaction is kinetically  involve  rwo parallel  complex reactions, each  inch,tdes there  difierent e_onsecutive steps of different

·

 

species of Ct(III).  The  reactant,  Ti, branches  through  byrolysis  into, doubly  charged anion, conjugated    se of  trans[Cr(ox)22(H0)0Hr2

whlch  inleracts  with  (AAH)   to  from  outer-sphere  complex,   that  is followed  by interchange reaction  of one molecule H20 with one end of    AA-        ron   from                   an         active        intermediate         species   of              trans­ [Cr(Qx)2(AA)OHT3           which               cbanges       to        final           product ;                c.is­ [Cr(ox}1(AA)J?. While  the  remai ning  part  of reactant   interacts also

with zwitter i:on (AAH)  on  other  side  to form  another  outer-sphere

.complex  which  also  undergaes interchange  reaction of one  molecule

 

H10 wHh AA- ion to ive two· active  intennediates species, trans and cis-[Cr(ox)2(AA)H2 or, whlch later convert tp the same prod·uct .; cis­

fCr(ox)z(AA)]2-.      TI1e      interchange      rate      co.nstant    of     trans­ [Cr(ox)2(AA)OH]                                             formation  relatively   appears  much  larger  than (A H*=8.8kc 1/n1ol)         that                                 of    ds[Cr(.oxh  AA)H:z Ot                     formation

( l\ H*·=14.0Kca l/mol), wbile  the latter rate constant'is oeaily  (5-10)

time l(!I'ger than that oftrans-{Cr(ox)2(AA)H20t fennatlon

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Publication Date
Thu Dec 16 2021
Journal Name
Kufa Medical Journal
Clinical and Refractive Outcomes of Toric Phakic Implantable Collamer Lens Implantation for correction of myopic astigmatism
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Background: Currently there are four general approaches to correct refractive errors: refractive corneal surgery, crystalline lens surgery and implantation of an intraocular lens in anterior or posterior chamber. Aim: To evaluate the predictability, safety and stability of toric phakic implantable collamer lens implantation to correct moderate to high myopic astigmatism. Methods: Sixty eyes of 40 patients underwent implantation of a toric implantable collamer lens (V4c design) in the Eye Specialty Private Hospital, Baghdad, Iraq were studied. The mean spherical refraction was -11.32±3.17 diopter (D) with a range of -6.00 to -18.00 D and a mean cylinder of -2.61±1.16 with range of -1.00 to -5.50 D. The outcome measures that evaluat

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Publication Date
Thu Jan 04 2018
Journal Name
International Journal Of Science And Research (ijsr)
Effect of Doping on Properties of the Hall Effect and Electrical Conductivity for AgInTe2 Thin Films
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The effect of different doping ratio (0.3, 0.5, and 0.7) with thickness in the range 300nmand annealed at different temp.(Ta=RT, 473, 573, 673) K on the electrical conductivity and hall effect measurements of AgInTe2thin film have and been investigated AgAlxIn(1-x) Te2 (AAIT) at RT, using thermal evaporation technique all the films were prepared on glass substrates from the alloy of the compound. Electrical conductivity (σ), the activation energies (Ea1, Ea2), Hall mobility and the carrier concentration are investigated as a function of doping. All films consist of two types of transport mechanisms for free carriers. The activation energy (Ea) decreased whereas electrical conductivity increases with increased doping. Results of Hall Effect

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Publication Date
Sat Dec 01 2018
Journal Name
Journal Of Pharmaceutical Sciences And Research
Pryparation, characterization and biological activity of new derivatives of 2-biphenyl-3-aminomethylimidazo(1,2-a)pyrimidine
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New Fourteen compounds were synthesized in four steps. The first step included synthesis of 2-biphenyl fused ring of imidazo(1,2- a)pyrimidine from the reaction of 2-aminopyrimidine and biphenyl phenacyl bromide . The second step was introduced aldehyde group from the reaction of 2-biphenyl fused rings of imidazo(1,2-a)pyrimidine with POCl3 in presence of DMF and CHCl3. 3-Carbaladehyde derivatives of fused imidazo/pyrimidine was reacted with different aromatic amines to afford new Schiff bases. These new 3- imines derivatives was reduced by using sodiumborohydride to yield another new 3-aminomethyl-2-biphenyl imidazo (1,2-a)pyrimidine derivatives in moderate yield .Some new prepared compounds were identified by melting point, FT- IR , 13C-

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Publication Date
Fri Jan 01 2021
Journal Name
Biochem. Cell. Arch.
SYNTHESIS AND CHARACTERIZATION OF SOME NEW METALS COMPLEXES OF 2-(3-ACETYLTHIOUREIDO)-3-PHENYLPROPANOIC ACID (APA)
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ABSTRACT : A new ligand [ 2- (3-acetylthioureido)-3-phenylpropanoic acid (APA) is synthesized by reaction of acetyl isothiocyanate with phenylalanine (1:1). It is characterized by micro elemental analysis (C.H.N.S.), FT-IR, (UV-Vis) and 1H and 13CNMR spectra. Some metals ions complexes of this ligand were prepared and characterized by FT-IR, UV-Visible spectra, conductivity measurements, magnetic susceptibility and atomic absorption. From results obtained, the following formula [M(APA)2] where M2+ = Mn, Co, Ni, Cu, Zn, Cd and Hg, the proposed molecular structure for these complexes as tetrahedral geometry, except copper complex is has square planer geometry.

Publication Date
Wed Feb 05 2025
Journal Name
Iraqi Journal Of Science
Effect of Diode Laser (805) nm on alpha-toxin production and antibiotic sensitivity of Staphylococcus aureus
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Publication Date
Fri Jan 01 2021
Journal Name
International Journal Of Agricultural And Statistical Sci.
Evaluating the performance of introduced varieties of Maize (Zea mays L.) And estimating some genetic parameters
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Publication Date
Wed Jan 01 2020
Journal Name
Plant Archives
Response of some vegetative growth characteristics of organically fertilized potatoes to zinc and manganese foliar application
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Scopus (3)
Scopus
Publication Date
Sat Jul 08 2017
Journal Name
Research Journal Of Pharmaceutical , Biological And Chemical Sciences
Assessment activity and Partial purification of Alkaline phosphatase (AIP) from sera of patients with celiac disease
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Publication Date
Mon Jul 01 2019
Journal Name
Plant Archives
Effect of melatonin administration with different light colors on fertility traits and hatching of local chickens
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This study was conducted at the poultry farm of the Department of Animal Production/College of Agriculture/University of Baghdad/Abu Ghraib, on 252 birds (180 females and 72 males). This study aims to observe the effect of melatonin implantation and exposure to different light colors and their interaction on characteristics of fertility and hatching of local Iraqi chickens. The birds were divided into three sections (white, red and green) each section contains two lines, one of which has been planted melatonin under the skin of the neck of birds and the other has not been planted hormones. The results showed that melatonin implantation and exposure to different light colors did not significantly affect the hatching rate of fertilized eggs a

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Scopus (3)
Scopus
Publication Date
Fri Jan 01 2021
Journal Name
Systematic Reviews In Pharmacy
A COMPARATIVE STUDY OF CHEMICAL COMPOUNDS AND ANTI-BACTERIAL EFFICACY OF DIFFERENT ALLIUM CEPA PLANT EXTRACTS
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