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jih-1381
Equilibrium, Kinetic and Mechanistic Studies of Formation of Cis- mono (AA)bis (oxaJato) Chromate (III) C,omplex (where AA is · glycine, alanine and histidine)In Monderately Aqueous Acidic Solution
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Equilrium, kinetic  and mechanistic studies  for  thcoordination of

 

;

 

some amino acids  "'AA'1

 

glycine,  alanine, .a:ncl  histidine, to  Cr  (Ill)

 

center  of trans .[Cr(ox}2(B.2 0hr   {TJ'} cornplein monderarely  acidic

range ofpH=4.8-6-.7 ( p =Q.4M NaN03) are  reported.  The equili rium

c.onsta:nts   at  25°C   .were  found   logKequ.=4.95J ,5.206and5.128for glycine, alap.ine, md histidine, ligation. reactions  respectively..  The substitution reaction is kinetically  involve  rwo parallel  complex reactions, each  inch,tdes there  difierent e_onsecutive steps of different

·

 

species of Ct(III).  The  reactant,  Ti, branches  through  byrolysis  into, doubly  charged anion, conjugated    se of  trans[Cr(ox)22(H0)0Hr2

whlch  inleracts  with  (AAH)   to  from  outer-sphere  complex,   that  is followed  by interchange reaction  of one molecule H20 with one end of    AA-        ron   from                   an         active        intermediate         species   of              trans­ [Cr(Qx)2(AA)OHT3           which               cbanges       to        final           product ;                c.is­ [Cr(ox}1(AA)J?. While  the  remai ning  part  of reactant   interacts also

with zwitter i:on (AAH)  on  other  side  to form  another  outer-sphere

.complex  which  also  undergaes interchange  reaction of one  molecule

 

H10 wHh AA- ion to ive two· active  intennediates species, trans and cis-[Cr(ox)2(AA)H2 or, whlch later convert tp the same prod·uct .; cis­

fCr(ox)z(AA)]2-.      TI1e      interchange      rate      co.nstant    of     trans­ [Cr(ox)2(AA)OH]                                             formation  relatively   appears  much  larger  than (A H*=8.8kc 1/n1ol)         that                                 of    ds[Cr(.oxh  AA)H:z Ot                     formation

( l\ H*·=14.0Kca l/mol), wbile  the latter rate constant'is oeaily  (5-10)

time l(!I'ger than that oftrans-{Cr(ox)2(AA)H20t fennatlon

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Publication Date
Sat Jan 01 2022
Journal Name
Journal Of Pharmaceutical Negative Results
Morphological and Anatomical Review of Some Veronica Species from the Plantaginaceae Family
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Publication Date
Tue Jul 18 2017
Journal Name
Inorganica Chimica Acta
Synthesis, characterization and liquid crystalline properties of novel benzimidazol-8-hydroxyquinoline complexes
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The synthesis, characterization and liquid crystalline properties of N4,N40-bis((1 H-benzo[d]imidazol-2- yl)methyl)-3,30-dimethyl-[1,10-biphenyl]-4,40-diamine and of their corresponding Mn(II), Fe(II), Ni (II), Cu(II), and Zn(II) complexes are described. The ligand and complexes have been characterized by elemental analysis, magnetic susceptibility measurements (meff), conductometric measurements and Fourier Transform Infrared (FTIR), Nuclear Magnetic Resonance (1H NMR), (13C-NMR) and UV–Vis spectroscopy. Spectral investigations suggested octahedral coordination geometrical arrangement for M(II) complexes. The phase transition temperatures were detected by differential scanning calorimetry (DSC) analysis and the phases are confirmed by op

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Publication Date
Tue Jan 01 2019
Journal Name
Biochemical And Cellular Archives
Phenotypic and molecular detection of Escherichia coli efflux pumps from UTI patients
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Publication Date
Mon Apr 17 2017
Journal Name
Ibn Al-haitham Journal For Pure And Applied Sciences
Isolation and Identification of the (Myxococcus xanthus) Myxobacterium from the Grave Soil
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  The study was performed to isolate and identify the Myxococcus
 
xanthus from (50) samples of  grave  soils .Special growth conditions had been used to support the growth of  M.
   xanthus and to suppressed the growth of other microorganisms like (Drying , High concentration of antibiotics and specific growth media)
 M. . xanthus  isolates had been subjected to the morphological, cultural and biochemical examinations for identification .  Results obtaind could be summarized as follows : 1. Myxobacteria were found as normal flora  inhabitants of the arid soils. 2. Ten local  isplates  of   M.  xanthus out of (50) soil samples were  isolated

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Publication Date
Thu Dec 29 2016
Journal Name
Ibn Al-haitham Journal For Pure And Applied Sciences
Study of the Dielectric Properties Ceramics Specimens Prepared from Alumina and MgO
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A study carried out on ceramic material made at (a-Al2O3) doped with MgO (0.5 , 0.3 , 0.2,0.1)%,with particle size at 63mm.
A Hydraulic press of 5kn at diameter of 2cm.A nnalelling at 1500Co and 6 hrs still to see the effect on the changes of the dielectric material. With frequency range at (1K – 1M) Hz. And the result show that at percentage of 0.5% of MgO, the real dielectric material decreased with the increased frequency

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Publication Date
Tue Jan 01 2019
Journal Name
Journal Of Global Pharma Technology
Synthesis and characterization of chitosan schiff base hydrogel for controlled drug release
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Chitosan-schiff base with three different ratios of para-Dimethyl aminobenzaldehyde& chitosan Schiff base hydrogels have been prepared for controlled drug release study. The synthesized chitosan Schiff base and chitosan Schiff base hydrogel were characterized by FT-IR, UV-Visible, SEM, analysis. Swelling properties of the hydrogel were investigated at three different media pH (2, 7, 10). The swelling degree varied with the pH, amount of crosslinking agent glutaraldehyde and with the amount of paraDimethylaminobenzaldehyde for the hydrogels. All hydrogels were used for controlled drug release system. Aspirin was used as model drug, in three different buffer solution (2, 7, 10) as release media. The rate of release of drugs in the pH2 is m

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Publication Date
Thu Apr 28 2022
Journal Name
Iraqi Journal Of Science
Determination of the shape for (54Xe and 82pb) nuclei from deformation parameters ( , )
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The shape for even-even (54Xe 118≤ A ≤ 140 and 82Pb 204 ≤ A ≤ 210 ) nuclei have been studied and investigated through the deformation parameters and δ , these deformation parameters were calculated by two different methods. The first one is nucleus quadrupole deformation parameter β2 from reduced transition probability B(E2)↑ for 0+→2+1 transitions and the second is nucleus quadrupole deformation parameters δ from quadrupole moment Qo.The relationship between two deformation parameters ( , ) and neutrons magic number (N=82 & 126) was studied through plotting the deformation parameters ( , ) as a function of neutrons number , from this relationship we can see very cleary that the deformation of nucleus decreased when th

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Publication Date
Wed Mar 23 2022
Journal Name
Journal Of Educational And Psychological Researches
Self-control and its relation to the work pressure of educational counselors
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1- The degree of self-control of the educational counselors.

2- The level of work pressures that educational counselors are exposed to from their point of view.

3- The significance of the differences in the degree of self-control and work pressures according to the gender variable (male / female).

4- The relationship between self-control and work stress for the sample as a whole.

The current research was limited to educational counselors of both sexes in Anbar Governorate, Ramadi District, affiliated to the Anbar Education Directorate. The researcher adopted the steps of the relational descriptive approach to achieve the research objectives. The current research community consists of (100) m

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Publication Date
Fri Dec 01 2023
Journal Name
Al-khwarizmi Engineering Journal
Preparation, Characterization, and Tetracycline Adsorption Efficiency of Tea Residue-Derived Activated Carbon
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The process for preparing activated carbon (AC) made from tea residue was described in this paper. Investigated were the physicochemical characteristics and adsorption efficiency of the produced AC. Activation with potassium hydroxide (KOH) and carbonization at 350 °C are the two key steps in the manufacturing of AC. The activated carbon was used to adsorb Tetracycline (TC). Different parameters were studied at room temperature to show their effects on the adsorption efficiency of TC. These parameters are the initial concentration of adsorbate TC, solution acidity pH, time of adsorption, and adsorbent dosage. The prepared active carbon was characterized using Fourier transform infrared spectroscopy (FTIR), scanning electron microsc

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Publication Date
Mon Jul 01 2019
Journal Name
Journal Of Craniofacial Surgery
The Impact of Blast Implosions and Bullet Injury on Maxillary Air Sinus
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Background:

Successive waves and generations of terrorists attacked the Iraqis in the years following the fall of the regime in Iraq in 2003, after the US invasion of the country under the pretext of weapons of mass destruction. Hence, the Iraqi people enrolled in ongoing war with these armed groups which led to massive casualties due to blasts and missile injuries.

Mechanism of blasts injury can be classified into primary, secondary, tertiary, and quaternary. While bullet injuries can be classified into low and high-energy injuries, the type and severity of the injury will influence the type of management, together with facilities available in

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