In the present study, we have reported investigations on the effect of simultaneous substitution of Tl at the Hg site in the oxygen deficient HgOδ layer of Hg1-xTlxBa2Ca2Cu3O8+ δ cuprate superconductor. Bulk polycrystalline samples were prepared by the two-step solid state reaction process. It was observed that the grown Hg1-xTlxBa2Ca2Cu3O8+ δ corresponds to the 1223 phase. Electrical resistivity, using four probe technique, is used to find the transition temperature Tc. The highest Tc(0ffset) were 108, 102,113, 118, 125 and 121K for Hg1xTlxBa2Ca2Cu3O8+ δ with x = 0.0, 0.05, 0.10, 0.15, 0.20 and 0.25 respectively. The optimum Tc(off) of ~ 125 K and Tc(onset) ~ 136K was found for the composition Hg0.80Tl0.20Ba2Ca2Cu3O8.293. All the samples preparation with O2 flow, we found that the O2 flow in our samples produce high- Phase superconductors. X-ray diffraction(XRD) analysis showed a pseudotetragonal structure with an increase of the c-axis lattice constant for the samples doped with Tl as compared with these have no Tl content. It was found that the change of the Tl concentrations of all our samples produces a change in the Mass density Ïm, c/a and volume fraction VPh(1223).
Influence of Simultaneous Doping of Tl on the Transition Temperature Tc and the Lattice Parameters of HgBa2Ca2Cu3O8+ δ Superconductors
Publication Date
Thu Jul 20 2023
Journal Name
Ibn Al-haitham Journal For Pure And Applied Sciences
Synthesis, Characterization and Biological Activity Study for Some New Metals Complexes with (3Z,3'E)-3,3'-(((2E,5E)-hexane-2,5-diylidene)bis(hydrazine-2,1-diylidene))bis(indolin-2-one)
antibiotic
FTIR
1H-NMR
Mass
Schiff-species
Hexadion
Isatin-3-hydrazone
Schiff_bases complexes
biological activity
Our recent work displays the successful preparation of Schiff_bases that carried out between hexane-2,5-dione and 2 moles of (Z)-3-hydrazineylideneindolin-2-one forming in Schiff-bases-(L), Which in turn allowed combining with each of the next metal ions: (M2+) = Ni, Mn, Zn, Cu and Co forming complexes_ in high stability. The formation of resulting Schiff_ bases (L) is detected spectrally using LC_Mss which gave approximately matching results with theoretical incomes, 1HNMR proves the founding of doublet signal of (2H) for 2NH, FTIR indicates the occurrence of two interfered imine bands and UV-VIS mean is also indecates the formation of ligand. On the other hand, complexes-based-Schiff were characterized using the s
... Show More
(1)
Publication Date
Mon Jan 01 2024
Journal Name
Computers, Materials & Continua
