The issue of dignity is one of the topics that do not pass as long as the earths and the heavens remain; Because the earth is not devoid of the righteous, the believers, the saints, and the pious, and these do not cease from them aid, dignity, insight, or good vision, and from here the authorship in this section was continuous; Because the people’s need for it is confirmed as time progresses, and in that, Ibn Taymiyyah says in the sum of his fatwas, “And from what it should be known is that dignities may be according to the man’s need, so if the weak needs them Faith or the needy, he is given from it what strengthens his faith and fulfills his needs, and he who is more complete is the guardianship of God than him. He is independent of that, and the like of that does not come to him because of his high rank and his indispensability of it, not because of the lack of his mandate; and for this reason it was These matters are more among the Taabi’een than they are among the Companions, in contrast to the one who performs the supernatural at his hands due to the guidance of creation and their need. These are the greatest in degree.”
The need for it and its frequent incidence led to a large number of authors in it, so Muhammad bin Ziyad, known as Ibn Al-Arabi (d. 231 AH) wrote “Karamat Al-Awliyaa”, and Ibn Abi Al-Dunya (d. 281 AH) wrote his book: “The Guardians”, and Al-Hafiz Abu Ahmad Al-Ghassal Qadi Isbahan (d. 349 AH) wrote a book called: “Karamat al-Awliya’” and Ibn Abi Zayd al-Qayrawani (386 AH) who called it “Ithbat Karamat al-Awliya’” and Ibn Futais (d. Al-Khalal al-Baghdadi (d. 439 AH) called it: “Karamat al-Awliya’” while al-Saqli al-Maliki (d. 380 AH) called it: “Karamat of the saints and obedient companions and followers.” Ibn Shaq al-Layl (d. 445 AH) called his book: “The Nobles and Proofs of the Righteous And Abu al-Ma’ali al-Baghdadi called his work: “Karamat al-Awliya’.” Ibn Sayyid al-Nas (d. 734 AH) wrote a book called: “The Sublime Maqamat fi al-Karamat al-Jaliya.” And Muhammad bin Ahmad al-Barulsi al-Ansari (d. after 1096 AH) wrote a work on that with the title: “ The clear verses confirm the dignity of the saints in life and after death.” Al-Shehab Ahmed bin Al-Hassan Al-Karimi Al-Gawhari Al-Shafi’i Al-Azhari (d. D. 1305 AH) A Treatise on the Honorable Mentions of the Saints, and Sheikh Yusuf Al-Nabhani (d. 1350 AH) authored “Al-Jami’ L’honoring Honorable Mentions.”
The large number of writings on these miracles and the uninterrupted nature of miracles was the great motive for researching them, and finding out the doctrines of scholars regarding them.
In this research, I dealt with the study of dignity and its provisions in the Islamic faith, and it included three topics. The first topic dealt with its definition and conditions. Its occurrence and the ruling of its denial, and there were two demands - also - the first was in the difference of schools in its occurrence, and the evidence of each team and the most correct of them, while the second came in the ruling of those who denied it. and deepened the research in it, and explored its depths; Because it is one of the issues that appear in most of the works with brief references, and I showed the most correct of the scholars’ sayings about it, then I added all of that with a conclusion in which I showed the most important results that I reached in this research.
In all of this, I have referred to the original sources in books of beliefs, biographies, and so on, and I do not claim perfection in that. Whatever was correct is by the grace of God Almighty, and whatever was of defect or error was from myself, my shortcomings, and my incapacity.
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الوصف A simple chemistry method approach was used to synthesise new ligand derivate from L-ascorbic acid and its complexes. All of them were water-soluble and are used quite extensively in the medical and pharmaceutical fields. This study synthesised the new ligand derivative from L-ascorbic acid-base using the following steps: A 5, 6-O-isopropylidene-L-ascorbic acid was prepared by reacting dry acetone with L-ascorbic acid followed by reacting it with trichloroacetic acid to yield [chloro (carboxylic) methylidene]-5, 6-O-isopropylidene-L-ascorbic acid in the second stage. In the third stage, the derivative was reacted with (methyl (6-methyl-2-pyridylmethyl) amine to create a new ligand (ONMILA). This novel ligand was identified using
... Show MoreThe ligand [Potassium (E)-(4-(((2-((1-(3-aminophenyl) ethylidene) amino)-4-oxo-1,4- dihydropteridin-6-yl) methyl) amino)benzoyl)-L-glutamate] was prepared from the condensation reaction of folic acid with (3-aminoacetophenone) through Schiff reaction to give a new Schiff base ligand [H2L]. The ligand [H2L] was characterized by elemental analysis CHN, atomic absorption (A.A), (FT-I.R.), (U.V.-Vis), TLC, E.S. mass (for spectroscopes), molar conductance, and melting point. The new Schiff base ligand [H2L], reacts with Mn(II), Co(II), Ni(II), Cu(II), Cr(III) and Cd(II) metal ions and (2-aminophenol), (metal : derivative ligand : 2-aminophenol) to give a series of new mixed complexes in the general formula:- K3[M2(HL)(HA)2], (where M=Mn(II) and
... Show MoreThe N-[(2,3-dioxoindolin-1-yl)-N-methylbenzamide] was prepared by the reaction of acetanilide with isatin then in presence of added paraformaldehyde, the prepared ligand was identified by microelemental analysis, FT.IR and UV-Vis spectroscopic techniques. Treatment of the prepared ligand with the following selected metal ions (CoII, NiII, CuII and ZnII) in aqueous ethanol with a 1:2 M:L ratio, yielded a series of complexes of the general formula [M(L)2Cl2]. The prepared complexes were characterized using flame atomic absorption, (C.H.N) analysis, FT.IR and UV-Vis spectroscopic methods as well as magnetic susceptibility and conductivity measurements. Chloride ion content was also evaluated by (Mohr method). From the obtained data the octahed
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Background: Masseter muscle is one of the most obvious muscles of mastication and considered as one indicator of jaw muscle activity. It has a major influence on the transverse growth of the midface and the vertical growth of the mandible. This study undertaken to determine the role of cephalometric analysis for discrimination between Cl I and Cl III skeletal relationships, determine the role of ultrasonography in determination of masseter muscle thickness, compare masseter muscle thickness between Cl I and Cl III skeletal relationships, and determine the effect of gender on masseter muscle thickness. Material and Method: The sample of the current study consisted of 70 Iraqi subjects 40 males and 30 females with age ranging 18-25 years. The
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Antibiotic resistance has been a growing worldwide public health issue. The World Health Organization (WHO) has stated that the search for new antibiotics is slow, while antibiotic resistance is growing. WHO has also declared that antibiotic resistance is one of the top 10 global public health threats facing humanity in the 21st century. Therefore, this review discusses the potential of metal-based drugs as antibacterial agents from the period of the early 2000s to date. The review reveals that a lot of preliminary work has been done to assess these as potential drugs. However, their mode of action is faintly described. Furthermore, a few examples of metal-based drugs assessed for their modes of action are described. These compounds are ide
... Show MoreThe [2-hydroxy-1, 2-diphynel-ethanone oxime] was reacted with 1, 2-dichloroethan to give the new ligand [H2L]. this ligand was reacted with some metal ions (Co (II), Ni (II), Cu (II), Zn (II) and Cd (II) in methanol as a solvent to give a series of new (1: 1) complexes of the general formula [M (HL)] Cl,(where: M= Co (II), Ni (II), Cu (II), Zn (II) and Cd (II)) are isolated All compounds have been characterized by spectroscopic methods [IR, UV-Vis] atomic absorption. Chloride content along with conductivity measurements. From the above data the proposed molecular structure for (Co, Cu, Ni, Zn and Cd) complexes adopting a tetrahedral structure
Background/aim: The rising challenge of microbial resistance necessitates the development of novel therapeutic agents. This study aims to synthesize, characterize, and evaluate the antimicrobial potential of a new series of mixed-ligand metal complexes (ZnII, CuII, NiII, and MnII) derived from a p-hydroxybenzaldehyde-4-aminoantipyrine Schiff base and 2,2′-bipyridine, in addition to assessing the binding affinity and pharmacokinetic properties of the synthesized free Schiff base ligand through molecular docking and ADME profiling. Methods: The Schiff base ligand and its transition metal complexes were synthesized and subsequently characterized using single-crystal X-ray diffraction, elemental analysis, FTIR, UV–Vis spectroscopy, NMR, mag
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In this work, the preparation of new multidentate Schiff-base lig and and its metal complexes are described. The formation of the lig and{ 2,2`((5-methyl-1,3-phenylene)-bis-(oxy))-bis-N`(E`)-2- hydroxybenzylideneacetohydrazide}[H2L] was prepared from the reaction {2,2-((5-methyl-1,3-phenylene)-bis-(oxy))- di-(acetohydrazide)}[M]precursor and salicylaldehyde in a 1:2 mole ratio, respectively. The reaction of the lig and [H2L] with (Cr+3 , Mn+2 and Fe+2 )metal ions in a 1:2 (L:M) mole ratio. Ligand and complexes were characterised via spectroscopic analyses; [FT-IR, UV-Vis spectroscopy,(C.H.N) microanalysis, chloride content, thermal analysis(TG), electrospray mass, magnetic susceptibility and conductivity measurements. The characterisation d
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