Background: Dental caries is one of the most significant problems in world health care. Restoring carious primary teeth is one of the major treatment goals for Children, and the light activated resin restoration materials like composite, resin-modified glass ionomer and polyacid-modified which was introduced in dentistry in 1970, widely used in clinical dentistry but its application increased dramatically in recent years because of its biocompatibility, color matching, good adhesive properties of its resemblance in physical and mechanical aspects to tooth. The aim of this study: To evaluate the microleakage of Polyacid-Modified Composite resin Compared to Flowable Hybrid Composite and Resin-Modified Glass ionomer cement. Materials and methods: Thirty extracted primary molar teeth and thirty extracted permenant premolar teeth were used in this study 20 for each material, then standardized Class V cavities of teeth was prepared in the buccal and lingual surfaces. Using Polyacid-modified composite Resin (Compomer), flowable composite resin and Resin-modified glass Ionomer RMGI. The samples will be divided into three groups according to type of restorative material used and light cured with a light cure device (Ivoclar Vivadent Bluephace), after complete curing the sample will examined by Scanning electron microscope (SEM) and then measure the microleakage. Results: The RMGI shows the statistically significantly lowest mean value of microleakage, followed by Compomer shows statistically significantly lower mean value. Flowable Composite shows the statistically significantly highest mean microleakage. There is no statistically significant difference in microleakage values between the permanent and primary teeth. Conclusion: The Resin-modified glass Ionomer is better in term of microleakage than Polyacid-modified composite Resin and Flowable Composite.
The reaction oisolated and characterized by elemental analysis (C,H,N) , 1H-NMR, mass spectra and Fourier transform (Ft-IR). The reaction of the (L-AZD) with: [VO(II), Cr(III), Mn(II), Co(II), Ni(II), Cu(II), Zn(II), Cd(II) and Hg(II)], has been investigated and was isolated as tri nuclear cluster and characterized by: Ft-IR, U. v- Visible, electrical conductivity, magnetic susceptibilities at 25 Co, atomic absorption and molar ratio. Spectroscopic evidence showed that the binding of metal ions were through azide and carbonyl moieties resulting in a six- coordinating metal ions in [Cr (III), Mn (II), Co (II) and Ni (II)]. The Vo (II), Cu (II), Zn (II), Cd (II) and Hg (II) were coordinated through azide group only forming square pyramidal
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