The effect of the treatments were the combination of ozone gaz with high
temperatures ( 35، 40 and 45C) and tempreture alone in addition to control treatment
treatments were tested on Egges and Pupae stages of hairy grain beetle
Trogoderma granarium (Everts). Results showed that( Z+H) and (H) treatments
were more lethally effective (100%mortality) than to control treatment on Egges
and Pupae stages of insect . The results also showed that first treatment(Z+H) was
more effective than the second treatment (H) on two stages , 1Tthe total1T 1Tkillings1T 1T100% (LT100)1T 1Tin eggs1T 1Treached at1T 1Tperiods1T 1T15.001T, 1T13.001T 1Thours and1T 1T18 minutes1T, respectively1T
with treatment of1T 1Tthe 1Tozone gaz with high temperatures ( 35، 40 and 45C),when
tempreture alone showed 1Texposure to1T 1T0.01T, 1T0.01T 1Tand 30 minutes1T. 1TResult showed also
the pupae stage was1T 1Tmore resistant1T than egg stage 1Tthe time required1T 1Tto
achieve1T 1T100%1T 1Tkill1T 1Tratio1T 1Tis1T 1T15.001T, 1T13.301T 1Tand1T 1T1.001T 1Thours1T, respectively, 1Tand1T 1Tin the
treatment of1T tempreture alone showed 1Texposure to1T 1T0.01T, 1T0.01T 1Tand1T 1T1.151T 1Thours1T,
respectively. ,the temperature alone treatment with 35,40C was not effective on
Egg and Pupae while the temperature 45C alone and combined with Ozone gaz was
more effective on two stages of insect .It was also found that Egg stage was more
sensetive to all treatments than Pupae stage at 45 Celsius
The reaction oisolated and characterized by elemental analysis (C,H,N) , 1H-NMR, mass spectra and Fourier transform (Ft-IR). The reaction of the (L-AZD) with: [VO(II), Cr(III), Mn(II), Co(II), Ni(II), Cu(II), Zn(II), Cd(II) and Hg(II)], has been investigated and was isolated as tri nuclear cluster and characterized by: Ft-IR, U. v- Visible, electrical conductivity, magnetic susceptibilities at 25 Co, atomic absorption and molar ratio. Spectroscopic evidence showed that the binding of metal ions were through azide and carbonyl moieties resulting in a six- coordinating metal ions in [Cr (III), Mn (II), Co (II) and Ni (II)]. The Vo (II), Cu (II), Zn (II), Cd (II) and Hg (II) were coordinated through azide group only forming square pyramidal
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