doi:10.24996/ijs.2020.61.3.8

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Publication Date

Fri Mar 27 2020

Journal Name

Iraqi Journal Of Science

Volume

61

Issue Number

3

DOI

10.24996/ijs.2020.61.3.8

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(1)

Uranium Concentration in Some Medical Herbs

Medical Herbs

Uranium concentration

fission tracks technique

CR-39 track detector

Annual committed effective dose

Laith Ahmed

Nada F.

Enas M.

Ibtisam M.

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Uranium concentration and the annual committed effective dose in some selected medicinal plants commonly used in Iraq have been determined using fission tracks technique etch in twelve medical plants samples using CR-39 track detector. The results show that the uranium concentration ranged from 0.044Â±0.021 ppm in Thyme sample to 0.2Â±0.03 ppm in Black Pepper and Cardamom samples with an average value of 0.14 Â±0.0 4ppm. The average annual effective dose due to ingestion of uranium radionuclide was 13.77x10 -5 mSv/y, which is below the world average annual committed effective dose of 0.3 mSv/y for ingestion of natural radionuclides.

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Publication Date

Wed Jan 01 2020

Journal Name

Technologies And Materials For Renewable Energy, Environment And Sustainability: Tmrees20

Change detection of the land cover for three decades using remote sensing data and geographic information system

The changes in the land cover using geographical information systems and remote sensing techniques for the period (1990 - 2019) for part of the Baghdad governorate in central Iraq are detected and monitored. In this research

four satellite scenes with different sensors were used the TM

ETM+

and OLI

which were obtained by Landsat-5

Landsat-7 and Landsat-8 satellites

respectively. Maximum likelihood method supervised classification is adopted as the main classifier to distinguish different land cover types in the study region. The results showed that there are ten different classes in the values of their reflectance. This study proved that any landcover of the earth’s surface can be studied and determined by its spectral characteristics. The change for each class of the land cover for the study area was determined within the study period. The results of the study confirmed the possibility of identifying the types of land cover and finding the percentage of changes that occur in it and detecting it with high efficiency using the remote sensing technique.

Muna Aref

Amal Jabbar

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(3)

Publication Date

Sat Oct 01 2022

Journal Name

Environmental Advances

Stability and performance studies of emulsion liquid membrane on pesticides removal using mixture of Fe3O4Â nanoparticles and span80

The current study investigated the impact of nonionic surfactant span 80 in the existence of Fe3O4 magnetic nanoparticles on the emulsification of mixture of kerosene as petroleum based organic solvents and corn oil as a green diluent in the ratio 1:1

HCl was used as internal phase and the stability of the emulsion was carried out. The proposed Pickering emulsion liquid membrane has been exploited to investigate it is ability in the extraction of Abamectin pesticides from aqueous solution without utilizing carrier agent. Further

the effects of experimental parameters on extraction efficiency and emulsion stability such as

homogenizer speed

emulsification speed

contact time

Fe3O4-Span 80 ratios

HCL concentration

internal to membrane volume ratio (I/O) and pH of the external feed solution were carried out. The results showed that more than 99% of Abamectin could be extracted at 10 min contact time with a minimum breakage percent of 0.52% at the optimal conditions. The kinetic of the extraction were studied and the mass transfer coefficient was found to be for external phase () of 1.2

interfacial reaction rate constant () of 5.83 and the overall mass transfer coefficient () of 3.91 . The results of recyclability of the PELM revealed that the emulsion stability and extraction efficiency was nearly unchanged after three cycles.

Ahmed A.

Noor Q.

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(9)

Publication Date

Sat Sep 01 2018

Journal Name

Polyhedron

Novel dichloro (bis {2-[1-(4-methylphenyl)-1H-1, 2, 3-triazol-4-yl-κN3] pyridine-κN}) metal (II) coordination compounds of seven transition metals (Mn, Fe, Co, Ni, Cu, Zn and Cd)

The 1

3-dipolar cycloaddition “click” reaction between an azide and an alkyne to give a 1

2

3-triazole was reported by Huisgen in 1961 [1]. In 2002 the Copper(I)-catalyzed Azide-Alkyne Cycloaddition (CuAAC) to prepare a 1

2

3-triazole was reported [2]

[3]. The existence of relatively basic nitrogen atoms in the 1

2

3-triazole rings

and the possibility of introducing additional donor groups in the substituents (Fig. 1)

made the CuAAC “click” reaction an attractive method to prepare differently substituted 1

2

3-triazoles. These compounds have been used as ligands to coordinate to various metal ions that display a range of applications such as in electrochemical and photochemical studies

in supramolecular chemistry

magnetism

metal-ion sensing and catalysis [4]. The reasons for the success of the “click” reaction

is that it is easy to carry out and is widely applicable. It is not affected by a variety of functional groups

and can be carried out with a variety of Cu(I) catalysts and solvents

including aqueous conditions. The Cu(I) catalysts overcome the high activation energy barrier of the non-catalyzed Huisgen reaction by changing the mechanism of the reaction. A large variety of copper catalysts can be used for the CuAAC reaction

on condition that the maximum concentration of Cu(I) species is generated during the reaction. The pre-catalyst can be a Cu(II) salt (usually CuSO4) together with a reducing agent (often sodium ascorbate) or a Cu(I) compound in the presence of a base or amine ligand and a reducing agent to prevent oxidation to Cu(II). Some strong oxidising cupric salts or complexes such as Cu(OAc)2 also work. The solvent is very flexible from organic to aqueous

with the most commonly used combination water + an alcohol (t-BuOH

MeOH or EtOH). The key role of the solvent or solvent mixture is to solubilize the substrates and Cu(I) catalyst in order to ensure rapid reactions. Such aqueous conditions are very useful for biochemical conjugations

as well as for organic syntheses. We recently reported on the synthesis of a series of differently substituted 1

2

3-triazole chromophores

the substituted 2-(1-phenyl-1H-1

2

3-triazol-4-yl)pyridine ligands [5]

see Fig. 2 middle

with substituents R = H (L1)

CH3 (L2)

OCH3 (L3)

COOH

F

Cl

CN

CF3

O(CH2)3CH3 and N(CH3)2. These versatile ligands were found to coordinate to various first row transition metals

such as manganese

cobalt and nickel [6]. Here we extend the series to include more first row transition metal(II) coordination compounds

iron

copper and zinc

as well as a second row transition metal(II) coordination compound

cadmium

containing the 2-(1-(4-methyl-phenyl)-1H-1

2

3-triazol-1-yl)pyridine chromophore (Fig. 2 right with R = CH3). This series of seven novel coordination compounds is the first series of pyridyl-triazole based transition metal coordination compounds where seven different transition metals are coordinated to the same 1

2

3-triazole chromophore

namely 2-(1-(4-methyl-phenyl)-1H-1

2

3-triazol-1-yl)pyridine.

Kinaan M

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