The early Carboniferous Harur Formation from the Ora outcrop section of northern Iraq consists of black shale, calcareous shale and carbonate. The mineralogical and geochemical investigations (major and trace elements) of the black shale and calcareous shale units have been conducted to evaluate paleoenvironmental conditions including paleoclimate, paleoredox conditions, paleoproductivity, sedimentary rate, and to evaluate their effects on organic matter accumulation. The geochemical proxies such as the Chemical Index of Alteration (CIA), A-CN-K plot, Sr/Cu ratio, and the relation between the ratio of Ga/Rb and Sr/Cu suggest moderate to intense chemical weathering under humid conditions. The Rb/K and Sr/Ba ratios indicate a freshwater environment during deposition. Multiple paleo-redox indicators such as ratios of V/(V+Ni) and Th/U) and U index indicates deposition under depleted marine oxygen conditions and consequently recording an Ocean Anoxic Event (OAE). The Th/U ratio indicates that the sedimentary rate at the lower part of the section is less than that of the upper part of the section. The terrigenous clastic input index (Ti and Al) shows that clastic input reduced from the lower to the upper section which implies that the sea level rose first lower to the upper section. Both Al and Ti have positive correlations with TOC (Total Organic Carbon) which reveal that clastic input was advantageous for OM accumulation. The high ratios of (Fe + Mn)/Ti and the presence of nacrite minerals indicate hydrothermal activity during deposition. Hence, the main control factors of OM accumulation in the black shale and calcareous shale of the Harur Formation were terrigenous clastic fluxes, in addition to paleo-redox conditions and hydrothermal activities. On contrary, paleoproductivity proxies play a relatively less significant role in OM accumulation.
The effect of thickness variation on some physical properties of hematite α-Fe2O3 thin films was investigated. An Fe2O3 bulk in the form of pellet was prepared by cold pressing of Fe2O3 powder with subsequent sintering at 800 . Thin films with various thicknesses were obtained on glass substrates by pulsed laser deposition technique. The films properties were characterized by XRD, and FT-IR. The deposited iron oxide thin films showed a single hematite phase with polycrystalline rhombohedral crystal structure .The thickness of films were estimated by using spectrometer to be (185-232) nm. Using Debye Scherrerś formula, the average grain size for the samples was found to be (18-32) nm. Atomic force microscopy indicated that the films had
... Show MoreThe reaction oisolated and characterized by elemental analysis (C,H,N) , 1H-NMR, mass spectra and Fourier transform (Ft-IR). The reaction of the (L-AZD) with: [VO(II), Cr(III), Mn(II), Co(II), Ni(II), Cu(II), Zn(II), Cd(II) and Hg(II)], has been investigated and was isolated as tri nuclear cluster and characterized by: Ft-IR, U. v- Visible, electrical conductivity, magnetic susceptibilities at 25 Co, atomic absorption and molar ratio. Spectroscopic evidence showed that the binding of metal ions were through azide and carbonyl moieties resulting in a six- coordinating metal ions in [Cr (III), Mn (II), Co (II) and Ni (II)]. The Vo (II), Cu (II), Zn (II), Cd (II) and Hg (II) were coordinated through azide group only forming square pyramidal
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