The Yamama Formation is characterized by a wide geographic extension of southern Iraq. Microfacies analysis of this formation was studied in six wells distributed in six fields: Fayhaa, Sindbad, Siba, Zubair, Ratawi and West Qurna. This research aims to determine paleoenvironments by diagnosing biofacies and lithofacies. Miscellaneous marine fauna of foraminifera and calcareous algae, mainly green algae (dasycladacean.) and skeletal bioclasts from gastropods, pelecypods, bryozoans, sponge spicules, and echinoderms were found. Petrographic studies and well logs interpretations led to the identification of five main Microfacies ( Mudstone, Wackestone, Packestone, Grainestone and Rudstone and twelve submicrofacies (Foraminiferal-Lime mudstone submicrofacies, Argillaceous Lime Mudstone submicrofacies, Planktonic foraminiferal – Lime Wackestone submicrofacies, piculites/ Calcisphers – Lime Wackstone submicrofacies, Benthonic Foraminiferal -Lime wackestone/packestone submicrofacies, Algal (desycladecan) Lime wackestone submicrofacies, Algal-Lime packestone submicrofacies, Bioclastic/ Algal-Lime packestone submicrofacies, Algal/ Foraminiferal- Algal -Lime packstone submicrofacies, Peloidal poorly sorted grainstone with bioclasts submicrofacies, Intraclastic grainstone submicrofacies, Pesudo oolitic-Lithocodium aggregatum grainstone submicrofacies and finally Peloidal-intraclastic, and bioclastic grainstone submicrofacies). Microfacies are deposited in the lagoon, shoal, rudist biostrome and open marine gradient to middle and outer ramp environments. Vertical changes in microfacies with depth were reflected by lateral changes in marine depositional systems and the thickness of the formation. Shoal environments' microfacies are characterized by high thickness, while low thickness characterizes the open marine microfacies. The Yamama Formation was deposited on the low-angle homoclinic carbonate ramp, mainly in the inner and middle ramp, with outer ramp conditions in some parts of the formation.
The reaction oisolated and characterized by elemental analysis (C,H,N) , 1H-NMR, mass spectra and Fourier transform (Ft-IR). The reaction of the (L-AZD) with: [VO(II), Cr(III), Mn(II), Co(II), Ni(II), Cu(II), Zn(II), Cd(II) and Hg(II)], has been investigated and was isolated as tri nuclear cluster and characterized by: Ft-IR, U. v- Visible, electrical conductivity, magnetic susceptibilities at 25 Co, atomic absorption and molar ratio. Spectroscopic evidence showed that the binding of metal ions were through azide and carbonyl moieties resulting in a six- coordinating metal ions in [Cr (III), Mn (II), Co (II) and Ni (II)]. The Vo (II), Cu (II), Zn (II), Cd (II) and Hg (II) were coordinated through azide group only forming square pyramidal
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