This work presents the characteristics of plasma produced by fundamental wavelength (1064 nm) Q- switched Nd:YAG laser on Ag:Ni alloy in distilled water were investigated at different laser energies by optical emission spectroscopy technique. The size of produced nanoparticles from Ag:Ni target in distilled water were studied, by x-ray diffraction, UV-visible absorbance and atomic force microscopy, at different laser energies. Spectroscopic measurements show that electron temperature and electron density increase with increasing laser energy. It was found from AFM measurements that the produced nanoparticle size decrease from 97.13 nm to 71.20 nm, while XRD shows that the crestalline size decrease from 15.5 nm to 9 nm with increasing pulse laser energy. UV- visible absorbance shows at plasmon peaks shifted from 410 to 395 nm with increasing laser energy.
In the present study, pure Poly(viny1 alcohol) (PVA) and pyromellitic dianhydride (PMDA) cross linked PVA with (0,5,10,15 and 20)wt.% and doped with different molarity (5,9)M of sulfuric acid (H2SO4) were prepared by the solution casting method and were characterized as a function of frequency in the range (1-100) KHz.
The FT-IR results showed that the strong broad band observed at 3738.05 and 3857.63 cm-1 may be assigned to O-H stretching due to the strong hydrogen bond of intramolecular and intermolecular type in PVA film. When PVA is doped with 5M and 9M H2SO4, a new peak was noticed at 813 cm-1, this peak may be due to the fo
... Show MoreIn this present work, [4,4`-(biphenyl-4,4`-diylbis(azan-1-yl-1-ylidene))bis(methan-1-yl-1-ylidene)bis(2-methoxyphenl)(A1),4,4`-(biphenyl-4,4`-diylbis(azan-1-yl-1-ylidene))bis(methan-1-yl-1-ylidene)diphenol(A2),1,1`-(biphenyl-4,4`-diylbis(azan-1-yl-1-ylidene))bis(methan-1-yl-1-ylidene) dinaphthalen-2-ol (A3)]C.S was prepared in 3.5% NaCl. Corrosion prevention at (293-323) K has been studied by using electrochemical measurements. It shows that the utilized inhibitors are of mixed type based on the polarization curves. The results indicated that the inhibition efficiency changes were used with a change according to the functional groups on the benzene ring and through the electrochemical technique. Temperature increases with corrosion current
... Show MoreA non-destructive assay (NDA) for radioactive waste drum has been studied
using a local manufacturing gamma scanning system. The gamma system has been
designed and implemented using scanning system contains a high efficiency
portable HPGe detector for characterization and surveying the radioactive waste
drums at Al-Tuwaitha site- Baghdad. To achieve identification with nonhomogenous
radioactive waste drum, six parallel plastic pipes (2cm in diameter)
were inserted inside the cement type Portland contain radioactive sources and
located at different distances from the outer diameter of the drum. The efficiency
calibration is measured by conventional technique, using five miscellaneous radio
nuclides with drum. Th
This article reviews the construction of organic solar cell (OSC) and characterized their optical and electrical properties, where indium tin oxide (ITO) used as a transparent electrode, “Poly (3-hexylthiophene- 2,5-diyl) P3HT / Poly (9,9-dioctylfluorene-alt-benzothiadiazole) F8BT” as an active layer and “Poly(3,4-ethylenedioxythiophene)-poly (styrene sulfonate)” PEDOT: PSS which is referred to the hole transport layer. Spin coating technique was used to prepared polymers thin film layers under ambient atmosphere to make OSC. The prepared samples were characterized after annealing process at (80 ͦ C) for (30 min) under non-isolated circumference. The results show a value of filling factor (FF) of (2.888), (0.233) and (0.28
... Show MoreABSTRACT Fifty extremely halophilic bacteria were isolated from local high salient soils named Al-Massab Al-Aam in south of iraq and were identified by using numerical taxonomy. Fourty strains were belong to the genus Halobacterium which included Hb. halobium (10%). Hb. salinarium (12.5%), Hb.cutirubrum (17.5%), Hb-saccharovorum (12.5%), Hb. valismortis (10%) and Hb. volcanii (37.5%). Growth curves were determined. Generation time (hr) in complex media and logarithmic phase were measured and found to be 10.37±0.59 for Hb. salinarium. 6.49 ± 0.24 for Hb.cutirubrum. 6.70±0.48 for Hb-valismonis, and 11.24 ± 0.96 for Hb. volcanii
Acute myeloid leukemia is a malignant disease results from mutation in a multipotent haemopoietic stemcell. The study aimed to investigate NPM1 and FLT3-ITD mutations in Iraqi patients with AML and correlateresults with other clinical and laboratory findings. Fifty-eight AML patients, admitted to Baghdad TeachingHospital from October 2019 till March 2020 in addition to 25 normal controls, were included in the study.A detailed history, laboratory investigations including FLT3-ITD and NPM1 mutations were collected fromand analyzed. FLT3-ITD was detected in 17.24% of patients, NPM1 mutation in 10.34%. Most of thepatients are presented with pallor. FLT3-ITD mutation had a higher blast cell count (74%) while NPM1mutation had higher WBCs
... Show MoreNew complcxcof Cu (ll),Ni(ll) ,Co(ll), and Zn(ll) wi th 2- amino-5-p-Fiouro Phenyl 1,3,4-Thiadiazole have been synthesized . The products were isolated , studied and characterized by physical measurements, i.e., (Ff -IR) ,UV-Vis and the melting points were determined .The new Schiff base (L) has been used to prepare some complexes .The prepared complexes were identified and their tructural geometry were suggested.
New thermally stable aromatic poly(amide-imide)s ( PAI1- PAI4 ) were synthesized from direct polycondensation reaction of Terephthalic acid and Phthalic acid with two new different diamine monomers derivatives of 1,2,4,5-tetracarboxilic benzene dianhydride as a second diacides in a medium consisting of triphenyl phosphite (TPP) in N-methyl-2pyrrolidone (NMP) / pyridine solution containing dissolved calcium chloride CaCl2. The polymerization reaction produced a series of novel poly(amide-imide) in high yield. The new monomers were characterized by FTIR, 1H-NMR spectroscopy. The resulting polymers were typically characterized by means of FT-IR, 1H-NMR spectroscopy, and solubility tests. Thermal properties of the poly(amide-imide)s were als
... Show MoreA new ligand [N-(acetyl amino) thioxomethyl] valine was prepared from the reaction of acetyl iso thiocyanate with valine. The ligand was characterized by FT-IR, UV- vis and 1HNMR spectrum, The complexes with some metal ions (M +2 =Co,Ni,Cu,Zn,Cd,Hg) have been prepared and characterized. The structural diagnosis were established by IR,UV-Vis spectrum, flame atomic absorption spectroscopy conductivity and magnetic susceptibility ,the complexes showed tetrahedral geometry around the metal l.