Concentration of natural occurring radioactive material (NORM) in Markazia Degasing Station in North Rumaila oilfield (NDS) was measured in this study. Then, radiological assessment due to existing of NORM in different samples including soil, sludge, scale, oil, and water collected from different stages of oil and gas production NDS was done. Radioactivity concentration of Ra-226, Th-232 and K-40 were measured using gamma spectrometry system based on HPGe detector with efficiency of 30%. The results show that some locations within NDS are contaminated with NORM. The activity in Bq/kg of Ra-226, Th-232 and K-40 range between 15.19 in oil to 68.73 in sludge, 8.5 in oil to 23.45 in sludge and 80.23 in oil to 319.73 in saline water samples respectively. The places to be more contaminated among the other places within the processing stages of oil and gas production within NDS are dehydrator and desaltor stages. These locations have to be monitored and remediated periodically.
NORM in Markazia Degasing Station within North Rumaila Oilfield- Southern Iraq
NORM
Radiological
Oil and Gas
Rumaila
Radioactivity
Radiation
Publication Date
Fri Apr 01 2016
Journal Name
Journal Of Economics And Administrative Sciences
Comparing Bayes Estimators With others , for scale parameter and Reliability function of two parameters Frechet distribution
مقدر الإمكان الأعظم (MLE)
مقدر Bayes الأول
مقدر Bayes الثاني.
Maximum likelihood estimator (MLE) Bayes (1) and Bayes (2) Mean square error (E) is shape parameter is scale parameter under Quadratic loss function under General Entropy loss function
Publication Date
Sat Sep 01 2018
Journal Name
Polyhedron
Novel dichloro (bis {2-[1-(4-methylphenyl)-1H-1, 2, 3-triazol-4-yl-κN3] pyridine-κN}) metal (II) coordination compounds of seven transition metals (Mn, Fe, Co, Ni, Cu, Zn and Cd)
The 1
3-dipolar cycloaddition “click” reaction between an azide and an alkyne to give a 1
2
3-triazole was reported by Huisgen in 1961 [1]. In 2002 the Copper(I)-catalyzed Azide-Alkyne Cycloaddition (CuAAC) to prepare a 1
2
3-triazole was reported [2]
[3]. The existence of relatively basic nitrogen atoms in the 1
2
3-triazole rings
and the possibility of introducing additional donor groups in the substituents (Fig. 1)
made the CuAAC “click” reaction an attractive method to prepare differently substituted 1
2
3-triazoles. These compounds have been used as ligands to coordinate to various metal ions that display a range of applications such as in electrochemical and photochemical studies
in supramolecular chemistry
magnetism
metal-ion sensing and catalysis [4]. The reasons for the success of the “click” reaction
is that it is easy to carry out and is widely applicable. It is not affected by a variety of functional groups
and can be carried out with a variety of Cu(I) catalysts and solvents
including aqueous conditions. The Cu(I) catalysts overcome the high activation energy barrier of the non-catalyzed Huisgen reaction by changing the mechanism of the reaction. A large variety of copper catalysts can be used for the CuAAC reaction
on condition that the maximum concentration of Cu(I) species is generated during the reaction. The pre-catalyst can be a Cu(II) salt (usually CuSO4) together with a reducing agent (often sodium ascorbate) or a Cu(I) compound in the presence of a base or amine ligand and a reducing agent to prevent oxidation to Cu(II). Some strong oxidising cupric salts or complexes such as Cu(OAc)2 also work. The solvent is very flexible from organic to aqueous
with the most commonly used combination water + an alcohol (t-BuOH
MeOH or EtOH). The key role of the solvent or solvent mixture is to solubilize the substrates and Cu(I) catalyst in order to ensure rapid reactions. Such aqueous conditions are very useful for biochemical conjugations
as well as for organic syntheses.
We recently reported on the synthesis of a series of differently substituted 1
2
3-triazole chromophores
the substituted 2-(1-phenyl-1H-1
2
3-triazol-4-yl)pyridine ligands [5]
see Fig. 2 middle
with substituents R = H (L1)
CH3 (L2)
OCH3 (L3)
COOH
F
Cl
CN
CF3
O(CH2)3CH3 and N(CH3)2. These versatile ligands were found to coordinate to various first row transition metals
such as manganese
cobalt and nickel [6]. Here we extend the series to include more first row transition metal(II) coordination compounds
iron
copper and zinc
as well as a second row transition metal(II) coordination compound
cadmium
containing the 2-(1-(4-methyl-phenyl)-1H-1
2
3-triazol-1-yl)pyridine chromophore (Fig. 2 right with R = CH3). This series of seven novel coordination compounds is the first series of pyridyl-triazole based transition metal coordination compounds where seven different transition metals are coordinated to the same 1
2
3-triazole chromophore
namely 2-(1-(4-methyl-phenyl)-1H-1
2
3-triazol-1-yl)pyridine.
Publication Date
Wed Jan 02 2019
Journal Name
Journal Of The College Of Languages (jcl)
A traditional model of translation: Critical analysis: Традиционные модели перевода: критический анализ
traditional translation models
theory of formal and dynamic equivalence
theory of regular correspondences
informative
situational-denotative
functional-pragmatic theory of communication levels.
традиционные модели перевода
теория формальной и динамической эквивалентности
теория закономерных соответствий
информативная
ситуативно-денотативная
функционально-прагматическая теория уровней коммуникации
The article critically analyzes traditional translation models. The most influential models of translation in the second half of the 20th century have been mentioned, among which the theory of formal and dynamic equivalence, the theory of regular correspondences, informative, situational-denotative, functional-pragmatic theory of communication levels have been considered. The selected models have been analyzed from the point of view of the universality of their use for different types and types of translation, as well as the ability to comprehend the deep links established between the original and the translation.
Аннотация
Publication Date
Tue Dec 31 2019
Journal Name
Journal Of Economics And Administrative Sciences
Comparing Different Estimators for the shape Parameter and the Reliability function of Kumaraswamy Distribution
Kumaraswamy distribution
the shape parameter
reliability function
maximum likelihood
Bayes method
prior distributions (exponential distribution
chi-squared distribution and Erlang-2 type distribution)
the squared error loss function.
توزيع Kumaraswamy
معلمة الشكل
دالة المعولية
الإمكان الاعظم
طريقة بيز
التوزيعات الأولية (التوزيع الاسي
توزيع مربع كاي
توزيع ارلنك)
دالة الخسارة التربيعية.
In this paper, we used maximum likelihood method and the Bayesian method to estimate the shape parameter (θ), and reliability function (R(t)) of the Kumaraswamy distribution with two parameters l , θ (under assuming the exponential distribution, Chi-squared distribution and Erlang-2 type distribution as prior distributions), in addition to that we used method of moments for estimating the parameters of the prior distributions. Bayes
Publication Date
Sun Jun 01 2014
Journal Name
Baghdad Science Journal
Preparation and Identification of some new Pyrazolopyrin derivatives and their Polymerizations study
Synthesis
Fused Pyrazoles
1-(3
6-dimethyl-4-oxo-1
4-dihydro-5H-pyrazolo [4
3-C] pyridin-5-yl)-1H-pyrrole-2
5-Dione S1
1-[2-(3
6-dimethyl-4-oxo-1-phenyl-1
4-dihydro-5H-pyrazolo[4
3-C]pyridin-5-yl)ethyl]-1H-pyrrole-2
5-DioneS2 and 1-(3
6-dimethyl-4-oxo-1-phenyl-1
4-dihydro-5H-pyrazolo[4
3-C]pyridin-5-yl)-1H-pyrrole-2
5-Dione S3
reactivity ratios
copolymer composition
Mean Sequence lengths.
Preparation and Identification of some new Pyrazolopyrin derivatives and their Polymerizations study