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Structural, Gas Sensing and Dielectric Properties of HoXFe1-X FeO3 Perovskite Compound

Environmental pollutions and resources depletion motivates scientific research to innovate technologies for sustainable productive systems. To develop gas sensing substance with optimized performance a perovskite compound of HoxFe1-x FeO3 (where x= 0, 0.01, 0.03 and 0.05) were prepared by standard solid state reaction technique. The crystal structure was studied by XRD, which confirmed the formation of polycrystalline orthorhombic structure with space group Pbnm type perovskite. The preferred crystal growth of the main peak was (211). The structural parameters were also calculated and it was found that the lattice constants and particle size increased with the Ho doping ratio. The electrical properties were studied using the Hall effect, studied using the Hall effect, where the Hall coefficient, D.C conductivity (from 2.24E-06 (Ω-1.cm-1) at x=0) to 2.67E. -06 (Ω-1.cm-1) at x=0.05), mobility) 7.26 (cm2 / V.sec) at x=0 and decreased to 5.97 (cm2 / V .sec) at x=0.05 (and the concentration of charge carriers (2.14 E13 cm-3 at x=0 ) to 2.79E. 13 cm-3 at x=0.05 ) were calculated. The charge carrier concentration increased and charge mobility decreased with Ho addition. The Hall coefficient results revealed an n-type conduction mechanism. The dielectric constant ε r (in its real and imaginary parts) decreased with the increase in frequency of the applied electric field. tan δ and the AC conductivity were also calculated, and It was found that with the raise in the doping rate, the values of AC conductivity increase while tan δ decreases.

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Publication Date
Fri Dec 30 2022
Journal Name
Iraqi Journal Of Science
Synthesis and Dielectric Properties of MgO:ZnO Composites

      The dielectric properties of the fabricated composites MgO:ZnO with various mixing ratios (100,75:25,50:50,25:75, and 100 wt. %)were investigated. The structure analysis was conducted using X-ray diffraction. The structure phase, crystallite size and purity of the fabricated MgO:ZnO composites were confirmed using X-ray diffraction spectra. The results declared that the diffraction spectrum of 100%MgO composite samples were compatible with cubic structure along the plane (200) while the structures of residual composite's samples were compatible with hexagonal structures. The crystal size of the most pronounced plane (101) for crystal growth was changed from 30.4 nm to 53.2 nm by increasing ZnO ratio from 25 to 100wt%. The diel

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Publication Date
Wed Oct 28 2020
Journal Name
Iraqi Journal Of Science
Optical and Structural Properties of Titanium Dioxide Papered by DC Magneto-Sputtering as a NO2 Gas Sensor

 In this work, a reactive DC magnetron sputtering technique was used to prepare TiO2 thin films. The variation in argon and oxygen gases mixing ratios (4:1, 2:1, 1:1, 1:2, 1:4) was used to achieve optimal properties for gas sensing. In addition, an analysis of the optical XRD properties of TiO2 thin films is presented. High-quality and uniform nanocrystalline films were obtained at a working gas pressure of 0.25 mbar and  1:4 (Ar/O2) gas mixture. The optical properties showed a transparent thin film with uniform adherence to the substrate. The average transmission of the TiO2 films deposited on the glass substrates was higher than 95% over the range of 400 to 800 nm.

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Publication Date
Tue Feb 01 2022
Journal Name
Chalcogenide Letters
Copper telluride thin films for gas sensing applications

Copper Telluride Thin films of thickness 700nm and 900nm, prepared thin films using thermal evaporation on cleaned Si substrates kept at 300K under the vacuum about (4x10-5 ) mbar. The XRD analysis and (AFM) measurements use to study structure properties. The sensitivity (S) of the fabricated sensors to NO2 and H2 was measured at room temperature. The experimental relationship between S and thickness of the sensitive film was investigated, and higher S values were recorded for thicker sensors. Results showed that the best sensitivity was attributed to the Cu2Te film of 900 nm thickness at the H2 gas.

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Publication Date
Thu Sep 01 2022
Journal Name
Physical Chemistry Research
Dielectric Properties of Ultra-Low Dielectric Constant PVA-Pentaerythritol/MnO2 Nanocomposite

this work, a simple method was used to prepare the MnO2 nanoparticles. These nanoparticles then were characterized by several techniques, such as X-ray diffraction, Fourier transform infrared spectroscopy, scanning electron microscopy (SEM) and atomic force microscope (AFM). The results showed that the diffraction peak of MnO2 nanoparticles was similar to that of standard data. The images of AFM and SEM indicated that the MnO2 nanorods were growing from the MnO2 nano spherical shape. PVA-pentaerythritol/MnO2 nanocomposite films were fabricated by evaporating casting method. The dielectric constant and loss tangent of P-Ery/MnO2 films were measured between 10 kHz and 1 MHz using LCR. As the content of MnO2 increased, the dielectric constant

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Publication Date
Sun Jan 13 2019
Journal Name
Iraqi Journal Of Physics
Characterization of CuO thin films for gas sensing applications

Nanostructural cupric oxide (CuO) films were prepared on Si and glass substrate by pulsed laser deposition technique (PLD) using laser Nd:YAG, using different laser pulses energies from 200 to 600 mJ. The X-ray diffraction pattern (XRD) of the films showed a polycrystalline structure with a monoclinic symmetry and preferred orientation toward (111) plane with nano structure. The crystallite size was increasing with increasing of laser pulse energy. Optical properties was characterized by using UV–vis spectrometer in the wave lengthrange (200-1100) nm at room temperature. The results showed that the transmission spectrum decreases with the laser pulses energy increase. Sensitivity of NO2 gas at different operating temperatures, (50°C,

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Publication Date
Sun Jun 12 2011
Journal Name
Baghdad Science Journal
Study the effective of annealing on the structural and sensitivity properties for SnO2 thin films to CO2 Gas

In this research thin films from SnO2 semiconductor have been prepared by using chemical pyrolysis spray method from solution SnCl2.2H2O at 0.125M concentration on glass at substrate temperature (723K ).Annealing was preformed for prepared thin film at (823K) temperature. The structural and sensing properties of SnO2 thin films for CO2 gas was studied before and after annealing ,as well as we studied the effect temperature annealing on grain size for prepared thin films .

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Publication Date
Sat Sep 23 2017
Journal Name
Ibn Al-haitham Journal For Pure And Applied Sciences
Dielectric Properties of High Alumina Glass

High   Alumina   Glasses   "Alumina   Silicate   Glasses"   was prepared by utilizing powder technology technique. The starting materials are wasted soda-lime glass from an industrial site, Iraqi­ Duekhla raw kaolin and small amounts of potassium carbonates.

X-ray Diffraction and FTIR analysis show complete vitreous glasses are obtained. Increasing Alumina content plays an obvious role in improving physical and mechanical properties of the prepared high  alumina  glass.   In  addition,  the   increased  alumina  content enhanced the dielectric constant and reduced dielectric loss. These results may be interpreted as du

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Publication Date
Mon Oct 28 2019
Journal Name
Iraqi Journal Of Science
Oli and Gas Explorations via Satellite Remote Sensing Techniques for AL_Nasiriya

     This study investigates data set as satellite images of type multispectral Landsat-7, which are observed for AL_Nasiriya city, it is located in southern of Iraq, and situated along the banks of the Euphrates River. These raw data are thermal bands of satellite images, they are taken as thermal images. These images are processed and examined using ENVI 5.3 program. Consequently, the emitted Hydrocarbon is extracted, and the black body algorithm is employed. As well as, the raster calculations are performed using ArcGIS, where gas and oil features are sorted. The results are estimate and determine the oil and gas fields in the city. This study uncovers, and estimates several unexplored oil and gas fields. Whereas,

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Publication Date
Fri Nov 24 2023
Journal Name
Iraqi Journal Of Science
Effect of Annealing temperature on the Structural, Optical and Sensitivity Properties of Nanostructure SnO2 Films to CO2 and NH3 Gas

In this research, we studied the structural properties of SnO2 films nanostructure which prepared by chemical spray pyrolysis method at room temperature on the rules of glass heated (400oC) with rate of spraying (2.5 ml/ min). The effect of annealing temperaturs (450,500,550,600 and 650oC) for two hours on those properties has been indicated. The results of x-ray diffraction showed that all of the prepared films were polycrystalline with tetragonal type and orientation was (110) for all models before and after annealing, and the annealing led to an increase in the grain size. The full width at half maximum (FWHM) values of the (110) peaks of the films decreased from 1.492o to 1.064o with increasing annealing temperature .The surface morp

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Publication Date
Tue Feb 01 2022
Journal Name
Chalcogenide Letters
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