In this study, pure polylactic acid (PLA) and composite polylactic acid/ curcumin (PLA / Cur) were prepared by a suspension of ultrasonically agitated micrometer-sized curcumin powder, which was mixed with chloroform solvent under slow mechanical stirring and incorporated into the PLA. The resulting suspension was used to cast free-standing PLA / Cur composite films. The filler content was chosen to be 2.0 wt % curcumin. Physical properties (glass transition, temperature, mechanical and thermodynamic) were analyzed by Positron Annihilation Lifetime Spectroscopy (PALS), which is a unique tool for analyzing the defects of polymer materials. The free volume and holebility of PLA and PLA / Cur were studied in vacuum and temperature range of 283 to 353 K. Ortho-positronium (o Ps), life , and intensity were measured as more sensitive parameters to determine free volume dimensions. The results of the thermodynamic property of PLA, examined with PALS technique, revealed a phase change of around 58 ºC. Also, an improvement was observed in the PLA / Cur structure with the addition of curcumin, by reducing nano-size defects.
The present work involved four steps: First step include reaction of acrylamide ,N-?-Methylen-bis(acryl amide) and N-tert Butyl acryl amide with poly acryloyl chloride in the presence of triethyl amine (Et3N) as catalyst, the second step include homopolymerization of all products of the first step by using benzoyl peroxide(BPO) as initiator in (80-90)Co in the presence of Nitrogen gas(N2). In the third step the poly acrylimide which prepare in second step was convert into potassium salt by using alcoholic potassium hydroxide solution. Fourth step include Alkylation of the prepared polymeric salts in third step by react it with different alkyl halides(benzyl chloride, allylbromide , methyl iodide) by using DMF as solvent for(10-12) hours.
... Show MoreA total of 23 samples are collected from Injana and Mukdadiya Formations representing: sandstone (14 samples from Injana Formation and 9 samples from Mukdadiya Formation). 19 sandstone samples are thin sectioned for petrographic study (10 thin sections from Injana and 9 thin sections from Mukdadiya) and 23 sandstone samples are selected for heavy minerals study (14 samples from Injana and 9 samples from Mukdadiya). The petrographic investigations revealed that the sandstone of Injana and Mukdadiya Formations are composed primarily of rock fragments (sedimentary, igneous and metamorphic), quartz (monocrystalline and polycrystalline) and feldspars (orthoclase, microcline and plagioclase). The matrix is subordinate and the cement is mostly
... Show MoreElectro-kinetic remediation technology is one of the developing technologies that offer great promise for the cleanup of soils contaminated with heavy metals. A numerical model was formulated to simulate copper (Cu) transport under an electric field using one-dimensional diffusion-advection equations describing the contaminant transport driven by chemical and electrical gradients in soil during the electro-kinetic remediation as a function of time and space. This model included complex physicochemical factors affecting the transport phenomena, such as soil pH value, aqueous phase reaction, adsorption, and precipitation. One-dimensional finitedifference computer program successfully predicted meaningful values for soil pH profiles and Cu
... Show MoreAn interpretative study of the two-dimensional seismic data of the Afaq area was conducted using the Petrel 2017 software. 2D seismic reflection sections are used to give a structural interpretation of Afaq structure based on synthetic seismogram and well log data. Three reflectors, Zubair, Yamama, and Gotina Formations, were selected. These reflectors are defined from well west kifl (wk-1), Where located adjacent to the study area. Structural maps of the Zubair, Yamama, and Gotnia formations are prepared and interpreted, including TWT maps, Average velocity maps, and depth maps. The studies concluded that the Afaq structure area does not contain main faults, but secondary faults with short and limited extensions
... Show MoreInfertility represents a growing health problem in Mosul city and worldwide. Infertility defined as a failure to induce pregnancy after unprotected sexual intercourse for more than 12 months. Infertility in male is a multifactorial complex pathology that leads to different types of problems. This work try to explore the correlation between glycosylation gap and seminal fructosamine and another parameter in the young male patient in Mosul city. The study included 50 subjects with age range 19-29 year with BMI 18-26. The infertility group include 25 patients newly diagnosed with infertility before starting any treatment; have no infection and no structural abnormality. The control group included 25 healthy subjects. HbA1c, fructosamine, Se
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The current research aims to identify the level of partnership between school and community agencies to improve secondary school outcomes for students with intellectual disabilities and develop strategies that help enhance community partnerships between schools and agencies. The researcher used the qualitative research approach; he utilized the interviews as a tool for data collection. The sample of research included (12) participants: three female school leaders, three male-school leaders, three female-school supervisors, and three male-school supervisors in schools that have programs for students with intellectual disabilities in Riyadh. The results of the study showed that the level of partnership bet
... Show MoreThe present study aims to assess inter-specific competition between Hydrilla verticillata and Ceratophyllum demersum. A competition experiment design has five treatment combinations to terminal shoots of C. demersum only, terminal shoots of H. verticillata only and three different treatment combinations of C. demersum and H. verticillata together. Our results showed parameters growth of C. demersum were decreased of which, total chlorophyll, protein, and biomass while Superoxide dismutase (SOD), and Catalase (CAT) enzymes increase were significantly (p<0.05) compare with control treatment. While H. verticillata were increased total chlorop
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