Pomegranate peels were used to remove zinc, chromium and nickel from industrial wastewater. Three forms of these peels (fresh, dried small pieces and powder) were tested under some environmental factors such as pH, temperature and contact time.
The obtained results showed that these peels are capable of removing zinc, chromium and nickel ions at significant capacities. The powder of the peels had the highest capability in bioremoving all zinc, chromium and nickel ions while dried peels had the lowest capacity again for all metals under test. However, the highest capacities were found in a sequence of chromium, nickel and zinc. Furthermore, all these data were significantly (LSD peel forms = 2.761 mg/l, LSD metal ions = 1.756 mg/l) varied.
In case of chromium, these figures were 69.7 ± 0.9 mg/l, 58.0 ± 2.4 mg/l and 49.7 ± 0.5 mg/l for powder, fresh and dried peels respectively. Regarding nickel ions, the data were 58.7 ± 1.1 mg/l for peel powder, 50.7 ± 2.0 mg/l for fresh peel and 42.0 ± 1.2 mg/l for dry peel. While for zinc ions, the biosorption capacity was 48.4 ± 2.2 mg/l, 39.4 ± 0.8 mg/l and 32.0 ± 1.6 mg/l for powder, fresh and dry peels respectively.
However, some examined factors were found to have significant impacts upon bioremoval capacity of pomegranate peels such as pH, temperature, and contact time where best biosorption capacities were found at pH 4, with temperature 50 Cº and contact time of 1 hour.
Regarding pH, the highest bioremoval ability was found at pH 4 for all heavy metals, but with the sequence of Cr, Ni, and Zn and the data were 68.1 ± 1.5 mg/l, 56.0 ± 0.5 mg/l and 47.88 ± 1.21 mg/l respectively. Similar pattern of bioremoval capacity was detected for temperature which was 50 Cº giving capacities of 72.0 ± 0.0 mg Cr/l, 60.0 ± 1.84 mg Ni/l and 54.0 ± 1.72 mg Zn/l. In case of contact time, these capacities were again similar to those of pH and temperature and found to be 76.0 ± 3.0 mg/l , 64.0 ± 1.82 mg/l and 60.0 ± 2.0 mg/l for Cr, Ni, and Zn respectively but at 1 hour contact time.
Acidity constants at 30co and 0.125 ionic strength have been determined for the Nitrogous bases of nucleic acid; cytocine, uarcil and thymine, and found to be 3.55 x10-19 , 1.44 x10 -19 and 7.24 x10 -20 respectively. Stability constants of these bases with Thorium and uranyl ions have been determined. Results showed that metal ions Thorium and uranyl ions behave as hard acids and the nitrogenum bases behave as Hard bases according to Pearson's definition .Hardness – softness parameters for these ligands were calculated ,stability constants of complexes with metal ions could be arranged as follows :- Cytosine > Uracil > Thymine .
Electro coagulation treatment was used for zinc removal from electroplating wastewater of the State Company for Electrical Industries . This wastewater, here consists zinc ions with maximum concentration in solution of 90 ppm .
The parameters that influenced the wastewater treatment are: current density in the range 1-1.4 mA/cm2, pH in the range 5-10, temperature in the range 25-45°C and time in the range 10-180 minute.
The research is a laboratory experimental type using batch system for electrical process with direct current. The cell comprised of aluminum electrode as anode and stainless steel electrode as cathode. Thirty experiments and one hundred fifty sample lab tests were carried out in this research
... Show MoreReaction of  p-fluoro benzoic acid with the thiosemicarbazide and salcialdehyde gave the new bidentate ligand .The prepared ligand Identified by FT-I.R and U.V-Visible spectcopic technique .Treatment of the prepared   ligand   with following metal ions  M=Tb(III),Eu(III),Nd(III) and La(III) ,in ethanol with a (1:1) M:L ratio and at pH=7 yielded series of neutral complexes as the general formula  [M LCl (H O ]. The prepared complexes were characterized using (FT-IR, UV-Vis) spectra , melting point, molar conductivity measurements . chloride ion content were also evolution by (mhor method) . The proposed structure of the complexes using program , chem office 3D(2004) .
A comparative study was carried out on ecological and genetical adaptation of three Iraqi
freshwater snails, Physa acuta, Melanopsis buccinoidea and Melanoides tuberculata, in
respect to acute toxicity of heavy metals (Zn, Cd and Hg). Longevity are used as poisoning
tolerance criterion. LT 50 and LT 100 were determined for the studied snails at (0.5, 1, 5, and
10 ppm), for the three metals. Results indicated that Physa acuta had a higher tolerance than
Melanopsis buccinoidea and Melanoides tuberculata, which was the lower one. Previous
exposure to heavy metals in the original habitat was affecting on experimental tolerance and
no relationships of physical and chemical factors (total hardness, temperature, D. O. and
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This study depicts the removal of Manganese ions (Mn2+) from simulated wastewater by combined electrocoagulation/ electroflotation technologies. The effects of initial Mn concentration, current density (C.D.), electrolysis time, and different mesh numbers of stainless steel screen electrodes were investigated in a batch cell by adopting Taguchi experimental design to explore the optimum conditions for maximum removal efficiency of Mn. The results of multiple regression and signal to noise ratio (S/N) showed that the optimum conditions were Mn initial concentration of 100 ppm, C.D. of 4 mA/cm2, time of 120 min, and mesh no. of 30 (wire/inch). Also, the relative significance of each factor was attained by the analysis
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This study depicts the removal of Manganese ions (Mn2+) from simulated wastewater by combined electrocoagulation/ electroflotation technologies. The effects of initial Mn concentration, current density (C.D.), electrolysis time, and different mesh numbers of stainless steel screen electrodes were investigated in a batch cell by adopting Taguchi experimental design to explore the optimum conditions for maximum removal efficiency of Mn. The results of multiple regression and signal to noise ratio (S/N) showed that the optimum conditions were Mn initial concentration of 100 ppm, C.D. of 4 mA/cm2, time of 120 min, and mesh no. of 30 (wire/inch). Also, the relative significance of each factor was attained by the analysis of variance (ANO
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This study deals with the shallow alluvial aquifer situated beneath the urban area of kirkuk city. The ancient part of the city (Shorja) is affected by seepage from local agricultural areas causing relatively high heavy metals concentration in groundwater. The selection of polluted site depended on the highest TDS value (3856 mg/L) associated with the highest heavy metal concentrations (Pb, Ni, Co and Zn) in groundwater. This study focuses on the evaluation of natural attenuation effectivity for long-term protection of groundwater quality using realistic three-dimensional reactive-transport groundwater model. The requirements of 3-dimensional reactive transport model were obtained from field observation and laboratory works, in addition
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