A new Turbidimetric method characterized by simplicity, accuracy and speed for determination of Hydronium ion by continuous flow injection analysis. The method was based on the formation of complex Zn3[Fe(CN)6] for Zinc(II) that was eluted by Hydronium ion from cation exchanger column with Potassium hexacyanoferrate(III) for the formation of a pale yellow precipitate and this precipitate was determined using homemade Linear Array Ayah-5SX1-T-1D continuous flow injection analyser. The optimum parameters were 2.7 mL.min-1 flow rate using H2O as a carrier stream, 1.7 mL.min-1 reagent stream, 110 L sample volume and open valve for the purge of the sample segment. Data treatment shows that linear range 0.01-0.1 mol.L-1 for each acids (HClO4,HNO3,HCl,H2SO4) while L.O.D 30, 50.01,29.75,51.41 μg/sample for HClO4,H2SO4,HCl,HNO3 respectively from the stepwise dilution for minimum concentration of lowest concentration in linear dynamic range of the calibration graph. The correlation coefficient (r) was 0.9891, 0.9930, 0.9917, 0.9940 while percentage linearity (%r2) was 97.85%, 98.81%, 98.61%, 98.36% for HClO4, H2SO4, HCl, HNO3 respectively. R.S.D. % for the repeatability (n=5) was < 2% for determination of Hydronium ion with concentration 20 and 80 mMol.L-1. The method was applied successfully for the determination of Hydronium ion in commercial samples. Using paired t-test between the newly developed method and classical method; shows that there were no significant differences between either methods. On this basis the new method can be accepted as an alternative analytical method for determination of Hydronium ion in commercial samples.
This work is the first study of the Curculionoidea fauna from Kurdistan region of Iraq, based on the intensive survey in different localities of Kurdistan from March 2016 to November 2017. In total, 41 species belonging to 28 genera, 21 tribes and 3 families were collected and identified, including 25 species newly recorded for the Iraqi fauna.
General distribution, collecting localities and methods, with plant association data for each species are given.
16 March of every year marked the anniversary of the chemical gas attack on the City of Halabja, Kurdistan, Iraq, and its nearby villages. In the process, 5000 people reportedly died from the attack. Many more were wounded and the event left nearly 60 000 people displaced. A perceived consequence of the chemical bombing of Halabja City was the environmental pollution of the soil and water. A recent questionnaire completed by the population of Halabja City indicated that 35% believed that water pollution was still an issue, and 55% thought that soil pollution posed a high risk.
In 2016, were requested by the Halabja City governor to investigate the situation. And to lay to rest the perception and
In this study ZnS thin film was prepared by using thermal evaporation vacuum technique under the pressure (10-6) Torr on glass substrate at room temperature and annealing at 523 K Samples were irradiated to CO2 laser of power (1 watt) and wave length (10.6) μm at distance 10 cm from the source during (5 sec). The absorbance spectra was recorded by using UV-visible spectrophotometer and used to calculated some of optical properties investigated including their transmittance, reflectance spectra, energy gap, and extinction coefficient. From the result of thin films samples at room temperature and at 523 K, we conclude that the irradiation by laser causes a decrease in the transmittance and increasing in reflection and extinction coeffic
... Show MoreIn this paper, an estimate has been made for parameters and the reliability function for Transmuted power function (TPF) distribution through using some estimation methods as proposed new technique for white, percentile, least square, weighted least square and modification moment methods. A simulation was used to generate random data that follow the (TPF) distribution on three experiments (E1 , E2 , E3) of the real values of the parameters, and with sample size (n=10,25,50 and 100) and iteration samples (N=1000), and taking reliability times (0< t < 0) . Comparisons have been made between the obtained results from the estimators using mean square error (MSE). The results showed the
... Show MoreThis paper proposes improving the structure of the neural controller based on the identification model for nonlinear systems. The goal of this work is to employ the structure of the Modified Elman Neural Network (MENN) model into the NARMA-L2 structure instead of Multi-Layer Perceptron (MLP) model in order to construct a new hybrid neural structure that can be used as an identifier model and a nonlinear controller for the SISO linear or nonlinear systems. Two learning algorithms are used to adjust the parameters weight of the hybrid neural structure with its serial-parallel configuration; the first one is supervised learning algorithm based Back Propagation Algorithm (BPA) and the second one is an intelligent algorithm n
... Show MoreIn this work, new Schiff bases of quinazolinone derivatives (Q1-Q5) were synthesized from methyl anthranilate. The synthesis involved three steps. In the first step, methyl anthranilate was reacted with isothiocyanatobenzene, producing the thiourea derivative K1. The second step entailed reacting K1 with hydrazine hydrate, synthesizing 3-amino-2-(phenylamino) quinazolin-4(3H)-one (K2). The third step involved reaction of K2 with various aromatic aldehydes, yielding the Schiff bases derivatives Q1-Q5. The chemical structures of these compounds were identified by FT-IR,1H NMR and 13C NMR spectroscopy. The newly synthesized derivatives (Q1-Q5) were subjected to rigorous evaluation to assess their efficacy as corrosion inhibitors for ca
... Show MoreThe Pila Spi formation composed of seven lithotypes; carbonates (dolomite and
dolomitic limestone), marl, shale/claystone, red argillaceous mudstone, sandstone,
carbonate breccias and debris flow, which are arranged in repeated cycles of mixed
siliciclastic-calciturbidites in a range of gravity-flow regime in the Koi Sanjaq area.
Sedimentologic and facies evidences suggest developed marine environment for the
Pila Spi Formation. Facies analysis and associated sedimentary structures including
graded beddings decide turbidity and gravity flow regime origin of the rocks.
Marine environment is supported by the identifying glauconite and fossils types,
which is reported here for the first time rather than lagoon enviro