Asphaltenes are a solubility class described as a component of crude oil with undesired characteristics. In this study, Sharqy Baghdad heavy oil upgrading was achieved utilizing the solvent deasphalting approach as asphaltenes are insoluble in paraffinic solvents; they may be removed from heavy crude oil by adding N-Hexane as a solvent to create deasphalted oil (DAO)of higher quality. This method is known as Solvent De-asphalting (SDA). Different effects have been assessed for the SDA process, such as solvent to oil ratio (4-16/1 ml/g), the extraction temperature (23 ºC) room temperature and (68 ºC) reflux temperature at (0.5 h mixing time with 400 rpm mixing speed). The best solvent deasphalting results were obtained at room temperature and 12 ml/g solvents to oil ratio. As a result, the API of DAO was increased by 9.3º compared to the API of Sharqy Baghdad heavy oil. The asphaltene reduction was 61.56%. The Sulfur removal was 32.8%, the Vanadium removal was 36.48%, and the Nickel removal was 46.21%.
Low grade crude palm oil (LGCPO) presents as an attractive option as feedstock for biodiesel production due to its low cost and non-competition with food resources. Typically, LGCPO contains high contents of free fatty acids (FFA), rendering it impossible in direct trans-esterification processes due to the saponification reaction. Esterification is the typical pre-treatment process to reduce the FFA content and to produce fatty acid methyl ester (FAME). The pre-treatment of LGCPO using two different acid catalysts, such as titanium oxysulphate sulphuric acid complex hydrate (TiOSH) and 5-sulfosalicylic acid dihydrate (5-SOCAH) was investigated for the first time in this study. The optimum conditions for the homogenous catalyst (5-SOCAH) wer
... Show MoreA 3D geological model for Mishrif Reservoir in Nasiriyah oil field had been invented "designed" "built". Twenty Five wells namely have been selected lying in Nasiriyah Governorate in order to build Structural and petrophysical (porosity and water saturation) models represented by a 3D static geological model in three directions .Structural model showed that Nasiriyah oil field represents anticlinal fold its length about 30 km and the width about 10 km, its axis extends toward NW–SE with structural closure about 65 km . After making zones for Mishrif reservoir, which was divided into 5 zones i.e. (MA zone, UmB 1zone,MmB1 zone ,L.mB1 zone and mB2zone) .Layers were built for each zone depending on petrophysical propertie
... Show MoreThe studied succession (Lower Miocene-Early Middle Miocene) In central Iraq is distinguished by a wide range of fossils, mostly benthic foraminifera, and other fossils including bivalves, gastropods, echinoids fragments, red algae and coral are also presented. Index fossils of benthic foraminifera have been used for the purpose of determining the age of the Euphrates and Jeribe formations, because of their young age, wide geographical distribution and abundance in the selected wells.
The present study involves four selected wells of Ajil oil field and in terms of the biostratigraphy of the Euphrates, Dhiban, and Jeribe formations depending on benthic foraminifera and other associated fossils. Some of these fossils have a short ve
... Show MoreThe characterizations of reservoir require reliable knowledge of certain fundamental reservoir properties. Log measurements can define or at least infer these properties: resistivity, porosity, shale volume, lithology, and water, oil, or gas saturation and permeability. The current study represents evaluation of petrophysical properties in well LU-12 for Zubair Formation in Luhais Oil Field, southern Iraq. The petrophysical evaluation was based on geophysical well logs data to delineate the reservoir characteristics of Zubair Formation. The available geophysical well logs such as (sonic, density, neutron, gamma ray, SP, and resistivity logs) are digitized using the Didger software. The environmental corrections and petrophysical paramete
... Show MoreTEOS aerogel a is the most commonly used. a Aerogel has attracted increasing attention from both academic and industries due to its extraordinary performance and potentials. We have systematically studied the relationship between the densification temperature of the synthesis environment of silica aerogels on their resulting morphological, optical and thermal properties. SEM and BET measurements were employed as structural probes to ascertain the structural differences. Lee's disc apparatus was used for determining the thermal conductivity coefficient. There is a systematic correlation between the annealing temperature and the aerogel surface area, porosity, as well as pore size. The implemented autoclave was able to produce aerogel mono
... Show MoreDensity functional theory (DFT) with B3LYP level and 6-311G[Formula: see text] basis sets for light atoms like N and O and SDD basis sets for heavy atoms like Sn is used to examine the interaction of tin dioxide nanocrystals with nitrogen dioxide as a function of temperature from 273[Formula: see text]K to 373[Formula: see text]K through a Gaussian 09W software program. Gibbs free energy, enthalpy, and entropy of activation and reaction are calculated. The situation of transition of SnO2 clusters toward nitrogen dioxide is investigated. According to the findings, the activation energy of SnO2 clusters with nitrogen dioxide increases as the temperature rises (in negative value). Gauss view 0
... Show MoreThe subject of demand on oil derivative has occupied an important position at present time in the daily life context. The fuel of benzene and gas oil and kerosene is one of basic elements of that concern, and on local , regional and international levels. The oil derivatives have played a leading role in determining the course and nature of development since early 1970 to the present time whether in the productive Arab countries or the importing. The researcher set out from the hypothesis that the increase of the local consumer demand on some of the oil derivatives is because of the internal and external factors accompanied by the inability of the productive capability and local production to confront this increase, and the resort
... Show MoreIn this study, zinc ferrite magnetic nanoparticles (ZnFe2O4, ZFO MNPs) were employed as a sorbent for the removal of oil spill from water surfaces. ZFO MNPs were synthesized via a sol-gel process and characterized by Fourier transform infrared spectroscopy (FTIR) and X-ray powder diffraction (XRD). Both the apparent density and magnetic force were determined. ZFO MNPs presented a considerable magnetic force (40.22 mN) and an adequate density (0.5287 g/cm3), which are important for the magnetic separation and flotation. Four oil samples (gasoline engine oil, crude oil, used motor oil and diesel engine oil) were used to investigate the gravimetric oil removal capability of ZFO MNPs. The oil sorption capacit
... Show MoreThe use of ultraviolet rays is one of the methods of treating surface contamination of many foods especially pickles. however, there are some side effects to its use, especially in high percentage oil food products, it is necessary to determine the appropriate doses and time periods to avoid deterioration of its oil physicochemical characteristics. this study was conducted to see the effect of ultraviolet rays 15W on some chemical properties of olive oil when using it to preserve green olive pickles, treated for 5, 10 and 15 min daily. green olive fruits Iraqi variety (al-ashrasi), in season (2020-2021) were pickled using Spanish style, the best time period to pr
... Show MoreThe Early Cenomanian Ahmadi carbonates succession in selected oil-wells in south Iraqi oil fields have undergone; into sequence stratigraphic analysis as new reservoir stratigraphy optimization understanding. The sequence stratigraphy context: has applied on the mentioned carbonate reservoir in selected oil-wells from West-Qurna and Majnoon oil fields, with respect to Arabian-plate (AP) chronosequence stratigraphy and chrono-markers setting.
A meso-genetic buildup has infra-structured the studied Formation based-on; smallest-set of the genetically-related high-frequency lithofacies-cycle and cycles-set modeling. A genetic sequence (meso-sequence one MS1) is described as a well-encountered buildup between the (MFS-K120 of lower Ah
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