In this study, sulfur was removed from imitation oil using oxidative desulfurization process. Silicoaluminophosphate (SAPO-11) was prepared using the hydrothermal method with a concentration of carbon nanotubes (CNT) of 0% and 7.5% at 190 °C crystallization temperature. The final molar composition of the as-prepared SAPO-11 was Al2O3: 0.93P2O5: 0.414SiO2. 4% MO/SAPO-11 was prepared using impregnation methods. The produced SAPO-11 was described using X-ray diffraction (XRD) and Brunauer-Emmet-Teller (N2 adsorption–desorption isotherms). It was found that the addition of CNT increased the crystallinity of SAPO-11. The results showed that the surface area of SAPO-11 containing 7.5% CNT was 179.54 m2/g, and the pore volume was 0.317 cm3/g. However, the surface area of SAPO-11 containing 0% CNT was 125.311 m2/g, and pore volume was 0.275 cm3/g, while nanoparticles with an average particle diameter of 24.8 nm were obtained. Then, the prepared SAPO-11 was used in the oxidative desulfurization process. The oxidative desulfurization was studied using several factors affecting desulfurization efficiency, such as time (40, 60, 80, 100, and 120) min, amount of MO/SAPO-11 (0.3, 0.4, 0.5, 0.6, and 0.7) g/100 ml of simulated oil (100 ppm of dibenzothiophene), the amount of hydrogen peroxide (4ml) oxidizer/100 ml of simulated oil, and the temperature ranges from (40, 50, 60, 70, and 80 °C). The results showed that an increase in MO/SAPO-11 led to an increase in desulfurization. The best removal percentage for sulfur content was 92.79%, obtained at 70 °C and 0.6 g of MO/SAPO-11 containing 7.5% CNT, and the removal was 82.34% at 0% CNT and the same other conditions. While the equilibrium was achieved after 100 min. The results revealed that Freundlich's model described the adsorption of sulfur compounds better than Langmuir's, where the R2 of the Freundlich model was 0.9979 and the R2 of the Langmuir model was 0.9554.
Statistical fluctuations of nuclear energy spectra for the isobar A = 68 were examined by means of the random matrix theory together with the nuclear shell model. The isobar A = 68 nuclei are suggested to consist of an inert core of 56Ni with 12 nucleons in f5p-space (2p3/2, 1f5/2 and 2p1/2 orbitals). The nuclear excitation energies, required by this work, were obtained through performing f5p-shell model calculations using the isospin formalism f5pvh interaction with realistic single particle energies. All calculations of the present study were conducted using the OXBASH code. The calculated level densities were found to have a Gaussian shape. The distributions of level spacing P(s) an
... Show MoreSaxifraga afghanica Aitch. & Hemsl. is a new addition to the Saxifragaceae family in Iraq, from Qandil mountain (north-east of Erbil) within Rowanduz district (MRO). The collected specimens have different characteristics. S. afghanica is perennial, herb, with crowded shoots forming cushions, many branched. Leaves sessil, narrowly oblong, narrowly oblong-lanceolate, oblanceolate or sub-spatulate, glabrous, entire, ciliated at lower half, apex leaves aggregated into a rosette, chalk glands (pits at the leaves apex) 5. Bracts cultrate, linear or narrowly oblong, glandular-pubescent. Inflorescence corymbose cyme, flowers (3-5), white-pink, stamens 10, ovary semi-inferior, styles 2, divergent, recurved at the top. Capsule globose-semi glo
... Show MorePandemic COVID-19 is a contagious disease affecting more than 200 countries, territories, and regions. Recently, Iraq is one of the countries that have immensely suffered from this outbreak. The Kurdistan Region of Iraq (KRI) is also prone to the disease. Until now, more than 23,000 confirmed cases have been recorded in the region. Since the onset of the COVID-19 in Wuhan, based on epidemiological modelling, researchers have used various models to predict the future of the epidemic and the time of peak, yielding diverse numbers in different countries. This study aims to estimate the basic reproductive number [R0] for COVID-19 in KRI, using the standard SIR (Susceptible-Infected-Removed) epidemic model. A system of non
... Show MoreBackground: Glucose -6- phosphate deosphate dehydnogenase (G6PD) deficiency is a common problem in Iraqi as well as in tropical A subtropical region.
Aim of study: to study the epidemiological aspect of G6PD deftaiency among Iraqi children. Patients & Methods: This cross sectional study was conducted in the Pediatric ward/A L Kadhiymia Teaching Hospital during the season of Fava beans ingestion. Patients who were presented with acute attack of pallor were collected , history was taken and physical examination was done.
Results : Ninety seven cases were studied, males were affected more than female with a ratio of 3.85:1, the peak of age was between ( 1 - 5years ), 76 cases ,(78.36%).Previous history of neonatal jaundice was fou
In this research work, a new type of concrete based on sulfur-melamine modification was introduced, and its various properties were studied. This new type of concrete was prepared based on the sulfur-melamine modification and various ingredients. The new sulfur-melamine modifier was fabricated, and its fabrication was confirmed by IR spectroscopy and TG analysis. The surface morphology resulted from this modifier was studied by SEM and EDS analysis. The components ratios in concrete, chemical and physical characteristics resulted from sulfur-melamine modifier, chemical and corrosion resistance of concrete, stability of concrete against water adsorption, stability of concrete against freezing, physical and mechanical properties and durabi
... Show MoreThe general crisis of research methods in the social sciences
Research methodology: philosophy and techniques, founded by philosophers and applied by scientists, and no accurate application of techniques except with a deep understanding of philosophy, as a prerequisite. This fact is almost completely absent from the Iraqi and Arab academic mentality. This constituted one of the dimensions of the double crisis - theoretical and applied - of research methods in the social sciences. As first, there is no philosophy of science, neither as an independent material nor as an introductory subject, but not even an oral confirmation. Secondly, the advancement of quantitative research methods are presented without a background philosophy, as sol
This research includes a detailed morphological description of
the Sarcophaga dialensis sp . nov . in Iraq . Many morphological characters are used in identification especially chaetotaxy and male genitalia .Locality records , data of collection and host plant were mentioned.
War as a human phenomenon, has its own literature. Poetry is a major genre in this literature. This paper is an attempt to investigate and analyse some stylistic features in two selected, English and Arabic, war poems. These poems share the same theme.Both promote the principle of sacrificing one’s own life for the sake of homeland. This paper limits itself to analyse, thecontent words, tenses, semantic grouping of vocabulary and foregrounding in the two poems. The areas of analysis show great similarities in distributing the general content words (nouns, verbs, adjectives, and adverbs). In the analysis of the semantic areas of each content word, these poems reveal some similarities and some differences in their frequency rates.
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