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Rational assembly of Z-scheme FeTiO3/Fe-doped g-C3N4 photocatalytic heterojunctions: Photodegradation behavior and mechanism insight

Expanded use of antibiotics may increase the ability of pathogenic bacteria to develop antimicrobial resistance. Greater attention must be paid to applying more sustainable techniques for treating wastewater contaminated with antibiotics. Semiconductor photocatalytic processes have proven to be the most effective methods for the degradation of antibiotics. Thus, constructing durable and highly active photocatalytic hybrid materials for the photodegradation of antibiotic pollutants is challenging. Herein, FeTiO3/Fe-doped g-C3N4 (FTO/FCN) heterojunctions were designed with different FTO to FCN ratios by matching the energy level of semiconductors, thereby developing effective direct Z-type heterojunctions. The photodegradation behaviors of the FTO/FCN hybrids were systematically explored toward spiramycin (SPY) destruction under visible-irradiation. Using the FTO/FCN (1:2) photocatalyst, the photodegradation efficiency of the bare FTO boosted from 41.6 % to 96.6 %, which was due to suitable band positions of both photocatalysts and thus Z-type heterojunction transfer pathway to prevent the recombination of photo-charge carriers. More importantly, the FTO/FCN hybrid photocatalysts show broad applicability, as they can decompose other organic contaminants including ibuprofen (IBU), ciprofloxacin (CIP), bisphenol A (BPA), and Rhodamine B (RhB). The photodegradation rates of IBU, CIP, BPA and RhB were 90.9 %, 93.4 %, 80.6 %, and 86.2 %, respectively, after 120 min. The trapping analyses were performed and exhibited that the key reactive-species in the SPY photodegradation were •O2􀀀 and h+, while •OH and electrons were secondary species in the reaction. The FTO/FCN composite photocatalyst has the properties of high photo-stability and recycling (the SPY photodegradation and mineralization efficiencies decreased only by 4 % and 5.2 %, respectively).

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Publication Date
Thu Jan 13 2022
Journal Name
Iraqi Journal Of Science
Facies Analysis of The Siliciclastic-calciturbidites, Gercus Formation In Dokan Area, Ne-Iraq; New Insight On Deposition Enviroment And Basin Evolution

Sedimentologic and facies evidences reveal a marine environment for the Gercus Formation. Facies analysis and associated sedimentary structures including graded beddings decide turbidity origin of the rocks. Marine environment is supported by the identifying glauconite and fossils types reported for the first time.
The formation composed of seven lithotypes; shale/claystone, mudstone, sandstone, carbonate, conglomerate, breccias and debris flow, which are arranged in repeated cycles of mixed siliciclastic-carbonate turbidites in a range of gravity-flow regime. The Gercus successions are grouped into four facies associations confirming marine depositional systems, these are (from bottom to top); slump siliciclastic-calciturbidites (dol

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Publication Date
Tue Nov 01 2016
Journal Name
Iosr Journal Of Computer Engineering
Implementation of new Secure Mechanism for Data Deduplication in Hybrid Cloud

Cloud computing provides huge amount of area for storage of the data, but with an increase of number of users and size of their data, cloud storage environment faces earnest problem such as saving storage space, managing this large data, security and privacy of data. To save space in cloud storage one of the important methods is data deduplication, it is one of the compression technique that allows only one copy of the data to be saved and eliminate the extra copies. To offer security and privacy of the sensitive data while supporting the deduplication, In this work attacks that exploit the hybrid cloud deduplication have been identified, allowing an attacker to gain access to the files of other users based on very small hash signatures of

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Publication Date
Sat Jan 01 2022
Journal Name
Plasma Medicine
Effect of Cold Atmospheric Plasma on Osteoporosis by FE-DBD System

The work demonstrates the effect of cold atmospheric plasma (CAP) on adult female rats suffering from osteoporosis, the used plasma was generated by a floating electrode-dielectric barrier discharge system with an electrode diameter of 3 cm. The output power was from (12-20) watts. The effect of non-thermal plasma was observed on rats with various exposure times of 20, 30, and 40 sec. It was noted that the blood calcium percentage of animals exposed to cold plasma increased, as well as an increase in the level of vitamin D3 at the same time, it is noted that there is no effect on parathyroid hormone level. For the thyroid gland, it is noticed an increase in the level of T3, and T4 hormones in the blood during the period of induction for

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Publication Date
Sat Feb 26 2022
Journal Name
Iraqi Journal Of Science
Spectroscopic Analysis of CdO: Fe Plasma Generated by Nd: YAG Laser

     In this work, the optical emission spectrum technique was used to analyze the optical emission spectrum of (CdO: Fe) plasma produced by laser Nd: YAG with a wavelength of (532) nm, a period of 10 ns, and a focal length of 10 cm in the energy range of (200-500) mJ. The electron temperature (Te) was determined using the method of line intensities ratio. Using the Saha-Boltzmann equation, the electron density (ne) was determined. Other plasma parameters such as plasma frequency (fp), Debye length (λD) and Debye number (ND) were also measured. The CdO: Fe (at a mixing ratio of X= 0.5.) plasma spectrum was observed for different energies. As a fu

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Publication Date
Tue Feb 12 2019
Journal Name
Iraqi Journal Of Physics
Investigation of the dielectric properties of Sn – doped PMMA/PVA blends

Blends of Polymethyl methacrylate (PMMA)/polyvinyl alcohol (PVA) doped with 2% weight percentage of Sn were prepared with different blend ratios using casting technique. The measurements of A.C conductivity σa.c within the frequency range (25kHz – 5MHz) of undoped and Sn doped PMMA/PVA blends obeyed the relationship σ= Aws were the value of s within the range 0 > s > 1. The results showed that σa.c increases with the increase of frequency. The exponent s showed preceding increase with the increase of PVA content for PMMA/PVA blends doped with Sn. The dielectric constant, dielectric loss, A.C electrical conductivity are varied with the concentration of PVA in the blend and frequency of applied electrical field.

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Publication Date
Thu Dec 01 2011
Journal Name
Proceedings Of 2011 International Conference On Computer Science And Network Technology
A new proposed handoff scheme for mobile communication systems

There are many studies dealt with handoff management in mobile communication systems and some of these studies presented handoff schemes to manage this important process in cellular network. All previous schemes used relative signal strength (RSS) measurements. In this work, a new proposed handoff scheme had been presented depending not only on the RSS measurements but also used the threshold distance and neighboring BSS power margins in order to improve the handoff management process. We submitted here a threshold RSS as a condition to make a handoff when a mobile station moves from one cell to another this at first, then we submitted also a specified margin between the current received signal and the ongoing BS's received signal must be s

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Publication Date
Tue Jan 01 2013
Journal Name
Journal Of Geology & Geosciences
Sorption Mechanism and Capacity Evaluation of Palygorskite from Iraq to Remove Pb from Aqueous Solution

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Publication Date
Tue Nov 01 2016
Journal Name
Journal Of Engineering
Synthesis and Characterization Of CaMgO2 Nanoparticles Photocatalyst For the Decolorization Of Orange G Dye

A series of heterogeneous basic catalysts of CaO, MgO and CaMgO2 at different calcination temperature were synthesized via solution combustion method. Different characterization techniques have been carried out to investigate the structure of the produced catalysts i.e. X-ray diffraction (XRD), particle size analyzer, morphology by atomic force microscope (AFM) and reflection using UV-VIS diffuse reflectance spectra. The particles size analyzer revealed that the mixed oxide catalysts calcined at different calcination temperature possess smaller nano size particles compared to pure CaO. Moreover, the energy band gap was calculated based on the results of diffuse reflectance spectra. The energy band gap was redu

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Publication Date
Tue Oct 15 2019
Journal Name
International Journal Of Electrical And Computer Engineering (ijece)
Combining Convolutional Neural Networks and Slantlet Transform For An Effective Image Retrieval Scheme

In the latest years there has been a profound evolution in computer science and technology, which incorporated several fields. Under this evolution, Content Base Image Retrieval (CBIR) is among the image processing field. There are several image retrieval methods that can easily extract feature as a result of the image retrieval methods’ progresses. To the researchers, finding resourceful image retrieval devices has therefore become an extensive area of concern. Image retrieval technique refers to a system used to search and retrieve images from digital images’ huge database. In this paper, the author focuses on recommendation of a fresh method for retrieving image. For multi presentation of image in Convolutional Neural Network (CNN),

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Publication Date
Sat May 01 2021
Journal Name
Journal Of Physics: Conference Series
g-Closed Soft Sets in Soft Closure Spaces
Abstract<p>The aim of the present work is to define a new class of closed soft sets in soft closure spaces, namely, generalized closed soft sets (<italic>gc</italic>-soft sets, for short) which are defined over an initial universe set with a fixed set of parameters. This new class is a generalization to the class of closed soft sets. A necessary condition for a <italic>gc</italic>-soft set to be a soft closed is also obtainable. Moreover, the union and intersection of two <italic>gc</italic>-soft sets are discussed. Besides, some properties of <italic>gc</italic>-soft sets in the product soft closure spaces are also studied. Also, as an application of <jat></jat></p> ... Show More
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