Constructal theory plays a major role in the conceptual design stage of the structural system in architecture. It provides a conceptual framework for predicting the form depending on natural systems to model those systems geometrically according to the constructal law that works in two directions: the first is towards predicting the general form of the structural system, and the second is the physical application of the law in the process of detailed design of the parts of the system. The aim of this paper is to determine the mechanism adopted in the structural design according to the constructal theory, assuming that the structural design according to the constructal theory achieves high structural efficiency. The paper depends in its theoretical framework on the clarification of the concepts of constructal theory, the mechanism of constructal law work, and then the verification of its compliance with the applicable rules to achieve high efficiency. The paper concludes a set of indicators that can be adopted in assessing the level of structural efficiency - at the level of form and material - of architecturally designed structures according to the constructal theory. The research concluded that constructal theory contributes significantly to research on the origins of living systems, and to employ them in the process of creating the architectural form on one hand, and enhancing the structural efficiency of the structural performance on the other hand.