Carbonate matrix stimulation technology has progressed tremendously in the last decade through creative laboratory research and novel fluid advancements. Still, existing methods for optimizing the stimulation of wells in vast carbonate reservoirs are inadequate. Consequently, oil and gas wells are stimulated routinely to expand production and maximize recovery. Matrix acidizing is extensively used because of its low cost and ability to restore the original productivity of damaged wells and provide additional production capacity. The Ahdeb oil field lacks studies in matrix acidizing; therefore, this work provided new information on limestone acidizing in the Mishrif reservoir. Moreover, several reports have been issued on the difficulties encountered during the stimulation operation of the Ahdeb oil field, particularly for the development of the Mishrif reservoir. Since the new core flooding system is built to operate safely and straightforwardly. This study introduced the results of Matrix acidizing experiments, covering the most recent developments in linear core flooding. High-permeability flow pathways are created, and a longer and wider wormhole was generated at a high acid injection rate (6.67 cc/min). The acid efficiency curve yielded the lowest pore volume injected at the breakthrough of the PV_(bt-opt) is 2.73 and the v_(i-opt)=0.6 cm/min; thus, the optimum injection rate that results in an optimal possible wormhole and the least quantity of acid being used for this reservoir is 2.16 cc/min. This research evaluated the impact of matrix acidizing treatment on acoustic characteristics, which studies show are lacking or have never been investigated previously. Furthermore, in the assessment of geomechanical rock properties and elastic and petrophysical parameters before and after acid injection, one of the new concepts discovered during the lab experiment observation of the acoustic waveform before and after acid treatment for the tested rock sample is that the initial arrival time before acid treatment is 21.6 microseconds, with a delay of 31.2 microseconds attributed to the wormhole channel and mineral disintegration. CT-Scan applications in matrix acidizing were investigated in this research; additionally, a 3D view of plug samples was constructed to represent the wormhole extension via CT-processing software. A license of Stimpro Stimulation Software has been used to validate the experimental work to the field scale, making it the most comprehensive instrument for planning and monitoring matrix acid treatment and utilizing actual data to provide a far better knowledge of the well's reaction, with methods that represent the reality of what is happening in the reservoir before, during, and after matrix acid treatments, through the post-treatment skin factor which is the most often utilized statistic for analyzing stimulation treatments and relies on the geometry of the wormholed zone. The acid treatment evaluated for the well AD-12, primarily for the zone Mi4; matrix acid treatments can have their production behavior predicted or matched using the reservoir simulation and production analysis option, employing the numerical simulation license software Petrel (Schlumberger) and Rubis (KAPPA) to determine the efficacy of previous treatments and the economics associated with future treatments. The estimated oil gain volume and percentage for the Mi4 unit in Ad-12 using particularly skin value -3.97 computed from Stimpro software for real stimulation acid job, it is yield enhancement in production of oil gain volume 6154 barrels as well as 105% increase of gain percentage for three months after matrix acidizing.
The experiment was conducted in Al- Mahaweel Research Station in Babel Governorate, Ministry of Agriculture during autumn season 2016-2017 to determine the role of irrigation management processes and micronutrient fertilization in growth and productivity of two varieties of wheat IPA 99 and Al-Rasheed 22 in clay loam soil classified as Typic Torriflovent. The experiment included four irrigation treatments and six fertilization treatments. The experiment was designed under randomized complete block design (RCBD) with three replications. Wheat grain IPA 99 and Al-Rasheed 22 varieties were planted in 23/11/2016 and harvested in 13/5/2017. The amount and periods of irrigation depended on sensors reading of volumetric water content was measured
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Anaemia is a crucial issue among cancer patients and need to be treated properly. High incidence of anaemia in patients with cancer have been associated with several physiological manifestations, leading to decreased quality of life (QOL).
The current study aimed to assess the severity of anaemia, evaluate the current treatment guideline of anaemia, and to determine the association between the level of anaemia and its treatment on quality of life of breast cancer patients in Malaysia. This prospective study conducted among breast cancer patients in multicancer centers in Malaysia including three follow ups after receiving their chemotherapy. Clinical data were collected from their medical records and at each follow up, they asked
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One of most the important compounds which have active hydrogen (substrate) is the thiols which used in a wide field in preparation of Mannich bases . A large number of Mannich bases have been prepared as a biologically active compound (pharmaceutical, pesticides, bactericidal, fungicidal and tuberculostatic) and in order to correlate their structure and reactivity with their pharmacological activity such as . It has been reported that the reaction is easily proceeded by using primary and secondary amine beside formaldehyde. But when we tried the reaction of thiols as substrate and formaldehyde and succinimide instead of amine, the reaction did not proceed to give Mannich base but product were methylenene – bis – sulfide . Mann
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Abstract
The target derivative are gentamicin linked with L-Val- L-Ala by an ester linkage. These were synthesized by esterification method, which included the reaction of -OH hydroxyl group on (carbon No.5) of gentamicin with the acid chloride of the corresponding dipeptide, The preparation of new derivative of gentamicin involved protected the primary & secondary amine groups of Gentamicin, by Ethylchloroformate (ECF) to give N-carbomethoxy Gentamicin which was used for further chemical synthesis involving the free hydroxyl groups.
Then prepared dipeptide (L-Val- L-Ala) by conventional solution method in present DCC & HoBt then reacted with thionyl
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Abstract
The research aims to determine the nature of the Iraqi market in terms of banking financial stability and the extent impact of the operational efficiency on it, Accordingly, chosen 15 relational banks were chosen as an intentional sample that could represent the Iraqi banking system for the period 2010-2020. The operational efficiency variable was measured according to the data envelope model, and banking financial stability used CAMELS model which includes five indicators (capital adequacy, asset quality, management quality, profitability, and liquidity), so for testing the research hypotheses used the random regression model by adopting the S
... Show MoreBackground: The ideal maxillofacial prosthesis should have fine and thin boundaries that bindwith the surrounding facial structures and possess high tear strength.This study aims to determinethe best percentages of nanofiller (TiO2) and intrinsic pigment (silicone functional intrinsic) thatcould be mixed in as additives to improve the tear strength of Cosmesil M511 andVST50F siliconeelastomers with the least effect on their hardness.Materials and Methods: In this in vitro experimental study, a total of 80 samples, 40 for eachelastomer, were fabricated. Each elastomer sample was split into two equal groups to test for tearstrength and Shore A hardness. Each group consisted of 20 samples, including 10 control sampleswithout additives and 10 e
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The current work reports a new Schiff base [N1-benzylidenebenezene-1,2-diamine(L) = C20H16N2] has been synthesized from benzaldehyde (C6H5CHO) and O- aminoaniline (O-C6H4(NH2)2. Metal mixed ligand complexes of the Schiff base were prepared from chloride salts of Zn(II), Cd(II) and Hg(II) in ethanol and 8-hydroxyquinoline(8HQ)(C9H7NO) containing sodium hydroxide. All the complexes were characterized on the basis of their; FT-IR and U.V spectra, melting point, molar conductance, and determination of the percentage of the metal in the complexes by flame (AAS). In the all complexes, (8HQ) behaves as a bidentate ligand as primary ligand through –-OH phenolic group and –N groups of pyridine group. Also, the prepared ligand (L) was bidentate i
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