The Paleocene benthic foraminiferal zonation of the Umm Er Rhadhuma Formation from the borehole (K.H 12/7), South Anah City (Western Iraq), has been re-studied and re-analyzed precisely based on the large benthic foraminifera (LBF). They are represented by two biozone Rotorbinella hensoni Partial Range Zone, recorded from the Lower and middle parts of the Umm Er Rhadhuma Formation and Lockhartia praehaimei Partial Range Zone determined Uppermost of this unit, and dated to be the Selandian – Thanetian stage. Almost all the biogenic (micro and macro) and non-biogenic constituents, including large benthic foraminifera, Algae, Echinoderm, Bryozoans, Oyster, Gastropod fragments, and peloids, in addition to lithofacies types, indicate that this succession belongs to the Umm Er Rhadhuma Formation. Furthermore, the Paleocene shallowing upwards succession is recognized from seven identified microfacies (MF1 to MF7), which suggests three significant facies associations. A broad inner ramp represents them and is warm shallow open normal marine water (FA1). In contrast, the second facies association represents by the predominated bioclastic sand shoal facies association (FA2) and finally reaches the semi-restricted lagoon facies associations (FA3). The interaction between the local tectonic disturbance along Rutba high and eustatic sea level mainly controls the development of two sequence boundaries of Type-1 (SB1) that occurred respectively at the Cretaceous /Palaeogene K- Pg boundary and Paleocene /Eocene boundary. The Paleocene depositional system starts with major transgression during the Selandian above a sequence boundary of type one (SB.1), that separates the Late Cretaceous (Maastrichtian) successions of the Tayarat Formation from the overlying Paleocene succession with a significant gap, covering the whole Danian age (That is the top of Tectonic Megasequence AP. 9). The predominance of retrogradation staking tract indicated the transgressive system tract during the late Selandian and early Thanetian as a result of an increase in the sea level rise and expanded accommodation space. The highstand system tracts show aggradational and then change to a progradational stacking pattern by the end of the Thanetian and mark significant sea level drawdown with a new sequence boundary of type one between them.
The effect of thickness variation on some physical properties of hematite α-Fe2O3 thin films was investigated. An Fe2O3 bulk in the form of pellet was prepared by cold pressing of Fe2O3 powder with subsequent sintering at 800 . Thin films with various thicknesses were obtained on glass substrates by pulsed laser deposition technique. The films properties were characterized by XRD, and FT-IR. The deposited iron oxide thin films showed a single hematite phase with polycrystalline rhombohedral crystal structure .The thickness of films were estimated by using spectrometer to be (185-232) nm. Using Debye Scherrerś formula, the average grain size for the samples was found to be (18-32) nm. Atomic force microscopy indicated that the films had
... Show MoreThe reaction oisolated and characterized by elemental analysis (C,H,N) , 1H-NMR, mass spectra and Fourier transform (Ft-IR). The reaction of the (L-AZD) with: [VO(II), Cr(III), Mn(II), Co(II), Ni(II), Cu(II), Zn(II), Cd(II) and Hg(II)], has been investigated and was isolated as tri nuclear cluster and characterized by: Ft-IR, U. v- Visible, electrical conductivity, magnetic susceptibilities at 25 Co, atomic absorption and molar ratio. Spectroscopic evidence showed that the binding of metal ions were through azide and carbonyl moieties resulting in a six- coordinating metal ions in [Cr (III), Mn (II), Co (II) and Ni (II)]. The Vo (II), Cu (II), Zn (II), Cd (II) and Hg (II) were coordinated through azide group only forming square pyramidal
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