doi:10.21123/bsj.2023.7039

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Publication Date

Tue Aug 01 2023

Journal Name

Baghdad Science Journal

Volume

20

Issue Number

4

DOI

10.21123/bsj.2023.7039

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The Classical Continuous Optimal Control for Quaternary Nonlinear Parabolic Boundary Value Problems

Classical Optimal Control

Cost Function

Galerkin Method

Lipschitz continuity

Parabolic Boundary Value Problems.

jamil Amir

Wissam A. Abdul-Hussien

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In this paper, our purpose is to study the classical continuous optimal control (CCOC) for quaternary nonlinear parabolic boundary value problems (QNLPBVPs). The existence and uniqueness theorem (EUTh) for the quaternary state vector solution (QSVS) of the weak form (WF) for the QNLPBVPs with a given quaternary classical continuous control vector (QCCCV) is stated and proved via the Galerkin Method (GM) and the first compactness theorem under suitable assumptions(ASSUMS). Furthermore, the continuity operator for the existence theorem of a QCCCV dominated by the QNLPBVPs is stated and proved under suitable conditions.

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Publication Date

Tue Oct 02 2018

Journal Name

Iraqi Journal Of Physics

Study of effect acidic solution (HCl) and (EP/Al2O3 & EP/ TiO2) hybrid on thermal conductivity of epoxy resin.

This research studies the effect of adding micro

nano and hybrid by ratio (1:1) of (Al2O3

TiO2) to epoxy resin on thermal conductivity before and after immersion in HCl acid for (14 day) with normality (0.3 N) at weight fraction (0.02

0.04

0.06

0.08) and thickness (6mm). The results of thermal conductivity reveled that epoxy reinforced by (Al2O3) and mixture (TiO2 Al2O3) increases with increasing the weight fraction

but the thermal conductivity (k) a values for micro and Nano (TiO2) decrease with increasing the weight fraction of reinforced

while the immersion in acidic solution (HCl) that the (k) values after immersion more than the value in before immersion.

Abdul Adeem Zaily

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This research studies the effect of adding micro, nano and hybrid by ratio (1:1) of (Al2O3,TiO2) to epoxy resin on thermal conductivity before and after immersion in HCl acid for (14 day) with normality (0.3 N) at weight fraction (0.02, 0.04, 0.06, 0.08) and thickness (6mm). The results of thermal conductivity reveled that epoxy reinforced by (Al2O3) and mixture (TiO2+Al2O3) increases with increasing the weight fraction, but the thermal conductivity (k) a values for micro and Nano (TiO2) decrease with increasing the weight fraction of reinforced, while the immersion in acidic solution (HCl) that the (k) values after immersion more than the value in before immersion.

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(1)

Publication Date

Fri Mar 01 2019

Journal Name

Applied Acoustics

Theoretical model of absorption coefficient of an inhomogeneous MPP absorber with multi-cavity depths

Micro-perforated panel (MPP) absorber has been known as an alternative absorber to classical porous material given its facile installation

long durability

environmental friendliness and attractive appearance. Extensive studies of MPP absorber proposing the improvement of its absorption frequency bandwidth have been published. This study presents a MPP absorber introduced with inhomogeneous perforations and with multi-cavity depths. The MPP is divided into two sub-area

where each area has different hole diameter

perforation ratio and a separated backed cavity depth. The acoustic impedance is modelled using electrical equivalent circuit and the absorption coefficient is calculated under normal-incidence of sound. It is found that the inhomogeneous MPP can have good bandwidth of absorption by designing the sub-MPP of smaller perforation ratio with large hole diameter and the one having the larger perforation ratio with smaller hole diameter. The absorption bandwidth can be conveniently controlled by adjusting the cavity depth of each sub-MPP. The results from the experimental work show good agreement with the theoretical model.

Ali Ibrahim

Azma

Roszaidi

Iwan

Al-Ameri

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(72)

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Publication Date

Sat Oct 01 2022

Journal Name

Environmental Advances

Stability and performance studies of emulsion liquid membrane on pesticides removal using mixture of Fe3O4Â nanoparticles and span80

The current study investigated the impact of nonionic surfactant span 80 in the existence of Fe3O4 magnetic nanoparticles on the emulsification of mixture of kerosene as petroleum based organic solvents and corn oil as a green diluent in the ratio 1:1

HCl was used as internal phase and the stability of the emulsion was carried out. The proposed Pickering emulsion liquid membrane has been exploited to investigate it is ability in the extraction of Abamectin pesticides from aqueous solution without utilizing carrier agent. Further

the effects of experimental parameters on extraction efficiency and emulsion stability such as

homogenizer speed

emulsification speed

contact time

Fe3O4-Span 80 ratios

HCL concentration

internal to membrane volume ratio (I/O) and pH of the external feed solution were carried out. The results showed that more than 99% of Abamectin could be extracted at 10 min contact time with a minimum breakage percent of 0.52% at the optimal conditions. The kinetic of the extraction were studied and the mass transfer coefficient was found to be for external phase () of 1.2

interfacial reaction rate constant () of 5.83 and the overall mass transfer coefficient () of 3.91 . The results of recyclability of the PELM revealed that the emulsion stability and extraction efficiency was nearly unchanged after three cycles.

Ahmed A.

Noor Q.

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(12)

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Publication Date

Sun Dec 07 2014

Journal Name

Baghdad Science Journal

Synthesis, Characterization and Stability Study of V(IV), Zr(IV), Rh(III), Pd(II), Cd(II) and Hg(II) Complexes with Pyrazol Derivative

In this work lactone (1) was prepared from the reaction of p-nitro phenyl hydrazine with ethylacetoacetate

which upon treatment with benzoyl chloride afforded the lactame (2). The reaction of (2) with 2-amino phenol produced a new Schiff base (L) in good yield. Complexes of V(IV)

Zr(IV)

Rh(III)

Pd(II)

Cd(II) and Hg(II) with the new Schiff base (L) have been prepared. The compounds (1

2) were characterized by FT-IR and UV spectroscopy

as well as characterizing ligand (L) by the same techniques with elemental analysis (C.H.N) and (1H-NMR). The prepared complexes were identified and their structural geometries were suggested by using elemental analysis (C.H.N)

flame atomic absorption technique

FT-IR and UV-Vis spectroscopy

in addition to magnetic susceptibility and conductivity measurements. Metal to ligand [M:L] ratio was obtained for all complexes in ethanol using molar ratio method

which gave comparable results with those obtained for the solid complexes. As well as the appa

Sinan M.

Enaam M.

Maysoon A

Sarab M

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In this work lactone (1) was prepared from the reaction of p-nitro phenyl hydrazine with ethylacetoacetate, which upon treatment with benzoyl chloride afforded the lactame (2). The reaction of (2) with 2-amino phenol produced a new Schiff base (L) in good yield. Complexes of V(IV), Zr(IV), Rh(III), Pd(II), Cd(II) and Hg(II) with the new Schiff base (L) have been prepared. The compounds (1, 2) were characterized by FT-IR and UV spectroscopy, as well as characterizing ligand (L) by the same techniques with elemental analysis (C.H.N) and (1H-NMR). The prepared complexes were identified and their structural geometries were suggested by using elemental analysis (C.H.N), flame atomic absorption technique, FT-IR and UV-Vis spectroscopy, in additio

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Publication Date

Sat Sep 01 2018

Journal Name

Polyhedron

Novel dichloro (bis {2-[1-(4-methylphenyl)-1H-1, 2, 3-triazol-4-yl-κN3] pyridine-κN}) metal (II) coordination compounds of seven transition metals (Mn, Fe, Co, Ni, Cu, Zn and Cd)

The 1

3-dipolar cycloaddition “click” reaction between an azide and an alkyne to give a 1

2

3-triazole was reported by Huisgen in 1961 [1]. In 2002 the Copper(I)-catalyzed Azide-Alkyne Cycloaddition (CuAAC) to prepare a 1

2

3-triazole was reported [2]

[3]. The existence of relatively basic nitrogen atoms in the 1

2

3-triazole rings

and the possibility of introducing additional donor groups in the substituents (Fig. 1)

made the CuAAC “click” reaction an attractive method to prepare differently substituted 1

2

3-triazoles. These compounds have been used as ligands to coordinate to various metal ions that display a range of applications such as in electrochemical and photochemical studies

in supramolecular chemistry

magnetism

metal-ion sensing and catalysis [4]. The reasons for the success of the “click” reaction

is that it is easy to carry out and is widely applicable. It is not affected by a variety of functional groups

and can be carried out with a variety of Cu(I) catalysts and solvents

including aqueous conditions. The Cu(I) catalysts overcome the high activation energy barrier of the non-catalyzed Huisgen reaction by changing the mechanism of the reaction. A large variety of copper catalysts can be used for the CuAAC reaction

on condition that the maximum concentration of Cu(I) species is generated during the reaction. The pre-catalyst can be a Cu(II) salt (usually CuSO4) together with a reducing agent (often sodium ascorbate) or a Cu(I) compound in the presence of a base or amine ligand and a reducing agent to prevent oxidation to Cu(II). Some strong oxidising cupric salts or complexes such as Cu(OAc)2 also work. The solvent is very flexible from organic to aqueous

with the most commonly used combination water + an alcohol (t-BuOH

MeOH or EtOH). The key role of the solvent or solvent mixture is to solubilize the substrates and Cu(I) catalyst in order to ensure rapid reactions. Such aqueous conditions are very useful for biochemical conjugations

as well as for organic syntheses. We recently reported on the synthesis of a series of differently substituted 1

2

3-triazole chromophores

the substituted 2-(1-phenyl-1H-1

2

3-triazol-4-yl)pyridine ligands [5]

see Fig. 2 middle

with substituents R = H (L1)

CH3 (L2)

OCH3 (L3)

COOH

F

Cl

CN

CF3

O(CH2)3CH3 and N(CH3)2. These versatile ligands were found to coordinate to various first row transition metals

such as manganese

cobalt and nickel [6]. Here we extend the series to include more first row transition metal(II) coordination compounds

iron

copper and zinc

as well as a second row transition metal(II) coordination compound

cadmium

containing the 2-(1-(4-methyl-phenyl)-1H-1

2

3-triazol-1-yl)pyridine chromophore (Fig. 2 right with R = CH3). This series of seven novel coordination compounds is the first series of pyridyl-triazole based transition metal coordination compounds where seven different transition metals are coordinated to the same 1

2

3-triazole chromophore

namely 2-(1-(4-methyl-phenyl)-1H-1

2

3-triazol-1-yl)pyridine.

Kinaan M

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