The reaction oisolated and characterized by elemental analysis (C,H,N) , 1H-NMR, mass spectra and Fourier transform (Ft-IR). The reaction of the (L-AZD) with: [VO(II), Cr(III), Mn(II), Co(II), Ni(II), Cu(II), Zn(II), Cd(II) and Hg(II)], has been investigated and was isolated as tri nuclear cluster and characterized by: Ft-IR, U. v- Visible, electrical conductivity, magnetic susceptibilities at 25 Co, atomic absorption and molar ratio. Spectroscopic evidence showed that the binding of metal ions were through azide and carbonyl moieties resulting in a six- coordinating metal ions in [Cr (III), Mn (II), Co (II) and Ni (II)]. The Vo (II), Cu (II), Zn (II), Cd (II) and Hg (II) were coordinated through azide group only forming square pyramidal

    Suppose that A be an abelain ring with identity, B be a unitary (left) A-module, in this paper ,we introduce a type of modules ,namely Quasi-semiprime A-module, whenever   is a Prime Ideal For proper submodule N of  B,then B is called Quasi-semiprime module ,which is a Generalization of Quasi-Prime A-module,whenever  ann_AN is a prime ideal for proper submodule N of B,then B is Quasi-prime module .A comprchensive study of these modules is given,and we study the Relationship between quasi-semiprime module and quasi-prime .We put the codition coprime over cosemiprime ring for the two cocept quasi-prime module and quasi-semiprime module are equavelant.and the cocept of  prime module and quasi

In this paper, we introduce and study a new concept (up to our knowledge) named CL-duo modules, which is bigger than that of duo modules, and smaller than weak duo module which is given by Ozcan and Harmanci. Several properties are investigated. Also we consider some characterizations of CL-duo modules. Moreover, many relationships are given for this class of modules with other related classes of modules such as weak duo modules, P-duo modules.

     Let R be a commutative ring with unity and an R-submodule N is called semimaximal if and only if

 the sufficient conditions of F-submodules to be semimaximal .Also the concepts of (simple , semisimple) F- submodules and quotient F- modules are  introduced and given some  properties .