Electrical Properties of Preparing Biodegradable Polymer Blends of PVA/Starch Doping with Rhodamine –B

Zainab J.  Sweah; Fatima hameed Malik; Alyaa  Abdul Karem

doi:10.21123/bsj.2021.18.1.0097

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Publication Date

Wed Mar 10 2021

Journal Name

Baghdad Science Journal

Volume

18

Issue Number

1

DOI

10.21123/bsj.2021.18.1.0097

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Electrical Properties of Preparing Biodegradable Polymer Blends of PVA/Starch Doping with Rhodamine –B

PVA

starch

biodegradable polymers

and electrical conductivity.

Zainab J. Sweah

Fatima hameed Malik

Alyaa Abdul Karem

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This research focuses on the characteristics of polyvinyl alcohol and starch polymer blends doping with Rhodamine-B. The polymer blends were prepared using the solution cast method, which comprises 1:1(wt. /wt.). The polymer blends of PVA and starch with had different ratios of glycerin 0, 25, 30, 35, and 40 % wt. The ratio of 30% wt of glycerin was found to be the most suitable mechanical properties by strength and elasticity. The polymer blend of 1:1 wt ratios of starch/PVA and 30% wt of glycerin were doped with different ratios of Rhoda mine-B dye 0, 1, 2, 3, 4, 5, and 6% wt and the electrical properties of doping biodegradable blends were studied. The ratio of Rhodamine-B 5% wt to the polymer blends showed high conductivity up to 1×10^-3. In general, the electrical conductivity was increased with high temperature, which is similar to the behavior of semi-conductive polymers.

This work focuses on the characteristics of polymer blend based on starch and polyvinyl alcohol doping with Rhodamine-B. the polymer blends were prepared using the solution cast method, which comprising 1:1(wt./wt.). ratio starch and polyvinyl alcohol and different ratio of glycerin (0, 25, 30, 35,and 40) %. The ratio of 30% of glycerin was found to be the most suitable mechanical properties. The polymer blend of 1:1 starch/PVA and 30%of glycerin were doped with different ratio of Rhoda mine-B dye (0, 1, 2, 3, 4, 5, and 6%) and the electrical properties of doping biodegradable blends were studied. The ratio of Rhodamine-B 5% to the polymer blends was high conductivity up to 1×10^-3. In general, the electrical conductivity was increased with high temperature this is similar to the behavior of semi-conductive polymers.

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Suppression of Arabidopsis Mediator Subunit-Encoding MED18 Confers Broad Resistance Against DNA and RNA Viruses While MED25 Is Required for Virus Defense

Nasser K.

Layla J.

Edina

James

Emily

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Environmental Earth Sciences

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Euphrates River · Groundwater flow · Hydrochemistry · Iraq · Stable isotope

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Arid and semi-arid climates are critical for water security in sustainable river systems. The Euphrates River in western Iraq has been increasingly stressed by both geogenic and anthropogenic factors. This study analyzed hydro-geochemical processes, recharge dynamics, and groundwater flow modeling in western Iraq. Additionally, stable isotope tracing (δ¹⁸O, Cl⁻) integrated with hydro-chemical parameters was used to assess water quality and river-aquifer connectivity in both Syria and western Iraq. A total of 144 groundwater samples were collected annually across 12 stations in western Iraq. Surface water and groundwater data were collected from previous studies at 13 stations in Syria. Results revealed slightly alkaline freshwater con

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Publication Date

Sat Feb 07 2026

Journal Name

Journal Of Engineering And Applied Science

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Sat Sep 01 2018

Journal Name

Polyhedron

Novel dichloro (bis {2-[1-(4-methylphenyl)-1H-1, 2, 3-triazol-4-yl-κN3] pyridine-κN}) metal (II) coordination compounds of seven transition metals (Mn, Fe, Co, Ni, Cu, Zn and Cd)

The 1

3-dipolar cycloaddition “click” reaction between an azide and an alkyne to give a 1

2

3-triazole was reported by Huisgen in 1961 [1]. In 2002 the Copper(I)-catalyzed Azide-Alkyne Cycloaddition (CuAAC) to prepare a 1

2

3-triazole was reported [2]

[3]. The existence of relatively basic nitrogen atoms in the 1

2

3-triazole rings

and the possibility of introducing additional donor groups in the substituents (Fig. 1)

made the CuAAC “click” reaction an attractive method to prepare differently substituted 1

2

3-triazoles. These compounds have been used as ligands to coordinate to various metal ions that display a range of applications such as in electrochemical and photochemical studies

in supramolecular chemistry

magnetism

metal-ion sensing and catalysis [4]. The reasons for the success of the “click” reaction

is that it is easy to carry out and is widely applicable. It is not affected by a variety of functional groups

and can be carried out with a variety of Cu(I) catalysts and solvents

including aqueous conditions. The Cu(I) catalysts overcome the high activation energy barrier of the non-catalyzed Huisgen reaction by changing the mechanism of the reaction. A large variety of copper catalysts can be used for the CuAAC reaction

on condition that the maximum concentration of Cu(I) species is generated during the reaction. The pre-catalyst can be a Cu(II) salt (usually CuSO4) together with a reducing agent (often sodium ascorbate) or a Cu(I) compound in the presence of a base or amine ligand and a reducing agent to prevent oxidation to Cu(II). Some strong oxidising cupric salts or complexes such as Cu(OAc)2 also work. The solvent is very flexible from organic to aqueous

with the most commonly used combination water + an alcohol (t-BuOH

MeOH or EtOH). The key role of the solvent or solvent mixture is to solubilize the substrates and Cu(I) catalyst in order to ensure rapid reactions. Such aqueous conditions are very useful for biochemical conjugations

as well as for organic syntheses. We recently reported on the synthesis of a series of differently substituted 1

2

3-triazole chromophores

the substituted 2-(1-phenyl-1H-1

2

3-triazol-4-yl)pyridine ligands [5]

see Fig. 2 middle

with substituents R = H (L1)

CH3 (L2)

OCH3 (L3)

COOH

F

Cl

CN

CF3

O(CH2)3CH3 and N(CH3)2. These versatile ligands were found to coordinate to various first row transition metals

such as manganese

cobalt and nickel [6]. Here we extend the series to include more first row transition metal(II) coordination compounds

iron

copper and zinc

as well as a second row transition metal(II) coordination compound

cadmium

containing the 2-(1-(4-methyl-phenyl)-1H-1

2

3-triazol-1-yl)pyridine chromophore (Fig. 2 right with R = CH3). This series of seven novel coordination compounds is the first series of pyridyl-triazole based transition metal coordination compounds where seven different transition metals are coordinated to the same 1

2

3-triazole chromophore

namely 2-(1-(4-methyl-phenyl)-1H-1

2

3-triazol-1-yl)pyridine.

Kinaan M

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Publication Date

Tue Jan 18 2022

Journal Name

Materials Science Forum

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Gamma doses radiation

crystal size

strain

degree of crystallinity

Scherrer

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Balqees A.

Mohammed A.

Kareem A.

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Journal Name

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Journal Name

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