The experiment aimed to Manufacture a device for checking the nozzles and testing its efficiency and to study the effect of research factors on the studied traits. The device was manufactured locally through using materials available in the Iraqi market. The system is Both Hydraulic and electronic (ISO 5682-1)1 relay on sensors technology and the test platform was built and designed on a movable trolly at the department of Agricultural Machines and Equipment / College of Agricultural Science / University of Baghdad. The design includes the use of mechanical water pump and electrical AC water pump. The design includes a nozzle holder that can accommodate three nozzles per test. The design also consists of spreading wings and stationary wing that can accommodate 50 vessels and 50 ultra-sonic sensors. All that is controlled by a main control unit which consists of three branch modules (each one of them is responsible to collect and analyze data from several sensors on each of the wings. The idea behind the design is to merge between actual spraying and the use of electronic sensors to analyze the size of the sprayed liquid in each of the vessels, the concept of the design is based upon Volumetric distribution of the liquid. The concept of the device was based on using ultra sonic sensors to measure the volumetric distribution of liquids. The experiment aimed to determine the effects of these factors on flow rate, spraying angle, sprayed area, spraying swath, volumetric distribution (CV), and symmetry. The experiment was conducted at the college of Agricultural science, Baghdad University. The results showed that the spraying pressure had a non-significant effect on flow rate. However, increasing the pressure from 3.0 to 5.0 and then to 7.0 bar resulted in flow rates of 1.314, 1.286, and 1.36 l/m, respectively. The status of the nozzle (new or worn) did not significantly affect the flow rate, with new nozzles registering a slightly higher flow rate of 1.327 l/m compared to worn nozzles (1.312 l/m). On the other hand, the type of nozzle had a significant impact on flow rate, with plastic, brass, and steel nozzles registering flow rates of 1.243, 1.422, and 1.29 l/m, respectively. Regarding the spraying angle, the results indicated that the spraying pressure had a significant effect. Increasing the pressure from 3.0 to 5.0 and then to 7.0 bar resulted in spraying angles of 132, 132, and 136 degrees, respectively. The nozzle status significantly affected the spraying angle, with worn nozzles resulting in a higher angle of 137 degrees compared to new nozzles (130 degrees). However, the type of nozzle did not significantly affect the spraying angle. For the sprayed area, the spraying pressure had a significant effect, with higher pressures resulting in larger sprayed areas. Worn nozzles also significantly increased the sprayed area compared to new nozzles. The type of nozzle had a significant impact on the sprayed area, with plastic, brass, and steel nozzles resulting in areas of 70.4, 80.44, and 89.16 cm2, respectively. The experiment proved that nozzles must be tested periodically, otherwise they start to perform beyond the parameters they were designed to perform with.
New ligand of N-(pyrimidin-2-yl carbamothioyl)acetamide was synthesized and its complexes with (VO(II), Mn (II), Cu (II), Zn (II), Cd (II) and Hg (II) are formed with confirmation of their structures on the bases of spectroscopic analyses. Antimicrobial activity of new complexes are studied against Gram positive S. aureus and Gram negative E. coli, Proteus, Pseudomonas. The octahedral geometrical structures are proved depending on the outcomes from the preceding procedures
Two well-known fluorescent molecules: fluorescein sodium salt (FSS) and 2,7-dichloro fluorescein (DCF) were tried to prove the efficiency, trustability and repeatability of ISNAG fluorimeter by using discrete and continuous flow injection analysis modes.A linear range of 0.002-1 mmol/L for FSS and 0.003-0.7 mmol/L was for DCF, with LOD 0.0018 mmol/L and 0.002 mmol/L for FSS and DCF respectively, were obtained for discrete mode of analysis. While the continuous mode gave a linear range of 0.002-0.7 mmol/L and 0.003-0.5 mmol/L for FSS and DCF respectively, the LOD were 0.0016mmol/L and 0.0018 mmol/L for FSS and DCF respectively. The results were compared with classical method at variable λex for both fluorescent molecules at 95
... Show MoreThe research seeks to clarify the problems related to the aspects of the financial and accounting process resulting from entering into contractual arrangements with a period of more than 20 years, among which is the research problem represented by the lack of clarity of the foundations and procedures for the recognition of oil costs and additional costs borne by foreign invested companies, which led to a weakening of their credibility and reflection. Negatively "on the measurement and accounting disclosure of financial reports prepared by oil companies, and the research aims to lay down sound procedures for measuring and classifying oil costs and additional costs paid to foreign companies, and recognizing and recording them in th
... Show MoreNew Schiff base ligand (E)-6-(2-(4-(dimethylamino)benzylideneamino)-2-(4-hydroxyphenyl)acetamido)-3,3- dimethyl-7-oxo-4-thia-1- azabicyclo[3.2.0]heptane-2-carboxylic acid = (HL) was synthesized via condensation of Amoxicillin and 4(dimethylamino)benzaldehyde in methanol. Figure -1 Polydentate mixed ligand complexes were obtained from 1:1:2 molar ratio reactions with metal ions and HL, 2NA on reaction with MCl2 .nH2O salt yields complexes corresponding to the formulas [M(L)(NA)2Cl],where M=Fe(II),Co(II),Ni(II),Cu(II),and Zn(II), A=nicotinamide .
The effect of thickness variation on some physical properties of hematite α-Fe2O3 thin films was investigated. An Fe2O3 bulk in the form of pellet was prepared by cold pressing of Fe2O3 powder with subsequent sintering at 800 . Thin films with various thicknesses were obtained on glass substrates by pulsed laser deposition technique. The films properties were characterized by XRD, and FT-IR. The deposited iron oxide thin films showed a single hematite phase with polycrystalline rhombohedral crystal structure .The thickness of films were estimated by using spectrometer to be (185-232) nm. Using Debye Scherrerś formula, the average grain size for the samples was found to be (18-32) nm. Atomic force microscopy indicated that the films had
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... Show MoreEight different Dichloro(bis{2-[1-(4-R-phenyl)-1H-1,2,3-triazol-4-yl-κN3]pyridine-κN})iron(II) compounds, 2–9, have been synthesised and characterised, where group R=CH3 (L2), OCH3 (L3), COOH (L4), F (L5), Cl (L6), CN (L7), H (L8) and CF3 (L9). The single crystal X-ray structure was determined for the L3 which was complemented with Density Functional Theory calculations for all complexes. The structure exhibits a distorted octahedral geometry, with the two triazole ligands coordinated to the iron centre positioned in the equatorial plane and the two chloro atoms in the axial positions. The values of the FeII/III redox couple, observed at ca. −0.3 V versus Fc/ Fc+ for complexes 2–9, varied over a very small potential range of 0.05 V.
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