تم في هذا البحث تحضير وتشخيص تسعة معقدات مع الليكاند [N, N- Bis(2- hydroxy ethyl) Glycine] ومختصره (Bicine) وثمانية معقدات مع الليكاند [N- Tris(hydroxy Methyl) Methyl Glycine] ومختصره (Tricine) مع بعض الايونات الفلزية وقد جرى التفاعل على مرحلتين وكما ياتي:- أ. تحضير ملح البوتاسيوم لليكاندات وذلك من مفاعلة الليكاند مع هيدروكسيد البوتاسيوم وبنسب (1:1) (قاعدة: ليكاند) في محيط كحولي للحصول على ملح الليكاند. ب. وفي المرحلة الثانية: تم مفاعلة الملح الناتج مع املاح الفلزات المختارة للحصول على المعقدات المطلوبة. ولقد تم مفاعلة ملح الليكاند (Bic-k+) مع ايونات املاح العناصر الفلزية الاتية (Cd+2,Ag+,Pd+2, Zn+2,Cu+2, Ni+2, Co+2,Cr+3,VO+2), وكذلك مفاعلة ملح الليكاند (Tric-k+) مع كل من (Cd+2, Ag+, Zn+2, Cu+2, Ni+2, Co+2, Mn+2,Cr+3), للحصول على المعقدات المطلوبة. وقد درست هذه المعقدات بالطرائق الاتية:- أ. الدراسات الطيفية وتضمنت اطياف الاشعة تحت الحمراء والاشعة فوق البنفسجية- المرئية. ب. الامتصاص الذري. ج. التوصيلية المولارية وقابلية الذوبان. د. قياس الحساسية المغناطيسية. ه. استخدام طريقة النسب المولية وتعين ثوابت الاستقرارية لبعض المعقدات المحضرة. ومن هذه الدراسات التشخيصية اعلاه وبالمقارنة مع ما ورد في الادبيات من المعقدات المتشابهة اقترحت الصيغ التركيبية الاتية لمعقدات المحضرة: أ. المعقدات السداسية التناسق ذات الشكل الثماني السطوح ,إذ اعطت الصيغة العامة [M(Bicine)3] و [M(Tricine)3],إذ M تمثل ايون الكروم الثلاثي التكافؤ. ب. المعقدات الخماسية التناسق ذات الشكل الهرم المربع القاعدة (Square Pyramid) واعطيت لها الصيغة العامة[VO(Bicine)2]. ج. المعقدات الرباعية التناسق واعطيت لها الصيغة العامة:-.xH2O[M(Bicine)2] و .xH2O[M(Tricine)2] .
In this study, the acid-alkaline transesterification of refined coconut seed oil (RCOSO) to fatty acid methyl ester was followed by the production of a trimethylolpropane-based thermosensitive biolubricant using potassium hydroxide, and its physicochemical characteristics were evaluated. The American Standard Test for Materials (ASTM) was employed to ascertain the biolubricant's pour point and index of viscosity, which were found to be -4 oC and 283.75, respectively. The opposite connection between lubricant viscosity and temperature was shown by the measured viscosities at varied transesterification to be transformed into biodiesel. Following this, a biolubricant was created by further transesterifiedtemperature. The ester gr
... Show MoreThe necessary optimality conditions with Lagrange multipliers are studied and derived for a new class that includes the system of Caputo–Katugampola fractional derivatives to the optimal control problems with considering the end time free. The formula for the integral by parts has been proven for the left Caputo–Katugampola fractional derivative that contributes to the finding and deriving the necessary optimality conditions. Also, three special cases are obtained, including the study of the necessary optimality conditions when both the final time and the final state are fixed. According to convexity assumptions prove that necessary optimality conditions are sufficient optimality conditions.
... Show MoreThe main objectives of present study are to evaluate the trace elements pollution in the sediment of the Tigris River and drainage canals in Wasit Governorate, Iraq. Assessment of trace elements pollutants were conducted for 18 sediment samples collected in March 2017. Trace elements were analyzed in sediment Tigris River samples in Wasit Governorate. This metal pollution was evaluated using geo-accumulation (I-geo) index, Contamination Factor (CF) and Pollution Load Index (PLI). According to these statistical indices, the sediments collected from Tigris River in the study area are highly polluted with Titanium (71.9 ppm), Nickel (226.6 ppm) Chromium (425.2 ppm), Cadmium (2ppm) and Molybdenum (15.8 ppm) while the sediments&nb
... Show MoreThe analysis of time series considers one of the mathematical and statistical methods in explanation of the nature phenomena and its manner in a specific time period.
Because the studying of time series can get by building, analysis the models and then forecasting gives the priority for the practicing in different fields, therefore the identification and selection of the model is of great importance in spite of its difficulties.
The selection of a standard methods has the ability for estimation the errors in the estimated the parameters for the model, and there will be a balance between the suitability and the simplicity of the model.
In the analysis of d
... Show MoreThe study aimed to determine of some Optimum conditions for bioremediation and removing of seven mineral elements included hexavalent chromium, nickel, cobalt, cadmium, lead, iron and copper as either alone or in group by living and heat treated cells of baker’s yeast Saccharomyces cerevisiae. The dried baker's yeast from Aldnaamaya China Company was used in this study. Biochemical tests was used to ensure yeast belonging to S. cerevisiae and then used to remove the mentioned mineral elementes under different conditions which included incubation period, pH, and temperature. It was found that the best of these conditions was 60 minutes for duration of incubation, 6 for pH, 25 ᵒC for temperature. During the study the behavior of living
... Show Moreيتضمن البحث طرق تحضير والخواص الكيمائية لمشتقات حلقة 1,3,-4 اوكسادايازول المعوضة في الموقعين 2,5 . كما يتضمن كيفية تحضير بوليمرات بلورية سائلة من المركبات الحلقية غير المتجانسة لحلقة 1,3,-4 اوكسادايازول المعوضة والطرق الطيفية المستخدمة في تشخيص المركبات المحضرة.
In this work, we synthesized thirteen compounds of 1-(2-furoyl)thiourea derivatives 1-13 by conversion of 2-furoyl chloride to 2-furoyl isothiocyanate by reacting it with potassium thiocyanate in dry acetone in a quite short reflux time then, in the same pot, different of (primary and secondary amines) were added individually to achieve thiourea derivatives. The products were characterized spectroscopically using (FT-IR, 1H NMR and 13C NMR) techniques. Some of them were evaluated as antioxidant agents using DPPH radical scavenging method, and all were examined theoretically as enzyme inhibitors against Bacillus pasteurii urease (pdb id: 4ubp) and by studying molecular docking using Autodock (4.2.6) software.
New chelating ligand derived from triazole and its complexes with metal ions Rhodium, Platinum and Gold were synthesized. Through a copper (I)-catalyzed click reaction, the ligand produced 1,3-dipolar cycloaddition between 2,6-bis((prop-2-yn-1-yloxy) methyl) pyridine and 1-azidododecane. All structures of these new compounds were rigorously characterized in the solid state using spectroscopic techniques like: 1HNMR, 13CNMR, Uv-Vis, FTIR, metal and elemental analyses, magnetic susceptibility and conductivity measurements at room temperature, it was found that the ligand acts as a penta and tetradentate chelate through N3O2, N2O2, and the geometry of the new complex
... Show MoreIn this study, the preparation and characterization of hyacinth plant /chitosan composite, as a heavy metal removal, were done. Water hyacinth plant (Eichhorniacrasspes) was collected from Tigris river in Baghdad. The root and shoot parts of plant were ground to powder. Composite materials were prepared at different ratios of plant part (from 2.9% to 30.3%, wt /wt) which corresponds to (30-500mg) of hyacinth plant (root and shoot) and chitosan. The results showed that all examined ratios of plant parts have an excellent absorption to copper (Cu (II)). Moreover, it was observed that 2.9% corresponds (30mg) of plant root revealed highest removal (82.7%) of Pb (II), while 20.23% of shoot removed 61% of Cd (II) within 24 hr
... Show MoreThis paper describes a number of new interleaving strategies based on the golden section. The new interleavers are called golden relative prime interleavers, golden interleavers, and dithered golden interleavers. The latter two approaches involve sorting a real-valued vector derived from the golden section. Random and so-called “spread” interleavers are also considered. Turbo-code performance results are presented and compared for the various interleaving strategies. Of the interleavers considered, the dithered golden interleaver typically provides the best performance, especially for low code rates and large block sizes. The golden relative prime interleaver is shown to work surprisingly well for high puncture rates. These interleav
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