The Esterification kinetics of acetic acid with ethanol in the presence of sulfuric acid as a homogenous catalyst was studied with isothermal batch experiments at 50-60°C and at a different molar ratio of ethanol to acetic acid [EtOH/Ac]. Investigation of kinetics of the reaction indicated that the low of [EtOH/Ac] molar ratio is favored for esterification reaction, this is due to the reaction is catalyzed by acid. The maximum conversion, approximately 80% was obtained at 60°C for molar ratio of 10 EtOH/Ac. It was found that increasing temperature of the reaction, increases the rate constant and conversion at a certain mole ratio, that is due to the esterification is exothermic. Activity coefficients were calculated using UNIFAC program. Results showed deviation in activation energy in the non-ideal system of about 20% this is due to the polarities of water and ethanol compared to the non-polar ethyl acetate this dissimilarity leading to strong non- ideal behavior. The homogenous reaction has been described with simple power-law model. The chemical equilibrium combustion calculated form the kinetic model in agreement with the measured chemical equilibrium.
لم تعد اللغة مجرد أداة للتعبير عما يفكر به المتكلمون، إذ تعدت ذلك إلى أن تكون سبيلاً في صناعة العالم على وفق مقاربة تداولية، وقف عليها علماء البحث اللساني من أمثال أوستن و هرسل، للكشف عما وراء اللغة، وما يقصده المتكلمون، والبحث عن أفعال الكلام التي يسعى المتحدثون الى استعمالها، ولذلك اتجهت هذه الدراسة للوقوف على شعر عصر صدر الإسلام، واجراء دراسة تداولية لاستكشاف الأفعال التي كثيرا ما استعملها شعراء الإسلام
... Show Moreعلى وفق ستراتيجية توظيف الامكانيات الاسلوبية والفنية والجمالية للحوار بنوعيه( الحوار الداخلي ) و( الحوار الخارجي ) استطاعت الكاتبة ان تمنح روايتها ( ذاكرة الجسد ) خصوصيتها الادبية .فعلى مستوى الوظيفة البنائية اسهم الحوار في التشكيل الزمني لبناء الرواية ،وتقديم الشخصية ،وبناء الحدث وتطويره .وعلى المستوى الاسلوبي نجد أن الحوار تجاوز وظيفته الاخبارية الى وظيفة التأثير في المتلقي من خلال الافادة من معطيات المسر
... Show MoreThe concept of poetics has different dimensions, part of which is related to the creative achievement, and part is related to the critical perspective.
The main target of this research is to follow the stages of the emergence of
the idea of republican form of government from its very beginning , yet there
were many elements from different estates thinker , educated , few of heads of
clans . This first opportunity for the mobilization of politically-minded people
with fundamental activity like najei shokat . hussain al-rahal notable poet maruf
al-rasafi those who formed what so called the political elite who believed in
constitutional , democratic parliamentary republic , one of them was al-rahal who
called for a constitutional republic even before the emergence of the
constitutional movement in Iran and ottoman empire (1908).
The holy najaf become cultural cen
This study deals with The Millstone (1965) which is a dramatic depiction of a single
mother heroine in a classic predicament. This novel is considered as representative of the age
in which it was written. The primary theme is her intense preoccupation with questions of
fatalism and will. The work also involves, both explicitly and implicitly, feminist concerns.
Because the central protagonist is a woman and the society in which she lives is depicted,
accurately, as deeply patriarchal and class-bound, the problem of the individual's capacity for
self-determination is inevitably tied to the feminist perspective.
Each poem has its own theme; each subject has its own specificity. The theme of sadness has an effect on the soul. Its privacy has become a condition that is affected by all those who have experienced this painful
التنظيم القانوني للمهني – دراسة مقارنة في نطاق الاعمال التجارية