Spectral Study of Pt (II), Cr (II) Polymeric Complexes of the Ligand  N- Crotonyl -2- Hydroxy-Phenylazomethine

Alyaa Esam Mahdi

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Publication Date

Tue Dec 31 2013

Journal Name

Al-khwarizmi Engineering Journal

Volume

9

Issue Number

4

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Spectral Study of Pt (II), Cr (II) Polymeric Complexes of the Ligand N- Crotonyl -2- Hydroxy-Phenylazomethine

Schiff Base

Polymeric Complexes

Spectroscopic Methods

Divalent Metals

Alyaa Esam Mahdi

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The polymeric complexes were obtained from the reaction of polymeric Schiff base.N-crotonyl-2-hydroxyphenylazomethine (HL), with divalent metals Pt (II), Cr (II). The modes of bonding and overall geometry of the complexes were determine through spectroscopic methods and compared with that reported from analogous monomeric ligand. This study revealed square planer geometry around the metal center for [Pt(L)Cl] and distorted octahedral geometry for Cr complex [Cr(L)Cl(H₂O)₂].

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Preparation, kinetics, and thermodynamic investigation of Janus green dye removal from aqueous solutions using MnO2 nanoparticles as an adsorbent

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Corrosion inhibition Heterocyclic rings Corrosion cell Polarization curve

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