The improvement of the mechanical soil characteristics of jet grouting technique is very attractive. The jet grouted soil cement columns in soft is a complicated issue because it depends on a number of factors such as, soil nature, mixture, influence among soil and grouting materials, jetting force of nozzle, jet grouting and water flow rate, rotation and lifting speed. This paper discusses the estimation of shear strength parameters of soil-cement column (soilcrete) in soft clayey soil based on the relationships between the unconfined compressive and split tensile strength for the soilcrete and the effect of the jet grouting and water pressure in the values of cohesion and internal friction. For this reason, theoretical and field work models have been developed. The relation between split tensile and unconfined compressive strength results were used to draw a Mohr’s circle and failure enveloped to define the shear strength parameters of soilcrete. According to that, the results indicate that the resistance of the jet grout columns increases by increasing the nominal resistance of the grouting material (cement), water and jet grouting pressure. The shear resistance variables are increased by increasing the unconfined compressive and tensile strength of the jetting column. The value of the unconfined compressive strength ranges from (2.78-5.52 MPa). While the internal friction angle varies from 38° to 44°. On the other hand, the tensile strength is increased by increasing the unconfined compressive strength and ranges from (0.66-1.02 MPa).
The reaction oisolated and characterized by elemental analysis (C,H,N) , 1H-NMR, mass spectra and Fourier transform (Ft-IR). The reaction of the (L-AZD) with: [VO(II), Cr(III), Mn(II), Co(II), Ni(II), Cu(II), Zn(II), Cd(II) and Hg(II)], has been investigated and was isolated as tri nuclear cluster and characterized by: Ft-IR, U. v- Visible, electrical conductivity, magnetic susceptibilities at 25 Co, atomic absorption and molar ratio. Spectroscopic evidence showed that the binding of metal ions were through azide and carbonyl moieties resulting in a six- coordinating metal ions in [Cr (III), Mn (II), Co (II) and Ni (II)]. The Vo (II), Cu (II), Zn (II), Cd (II) and Hg (II) were coordinated through azide group only forming square pyramidal
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