The improvement of the mechanical soil characteristics of jet grouting technique is very attractive. The jet grouted soil cement columns in soft is a complicated issue because it depends on a number of factors such as, soil nature, mixture, influence among soil and grouting materials, jetting force of nozzle, jet grouting and water flow rate, rotation and lifting speed. This paper discusses the estimation of shear strength parameters of soil-cement column (soilcrete) in soft clayey soil based on the relationships between the unconfined compressive and split tensile strength for the soilcrete and the effect of the jet grouting and water pressure in the values of cohesion and internal friction. For this reason, theoretical and field work models have been developed. The relation between split tensile and unconfined compressive strength results were used to draw a Mohr’s circle and failure enveloped to define the shear strength parameters of soilcrete. According to that, the results indicate that the resistance of the jet grout columns increases by increasing the nominal resistance of the grouting material (cement), water and jet grouting pressure. The shear resistance variables are increased by increasing the unconfined compressive and tensile strength of the jetting column. The value of the unconfined compressive strength ranges from (2.78-5.52 MPa). While the internal friction angle varies from 38° to 44°. On the other hand, the tensile strength is increased by increasing the unconfined compressive strength and ranges from (0.66-1.02 MPa).
Two simple methods for the determination of eugenol were developed. The first depends on the oxidative coupling of eugenol with p-amino-N,N-dimethylaniline (PADA) in the presence of K3[Fe(CN)6]. A linear regression calibration plot for eugenol was constructed at 600 nm, within a concentration range of 0.25-2.50 μg.mL–1 and a correlation coefficient (r) value of 0.9988. The limits of detection (LOD) and quantitation (LOQ) were 0.086 and 0.284 μg.mL–1, respectively. The second method is based on the dispersive liquid-liquid microextraction of the derivatized oxidative coupling product of eugenol with PADA. Under the optimized extraction procedure, the extracted colored product was determined spectrophotometrically at 618 nm. A l
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