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A new ligand (H4L) and its complexes with ( ZnII, CdII and HgII) were prepared. This ligand
was prepared in two steps. In the first step a solution of terephthaldehyde in methanol was reacted
under reflux with 1,2-phenylenediamine to give an precursor compound which reacted in the
second step with 2,4-dihydroxybenzaldehyde to give the ligand. The complexes were then
synthesized by direct reaction of the corresponding metal chloride with the ligand. The ligand and
complexes were characterized by spectroscopic methods FT-IR, UV-Vis, 1
HNMR, and atomic
absorption, chloride content, HPLC, mole-ratio determination. in addition to conductivity
measurement. The data of these measurements suggest a distorted tetrahedral geometry for ZnII,
C
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