Azo-Schiff base ligand
Vanadyl complexes
Kinetics thermodynamic
parameters and bacterial
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Azo-Schiff base compounds (L1 and L2) have been synthesized from the reaction of
m-hydroxy benzoic acid with 1,5-dimethyl-3-[2-(5-methyl-1H-indol-3-yl)-ethylimino]-2-phenyl-2,3-
dihydro-1H-pyrazol-4-ylamine and with 3-[2-(1H-indol-3-yl)-ethylimino]-1,5-dimethyl-2-phenyl-
2,3-dihydro-1H-pyrazol-4-ylamine. The free ligands and their complexes were characterized based
on elemental analysis, determination of metal, molar conductivity, (1H, 13C) NMR, UV–vis, FT-IR,
mass spectra and thermal analysis (TGA). The molar conductance data revealed that all the complexes are non-electrolytes. The study of complex formation via molar ratio in DMF solution has
been investigated and results were consistent to those found in the solid complexes with a rat
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