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Planktonic Foraminiferal Biostratigraphy of the Late Cretaceous (Kometan–Shiranish formations) Boundary at Sarchinar and Goizha Sections, Northeastern Iraq
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This study investigates the boundary between the Upper Cretaceous Kometan (Turonian–Campanian) and Shiranish (Late Campanian–Maastrichtian) formations at the Sarchinar and Goizha surface sections in the Sulaymaniyah area, northeastern Iraq, in order to refine their biostratigraphic framework and reconstruct the depositional evolution across the formation boundary. The two formations are characterized by thin- to medium-bedded chalky and marly limestones overlain by blue to grey marls and marly limestones, which record a transition from outer-shelf to upper-bathyal ramp carbonates into deeper hemipelagic basinal deposits within the Zagros fold–thrust belt. A total of 100 rock samples were collected from the exposed successions and were prepared either as washed residues or standard thin sections, allowing for integrated analysis of planktonic foraminifera and microfacies. Planktonic foraminiferal biostratigraphy identifies five biozones within the Kometan and lower Shiranish formations: the Dicarinella primitiva Interval Zone, Dicarinella concavata Interval Zone, Dicarinella asymmetrica Total Range Zone, Globotruncanita elevata Total Range Zone in the uppermost Kometan, and the overlying Globotruncana aegyptiaca Interval Zone at the base of the Shiranish. The absence of the intervening Globotruncana ventricosa and Globotruncanella havanensis zones suggests a short intra-Campanian hiatus or condensed section at the Kometan–Shiranish transition. The combined stratigraphic and biostratigraphic data demonstrate that the contact is generally unconformable in the studied sections, thus providing a key reference for constraining the Late Cretaceous tectono-stratigraphic evolution of the northeastern Arabian Plate margin in Iraq.

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Publication Date
Thu Nov 19 2020
Journal Name
Indonesian Journal Of Chemistry
Determination of Eugenol in Personal-Care Products by Dispersive Liquid-Liquid Microextraction Followed by Spectrophotometry Using <i>p</i>-Amino-<i>N,N</i>-dimethylaniline as a Derivatizing Agent
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Two simple methods for the determination of eugenol were developed. The first depends on the oxidative coupling of eugenol with p-amino-N,N-dimethylaniline (PADA) in the presence of K3[Fe(CN)6]. A linear regression calibration plot for eugenol was constructed at 600 nm, within a concentration range of 0.25-2.50 μg.mL–1 and a correlation coefficient (r) value of 0.9988. The limits of detection (LOD) and quantitation (LOQ) were 0.086 and 0.284 μg.mL–1, respectively. The second method is based on the dispersive liquid-liquid microextraction of the derivatized oxidative coupling product of eugenol with PADA. Under the optimized extraction procedure, the extracted colored product was determined spectrophotometrically at 618 nm. A l

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