Factors affecting gel strength design for conformance control: An integrated investigation

Dheiaa Alfarge; Ahmed M. Aljarah; Mingzhen Wei; Baojun Bai; Najeh Alali; Abdul-Hussain Al-Shibly; Usama Alameedy

doi:https://doi.org/10.1016/j.petrol.2021.108711

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Publication Date

Wed Sep 01 2021

Journal Name

Journal Of Petroleum Science And Engineering

Volume

204

DOI

https://doi.org/10.1016/j.petrol.2021.108711

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Factors affecting gel strength design for conformance control: An integrated investigation

Conformance control

Gel treatment

Water production in oil wells

Water flooding

Numerical simulation

Enhanced oil recovery

Dheiaa Alfarge

Ahmed M. Aljarah

Mingzhen Wei

Baojun Bai

Najeh Alali

Abdul-Hussain Al-Shibly

Usama Alameedy

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Publication Date

Sat Sep 01 2018

Journal Name

Polyhedron

Novel dichloro (bis {2-[1-(4-methylphenyl)-1H-1, 2, 3-triazol-4-yl-κN3] pyridine-κN}) metal (II) coordination compounds of seven transition metals (Mn, Fe, Co, Ni, Cu, Zn and Cd)

The 1

3-dipolar cycloaddition “click” reaction between an azide and an alkyne to give a 1

2

3-triazole was reported by Huisgen in 1961 [1]. In 2002 the Copper(I)-catalyzed Azide-Alkyne Cycloaddition (CuAAC) to prepare a 1

2

3-triazole was reported [2]

[3]. The existence of relatively basic nitrogen atoms in the 1

2

3-triazole rings

and the possibility of introducing additional donor groups in the substituents (Fig. 1)

made the CuAAC “click” reaction an attractive method to prepare differently substituted 1

2

3-triazoles. These compounds have been used as ligands to coordinate to various metal ions that display a range of applications such as in electrochemical and photochemical studies

in supramolecular chemistry

magnetism

metal-ion sensing and catalysis [4]. The reasons for the success of the “click” reaction

is that it is easy to carry out and is widely applicable. It is not affected by a variety of functional groups

and can be carried out with a variety of Cu(I) catalysts and solvents

including aqueous conditions. The Cu(I) catalysts overcome the high activation energy barrier of the non-catalyzed Huisgen reaction by changing the mechanism of the reaction. A large variety of copper catalysts can be used for the CuAAC reaction

on condition that the maximum concentration of Cu(I) species is generated during the reaction. The pre-catalyst can be a Cu(II) salt (usually CuSO4) together with a reducing agent (often sodium ascorbate) or a Cu(I) compound in the presence of a base or amine ligand and a reducing agent to prevent oxidation to Cu(II). Some strong oxidising cupric salts or complexes such as Cu(OAc)2 also work. The solvent is very flexible from organic to aqueous

with the most commonly used combination water + an alcohol (t-BuOH

MeOH or EtOH). The key role of the solvent or solvent mixture is to solubilize the substrates and Cu(I) catalyst in order to ensure rapid reactions. Such aqueous conditions are very useful for biochemical conjugations

as well as for organic syntheses. We recently reported on the synthesis of a series of differently substituted 1

2

3-triazole chromophores

the substituted 2-(1-phenyl-1H-1

2

3-triazol-4-yl)pyridine ligands [5]

see Fig. 2 middle

with substituents R = H (L1)

CH3 (L2)

OCH3 (L3)

COOH

F

Cl

CN

CF3

O(CH2)3CH3 and N(CH3)2. These versatile ligands were found to coordinate to various first row transition metals

such as manganese

cobalt and nickel [6]. Here we extend the series to include more first row transition metal(II) coordination compounds

iron

copper and zinc

as well as a second row transition metal(II) coordination compound

cadmium

containing the 2-(1-(4-methyl-phenyl)-1H-1

2

3-triazol-1-yl)pyridine chromophore (Fig. 2 right with R = CH3). This series of seven novel coordination compounds is the first series of pyridyl-triazole based transition metal coordination compounds where seven different transition metals are coordinated to the same 1

2

3-triazole chromophore

namely 2-(1-(4-methyl-phenyl)-1H-1

2

3-triazol-1-yl)pyridine.

Kinaan M

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Publication Date

Sun Oct 17 2021

Journal Name

Iraqi Journal Of Physics

The effect of inorganic pigment on the tensile properties of polycarbonate irradiated with UV – light

The effect of UV-light on the tensile properties of pure PC has been studied. It was shown that irradiation of PC undergo a drop in the tensile properties of 30 hour of exposure. The results of irradiated samples shows that the addition of ZnO and TiO2 with different percentages (0.5

1

1.5 %) will reduce the Young modulus and ultimate stress of PC/ZnO

PC/ TiO2 composites

Z. R.

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The effect of UV-light on the tensile properties of pure PC has been studied. It was shown that irradiation of PC undergo a drop in the tensile properties of 30 hour of exposure. The results of irradiated samples shows that the addition of ZnO and TiO2 with different percentages (0.5, 1, 1.5 %) will reduce the Young modulus and ultimate stress of PC/ZnO ,PC/ TiO2 composites

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Publication Date

Sun Sep 04 2011

Journal Name

Baghdad Science Journal

Pulse Profile Rule in Laser Heating of Opaque Targets in Air

A theoretical model is developed to determine time evolution of temperature at the surface of an opaque target placed in air for cases characterized by the formation of laser supported absorption waves (LSAW) plasmas. The model takes into account the power temporal variation throughout an incident laser pulse

(i.e. pulse shape

or simply: pulse profile). Three proposed profiles are employed and results are compared with the square pulse approximation of a constant power.

Bassam H.

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A theoretical model is developed to determine time evolution of temperature at the surface of an opaque target placed in air for cases characterized by the formation of laser supported absorption waves (LSAW) plasmas. The model takes into account the power temporal variation throughout an incident laser pulse, (i.e. pulse shape, or simply: pulse profile).
Three proposed profiles are employed and results are compared with the square pulse approximation of a constant power.

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Publication Date

Wed Dec 01 2021

Journal Name

Structures

The effect of ground motion characteristics on the fragility analysis of reinforced concrete frame buildings in Australia

The seismic performance of buildings can be assessed through fragility analysis as it yields the probability of the demand exceeding the capacity at a specified level of intensity. Although it's well-identified that earthquake uncertainties dominate the fragility characteristics

the influence of the characteristics of the earthquake on the fragility analysis is not well investigated. This study aims to compare the effect of earthquake characteristics on the fragility values of typical buildings in Australia. To achieve this

a typical reinforced concrete building is selected and modeled using a finite element approach. Various ground motion suites

such as near-fault

far-fault

and long-duration are selected

and the fragility analysis has been carried out for each ground motion suite. It is observed that the variation in the median values of the collapse fragilities can be as high as 48% between short-duration and long-duration ground motions

and about 40% between long-duration and pulse-like ground motions.

Aya

Sujith

Javad

Alaa

M.D. Morshed

Abbas A.

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