Diazotization reaction between 1-(2,4,6-trihydroxy-phenyl)-ethanone and diazonium salts produced the ligand 4-(3-Acetyl-2,4,6-trihydroxy-phenylazo)-N-(5-methyl-isoxazol-3-yl)- benzenesulfonamide, which in turn reacted with the metal ions (Ni2+, Zn2+, Pd2+ and Pt4+) forming stable complexes with Octahedral geometry suggest of (Ni2+ and Pt4+), Zn2+ complex Tetrahedral and Pd2+ complex Square planer. The creation of such complexes was detected by employing spectroscopic means involving ultraviolet-visible, which proved the obtained geometries; FT-IR confirmed the formation of the azo group and the coordination with metal ions through it. Thermogravimetric analysis studies demonstrated the coordination of water residues (aqua or hydrate) with metal ions inside the coordination sphere, as well as used curve DSC to calculate the thermodynamic parameters ΔH, ΔS, and ΔG. Moreover, element microanalysis and atomic absorption gave corresponding outcomes with theoretically counting outcomes. Neuclearmagnatic resonances for 1H and 13C, chlorine atoms, and magnetic moment quantifications also indicate the formation of azo dye ligand. The ligand and new complexes showed antioxidant abilities to scavenge free radicals
Synthesis, Characterization and Determination Antioxidant Activities for New
Azo Dyederived from Sulfamethoxazole and Some Metal Ion Complexes
Antioxidant
Mass spectroscopy
Azo dye
1-(2
4
6-trihydroxy-phenyl)-ethanone
Thermal analysis
Publication Date
Sun Oct 17 2021
Journal Name
Iraqi Journal Of Physics
The effect of inorganic pigment on the tensile properties of polycarbonate irradiated with UV – light
The effect of UV-light on the tensile properties of pure PC has been studied. It was shown that irradiation of PC undergo a drop in the tensile properties of 30 hour of exposure. The results of irradiated samples shows that the addition of ZnO and TiO2 with different percentages (0.5
1
1.5 %) will reduce the Young modulus and ultimate stress of PC/ZnO
PC/ TiO2 composites
The effect of UV-light on the tensile properties of pure PC has been studied. It was shown that irradiation of PC undergo a drop in the tensile properties of 30 hour of exposure. The results of irradiated samples shows that the addition of ZnO and TiO2 with different percentages (0.5, 1, 1.5 %) will reduce the Young modulus and ultimate stress of PC/ZnO ,PC/ TiO2 composites
Publication Date
Wed Dec 01 2021
Journal Name
Structures
The effect of ground motion characteristics on the fragility analysis of reinforced concrete frame buildings in Australia
The seismic performance of buildings can be assessed through fragility analysis as it yields the probability of the demand exceeding the capacity at a specified level of intensity. Although it's well-identified that earthquake uncertainties dominate the fragility characteristics
the influence of the characteristics of the earthquake on the fragility analysis is not well investigated. This study aims to compare the effect of earthquake characteristics on the fragility values of typical buildings in Australia. To achieve this
a typical reinforced concrete building is selected and modeled using a finite element approach. Various ground motion suites
such as near-fault
far-fault
and long-duration are selected
and the fragility analysis has been carried out for each ground motion suite. It is observed that the variation in the median values of the collapse fragilities can be as high as 48% between short-duration and long-duration ground motions
and about 40% between long-duration and pulse-like ground motions.
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