Azo-ligand-(HL) ([4- ((2-hydroxyquinolin-3-yl) diazenyl) -N- (5-methylisoxazol-3yl) benzenesulfonamide]), (2- hydroxy quinolin derivative),reacts with the next metal ions (Cr (III), Fe (III),Co (II) and Cu(II)) forming stable complexes with unique geometries such as(tetrahedral for bothCo (II) and Cu (II), octahedral for both Cr (III) and Fe (III)). The creation of such complexes was detected by employing spectroscopic means involving ultraviolet-visible which proved the obtained geometries, Fourier transfer proved the involvement of coordinated water molecule in all complexes besides the pyrolysis (TGA & DSC) studies proved the coordination of water residues with metal ions inside the coordination sphere as well as chlorine atoms. Moreover element-micro-analysis and AAS that gave corresponding outcome with theoretically counting outcome. Magnetic quantification scan also indicates the unique geometries of complexes. The degradation of reactive oxygen entities for the compounds were estimated toward (DPPH-radical then matched to the standard-natural antioxidant, Gallic acid. The incomes display good radical degradations-activities.The lower IC50 value, the higher antioxidant activity. Depending on this conception, the order of our compounds besides Azo-species-HL is as follows: (G_A<[Co(L)(H2O)Cl]> [Cr(L)(H2O)Cl]> [Fe(L)(H2O)2Cl2]> [Cu(L)(H2O)Cl]).
Cr (III), Fe (III), Co (II) and Cu(II)Metal ions Complexes with Azo Compound
Derived from 2-hydroxy Quinoline Synthesis, Characterization, Thermal Study
and Antioxidant Activity
antioxidant
azo dye
Mass spectroscopy
quinolin derivative
Thermal analysis.
Publication Date
Sat Dec 30 2023
Journal Name
Journal Of Economics And Administrative Sciences
The Cluster Analysis by Using Nonparametric Cubic B-Spline Modeling for Longitudinal Data
البيانات الطولية
نموذج الشرائح B-spline التكعيبية اللامعلمية
التحليل العنقودي
طريقة الاتجاه المتناوب لخوارزمية المضاعف ADMM.
Longitudinal Data
Nonparametric Cubic B-Spline
Cluster Analysis
The Alternating Direction Method for Multiplier Algorithm ADMM.
Longitudinal data is becoming increasingly common, especially in the medical and economic fields, and various methods have been analyzed and developed to analyze this type of data.
In this research, the focus was on compiling and analyzing this data, as cluster analysis plays an important role in identifying and grouping co-expressed subfiles over time and employing them on the nonparametric smoothing cubic B-spline model, which is characterized by providing continuous first and second derivatives, resulting in a smoother curve with fewer abrupt changes in slope. It is also more flexible and can pick up on more complex patterns and fluctuations in the data.
The longitudinal balanced data profile was compiled into subgroup
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Publication Date
Wed Dec 01 2021
Journal Name
Structures
The effect of ground motion characteristics on the fragility analysis of reinforced concrete frame buildings in Australia
The seismic performance of buildings can be assessed through fragility analysis as it yields the probability of the demand exceeding the capacity at a specified level of intensity. Although it's well-identified that earthquake uncertainties dominate the fragility characteristics
the influence of the characteristics of the earthquake on the fragility analysis is not well investigated. This study aims to compare the effect of earthquake characteristics on the fragility values of typical buildings in Australia. To achieve this
a typical reinforced concrete building is selected and modeled using a finite element approach. Various ground motion suites
such as near-fault
far-fault
and long-duration are selected
and the fragility analysis has been carried out for each ground motion suite. It is observed that the variation in the median values of the collapse fragilities can be as high as 48% between short-duration and long-duration ground motions
and about 40% between long-duration and pulse-like ground motions.
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