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Oily water treatment by polyacrylonitrile/polysulfone blend ultrafiltration membrane embedded with alumina nanoparticles of improved antifouling properties
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<p>The polyacrylonitrile (PAN)/polysulfone (PSF) blended polymer membranes were modified by decaethylene glycol monododecyl ether (C<sub>12</sub>EO<sub>10</sub>) as a non-ionic surfactant. Polymeric solutions containing 17 wt.% of both PAN and PSF with a ratio of 80/20, and C<sub>12</sub>EO<sub>10</sub> with a mass concentration of 6 wt.% and aluminium oxide (Al<sub>2</sub>O<sub>3</sub>) nanoparticles with varying concentrations (1, 2, and 3 wt.%) were prepared. Adding 6 wt.% of C<sub>12</sub>EO<sub>10</sub> to the casting solution formed a membrane with distinguished hydrophilicity and fouling resistance, higher porosity, appreciable permeate flux (77.1 L/m<sup>2</sup>.h), and distinct vacuum gas oil rejection (92%) in comparison with the pure PAN ultrafiltration membrane. Further improvement for the PAN/PSF blend membrane using 2 wt.% of γ-Al<sub>2</sub>O<sub>3</sub> in the presence of 6 wt.% of C<sub>12</sub>EO<sub>10</sub> (PPCA-6-2γ membrane) produced an excellent permeate flux of&nbsp;189.2 L/m²·h, favorable hydrophilicity with a contact angle of 26.55°, and an optimistic COD removal%, expressing the VGO rejection, of 97.15%. The&nbsp;PPCA-6-2γ membrane revealed acceptable separation performance up to four cycles of filtration and exhibited enhanced antifouling properties with an FRR% of 95.4%.&nbsp;The fouling mechanism that determines the flux reduction during crossflow ultrafiltration by the PPCA-6-2γ membrane was studied using the Hermia models. The cake layer formation model provided the best match for the experimental behavior when analyzing the flux reduction with time for the PPCA-6-2γ membrane. The fabrication cost was determined for PPCA-6-2γ membrane to be $1.67/20 g, respectively. So, the local manufacturing costs of the PPCA-6-2γ membrane did not surpass 90 $/m<sup>2</sup> of the membrane.</p>

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Publication Date
Tue Oct 01 2024
Journal Name
Applied Science And Engineering Progress
ZrO2 Nanoparticles Filler-Based Mixed Matrix Polyethersulfone/Cellulose Acetate Microfiltration Membrane for Oily Wastewater Separation
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Membrane technology has emerged as a dynamic field of study in academia and industry for treating produced oily wastewater. ZrO2 nanoparticles (ZrO2 NPs) filler-based mixed matrix polyethersulfone/cellulose acetate microfiltration membranes were fabricated and inspected in the oily wastewater remediation. The fabricated bare PES membrane, PES/CA blended polymers membrane, and PES/CA blended polymers incorporating ZrO2 NPs (ZrO2@PES/CA) membranes by phase inversion technique were inspected by field emission scanning electron microscopy, atomic force microscopy, Fourier-transform infrared spectroscopy, and measurement of water contact angle and porosity. The ZrO2@PES/CA membrane which consisted of 0.5 wt.% ZrO2 NPs (0.5%ZrPC) afforded

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Publication Date
Fri Jun 29 2018
Journal Name
Journal Of Engineering
Preparation and Characterization of AgNp/PVDF Cmposite Ultrafiltration Membrane
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In this study, polymeric ultrafiltration (UF) membranes were prepared by phase inversion method to obtain both antibacterial and organic antifouling properties. The membranes were cast from a solution of polyvinylidene fluoride (PVDF) and formative silver (Ag) nanoparticles were successfully immobilized on a polymer. This was done using a solvent N, N-dimethylformamide (DMF) which is a solvent for the PVDF polymer meanwhile it is a reducing agent for silver ion. The effect of silver nanoparticles additives on the performance of polymeric ultrafiltration membrane was verified. Chemical composition and morphology of the surfaces of the membranes were characterized by Fourier transform infrared spectroscopy

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Publication Date
Thu Aug 01 2024
Journal Name
Applied Science And Engineering Progress
Efficient Separation of Organic Dyes using Polyvinylidene Fluoride/Polyethylene Glycol-Tin Oxide (PVDF/PEG-SnO2) Nanoparticles Ultrafiltration Membrane
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This work studies developing ultrafiltration (UF) membranes using organic and inorganic additives to remove organic dyes at UF conditions with high effectiveness. Flat sheet (18 wt%) polyvinylidene fluoride (PVDF) membranes were prepared via phase inversion and then developed by adding 6 wt% polyethylene glycol (PEG) as a pore former. Furthermore, the PVDF/PEG membranes were developed by embedding tin oxide nanoparticles (SnO2 NPs) with different contents of 0.3, 0.6, and 0.9 wt%. The prepared membranes were examined for their performance in the dye removal before being characterized using the field emission scanning electron microscope, atomic force microscopy, contact angle, Fourier-transform infrared spectroscopy, surface charge,

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Publication Date
Mon Jul 01 2024
Journal Name
Desalination And Water Treatment
Separation performance of cationic and anionic dyes from water using polyvinylidene fluoride-based ultrafiltration membrane incorporating polyethylene glycol
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Publication Date
Sat Jan 05 2019
Journal Name
Iraqi Journal Of Physics
Study the effect of CaCO3 nanoparticles on physical properties of biopolymer blend
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Chitosan (CH) / Poly (1-vinylpyrrolidone-co-vinyl acetate) (PVP-co-VAc) blend (1:1) and nanocomposites reinforced with CaCO3 nanoparticles were prepared by solution casting method. FTIR analysis, tensile strength, Elongation, Young modulus, Thermal conductivity, water absorption and Antibacterial properties were studied for blend and nanocomposites. The tensile results show that the tensile strength and Young’s modulus of the nanocomposites were enhanced compared with polymer blend [CH/(PVP-co-VAc)] film. The mechanical properties of the polymer blend were improved by the addition of CaCO3 with significant increases in Young’s modulus (from 1787 MPa to ~7238 MPa) and tensile strength (from 47.87 MPa to 79.75 MPa). Strong interfacial

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Publication Date
Fri Sep 30 2016
Journal Name
Iraqi Journal Of Chemical And Petroleum Engineering
A Morphological Study of Alumina Hollow Fiber Membrane
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Morphologies of ceramic hollow fiber membranes prepared by a combined phase-inversion and sintering method were studied. The organic binder spinning solution containing suspended Al₂O₃ powders was spun to a hollow fiber precursor, which was then sintered at elevated temperatures( 300 ˚C, 1400 ˚C, 25 ˚C) in order to obtain the Al₂O₃ hollow fiber membranes. The spinning solution consisted of polyether sulfone (PES), N-methyl-2-pyrrolidone (NMP), which were used as polymer binder, solvent, respectively. The prepared Al₂O₃ hollow fiber membranes were characterized by a scanning electron microscope (SEM). It is believed that finger-like void formation in asymmetric ceramic membranes is initiated by hydrodynamically unstable vis

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Publication Date
Tue Sep 01 2020
Journal Name
Iop Conference Series: Materials Science And Engineering
Adsorption Optimization of Congo Red Dye onto Electrospun Nanofibers of Polyacrylonitrile functionalized with Fe3O4 Nanoparticles
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Ferric oxide nanoparticles Fe3O4NPs have been prepared by the coprecipitation method, which were used to functionalize the surface of electrospun nanofibers of polyacrylonitrile to increase their effectiveness in adsorption of Congo red (CR) dye from their aqueous solutions. The effect factors of adsorption were systematically investigated such as adsorbent mass, initial concentration, contact time, temperature, ionic strength and pH. The maximum adsorbed amount of the dye was at 0.003g of adsorbent. The adsorption of dye increased with increasing initial dye concentration and the system reaches to the equilibrium state at 150 min. The adsorbed dye capacity decreases with increasing temperature which indicates to the exothermic nature of ad

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Publication Date
Wed Jul 01 2026
Journal Name
South African Journal Of Chemical Engineering
Enhancement of water-based drilling fluid using novel composite of silica and alumina nanoparticles
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One of the most recent research areas in subsurface applications, including well drilling, is the use of eco-friendly and sustainably synthesized nanoparticles to improve drilling fluid efficiency. Typically, Shale formations present significant challenges to traditional drilling fluids, including fluid infiltration and shale swelling, which jeopardize wellbore stability. Although water-based drilling fluids (WBM) are environmentally preferred, their performance often requires enhancement through advanced additives. This study thus examines the synthesis of silica (SiO₂) and alumina (Al₂O₃) nanoparticles (NPs) using sustainable methods, employing Iraqi bentonite for silica and recycled aluminum scrap for alumina, to improve WBM effici

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Publication Date
Thu Mar 15 2018
Journal Name
Moroccan Journal Of Chemistry
Corrosion Protection of Carbon Steel in seawater by alumina nanoparticles with poly (acrylic acid) as charging agent
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Nanostructured Al2O3has been applied as a protective coating against corrosion of the carbon steel (C.S) in seawater environment (3.5% NaCl) at temperatures range (298-328)K. Aluminananoparticles were deposited on carbon steel substrates by cathodic electrophoretic deposition (EPD) with ethanol as suspension medium and poly(acrylic acid) (PAA) as polymeric charging agent. Meanwhile, thesurface morphology was examined using Atomic-force microscopy (AFM). The cross-section AFM showed that the particles sizes for the Al2O3 NPs is around 60-80 nm. The anticorrosion behaviour of coated C.S was investigated in 3.5% NaCl at temperature range 298-328 K by potentiodynamic polarization measurements. Results show that using PAA in suspension coat incr

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Publication Date
Fri Dec 01 2023
Journal Name
Materials Today Sustainability
Structure and performance of polyvinylchloride microfiltration membranes improved by green silicon oxide nanoparticles for oil-in-water emulsion separation
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