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Oily water treatment by polyacrylonitrile/polysulfone blend ultrafiltration membrane embedded with alumina nanoparticles of improved antifouling properties
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<p>The polyacrylonitrile (PAN)/polysulfone (PSF) blended polymer membranes were modified by decaethylene glycol monododecyl ether (C<sub>12</sub>EO<sub>10</sub>) as a non-ionic surfactant. Polymeric solutions containing 17 wt.% of both PAN and PSF with a ratio of 80/20, and C<sub>12</sub>EO<sub>10</sub> with a mass concentration of 6 wt.% and aluminium oxide (Al<sub>2</sub>O<sub>3</sub>) nanoparticles with varying concentrations (1, 2, and 3 wt.%) were prepared. Adding 6 wt.% of C<sub>12</sub>EO<sub>10</sub> to the casting solution formed a membrane with distinguished hydrophilicity and fouling resistance, higher porosity, appreciable permeate flux (77.1 L/m<sup>2</sup>.h), and distinct vacuum gas oil rejection (92%) in comparison with the pure PAN ultrafiltration membrane. Further improvement for the PAN/PSF blend membrane using 2 wt.% of γ-Al<sub>2</sub>O<sub>3</sub> in the presence of 6 wt.% of C<sub>12</sub>EO<sub>10</sub> (PPCA-6-2γ membrane) produced an excellent permeate flux of&nbsp;189.2 L/m²·h, favorable hydrophilicity with a contact angle of 26.55°, and an optimistic COD removal%, expressing the VGO rejection, of 97.15%. The&nbsp;PPCA-6-2γ membrane revealed acceptable separation performance up to four cycles of filtration and exhibited enhanced antifouling properties with an FRR% of 95.4%.&nbsp;The fouling mechanism that determines the flux reduction during crossflow ultrafiltration by the PPCA-6-2γ membrane was studied using the Hermia models. The cake layer formation model provided the best match for the experimental behavior when analyzing the flux reduction with time for the PPCA-6-2γ membrane. The fabrication cost was determined for PPCA-6-2γ membrane to be $1.67/20 g, respectively. So, the local manufacturing costs of the PPCA-6-2γ membrane did not surpass 90 $/m<sup>2</sup> of the membrane.</p>

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Publication Date
Fri Mar 31 2017
Journal Name
Iraqi Journal Of Chemical And Petroleum Engineering
Treatment of Simulated Oily Wastewater by Ultrafiltration and Nanofiltration Processes
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A study in the treatment and reuse of oily wastewater generated from the process of fuel oil treatment of gas turbine power plant was performed. The feasibility of using hollow fiber ultrafiltration (UF) membrane and nanofiltration (NF) membrane type polyamide thin-film composite in a pilot plant was investigated. Three different variables: pressure (0.5, 1, 1.5 and 2 bars), oil content (10, 20, 30 and 40 ppm), and temperature (15, 20, 30 and 40 ᵒC) were employed in the UF process while TDS was kept constant at 150 ppm. Four different variables: pressure (2, 3, 4 and 5 bar), oil content (2.5, 5, 7.5 and 10 ppm), total dissolved solids (TDS) (100, 200,300 and 400 ppm), and temperature (15, 20, 30 and 40 ᵒC) were manipulated with the h

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Publication Date
Sat Jun 01 2024
Journal Name
Journal Of Environmental Chemical Engineering
High performance and antifouling zeolite@polyethersulfone/cellulose acetate asymmetric membrane for efficient separation of oily wastewater
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Publication Date
Mon Dec 21 2020
Journal Name
International Journal Of Environmental Analytical Chemistry
Comparative study of embedded functionalised MWCNTs and GO in Ultrafiltration (UF) PVC membrane: interaction mechanisms and performance
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Publication Date
Wed Sep 18 2024
Journal Name
Water Science & Technology
Mathematical modeling of osmotic membrane bioreactor process for oily wastewater treatment
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ABSTRACT<p>To evaluate the disposal effluent from the Al-Daura refinery in Iraq, which comprises oily wastewater, a mathematical model has been developed for both forward osmosis (FO) and osmotic membrane bioreactor (OsMBR). The procedure is explained mathematically, accounting for both the concentration and polarization aspects. As a result of mathematical modeling, the water flux was determined by the osmotic pressure, the concentration, and the polarization of the feed and draw solutions. Based on traditional methods of predicting water flux using external and internal concentration polarizations, it is determined that water flux will occur in the first model (Model-1). To increase the accura</p> ... Show More
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Publication Date
Wed Dec 13 2017
Journal Name
Al-khwarizmi Engineering Journal
Produced Water Treatment Using Ultrafiltration and Nanofiltration Membranes
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The application of ultrafiltration (UF) and nanofiltration (NF) processes in the handling of raw produced water have been investigated in the present study. Experiments of both ultrafiltration and nanofiltration processes are performed in a laboratory unit, which is operated in a cross-flow pattern. Various types of hollow fiber membranes were utilized in this study such as poly vinyl chloride (PVC) UF membrane, two different polyether sulfone (PES) NF membranes, and poly phenyl sulfone PPSU NF membrane. It was found that the turbidity of the treated water is higher than 95 % by using UF and NF membranes. The chemical oxygen demand COD (160 mg/l) and Oil content (26.8 mg/l) were found after treatment according to the allowable limits set

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Publication Date
Sat Dec 31 2016
Journal Name
Iraqi Journal Of Chemical And Petroleum Engineering
Osmotic Membrane Bioreactor for Oily Wastewater Treatment using External & Internal Configurations
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The present work aims to study the treatment of oily wastewater by means of forward osmosis membrane bioreactor process. Side stream (external) configuration and submerged (internal) configuration of osmotic membrane bioreactor were performed and investigated. The experimental work for each configuration was carried out continuously over 21 days. The flux behavior of forward osmosis membrane in an osmotic membrane bioreactor (OMBR) was investigated, using NaCl as the draw solution and CTA as FO membrane. The effect of mixed liquor suspended solids (MLSS) concentration and TDS accumulation of bioreactor on water flux and membrane fouling behaviors was detected. The accumulation and rejection of nutrients in the bioreactor (Nitrate, COD,

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Publication Date
Fri Jun 13 2025
Journal Name
Applied Sciences
Developing a Superhydrophilic/Underwater Superoleophobic Plasma-Modified PVDF Microfiltration Membrane with Copolymer Hydrogels for Oily Water Separation
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Polymer membranes often face challenges of oil fouling and rapid water flux decline during the separation of oil-in-water emulsions, making them a focal point of ongoing research and development efforts. Coating PVDF membranes with a hydrogel layer equips the developed membranes with robust potential to mitigate oil fouling. However, developing a controllable thickness of a stable hydrogel layer to prevent the blocking of membrane pores remains a critical issue. In this work, atmospheric pressure low-temperature plasma was used to prepare the surface of a PVDF membrane to improve its wettability and adhesion properties for coating with a thin hydrophilic film of an AM-NaA copolymer hydrogel. The AM-NaA/PVDF membrane exhibited superh

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Publication Date
Fri Jan 01 2021
Journal Name
Journal Of Renewable Materials
Corrosion Protection of 5083 AA in Saline Water by Polyacrylonitrile Nanofibers
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Publication Date
Fri Feb 01 2019
Journal Name
International Journal Of Mechanical Engineering And Technology (ijmet)
INVESTIGATION THE PROPERTIES OF SILICONE RUBBER BLEND REINFORCED BY NATURAL NANOPARTICLES AND UHMWPE FIBER
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Many faces are exposed to degradation, discoloration, changes in humidity. The primary objective has improved some properties of hybrid nanocomposites materials that used for restoring of the function maxillofacial prosthesis and improving the esthetic. In the present research different lengths chopped and continuous of ultrahigh molecular weight polyethylene (UHMWPE) fiber was added at selected percentage (0.0, 0.2% and 1%) to polymer blend composite (95%SR /5%PMMA: 0.2% Pomegranate Peels Powder (PPP)) for developing the properties of silicone rubber used for the maxillofacial prosthesis applications. Some mechanical and physical properties were done on the all prepared samples. The results showed that all properties have improved when add

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Publication Date
Fri Feb 24 2023
Journal Name
Membranes
Enhanced Antifouling in Flat-Sheet Polyphenylsulfone Membranes Incorporating Graphene Oxide–Tungsten Oxide for Ultrafiltration Applications
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In this study tungsten oxide and graphene oxide (GO-WO2.89) were successfully combined using the ultra-sonication method and embedded with polyphenylsulfone (PPSU) to prepare novel low-fouling membranes for ultrafiltration applications. The properties of the modified membranes and performance were investigated using Fourier-transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), contact angle (CA), water permeation flux, and bovine serum albumin (BSA) rejection. It was found that the modified PPSU membrane fabricated from 0.1 wt.% of GO-WO2.89 possessed the best characteristics, with a 40.82° contact angle and 92.94% porosity. The permeation flux of the best membrane was the highest. The pure water permeation f

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