The current study suggested a thermal treatment as a necessary proactive step in improving the adsorption capacity of bio-waste for contaminants removal in wastewater. This approach was based on the experimental and histological investigation of biowaste pods shell. This investigation showed that these shells compose of parenchyma cells that store secondary metabolites compounds produced from cells were exhibited in present study. The results also reported that these compounds are extracted directly from the cells as soon as they are exposed to an aqueous solution, hampering their use as an adsorbent material. The increase in the weight of bio-waste adsorbent at unit liquid volume increases the production of secondary metabolites compounds under normal conditions. While thermal conditions accelerate the exit of these compounds from their storage places. After suggested thermal processing, the bio-waste was examined for azo dye removal under different operational conditions (adsorbent weight (1,0.1 g), contact time (24 and 48 hr), and temperature (30, 40, 50,and 60°C). In general, the experimental data showed a good improvement in adsorption potential. The results presented clearly that the increase in temperature has a positive effect on the performance of pollutant removal. The maximum adsorption capacity was 0.035833 mol/g at a temperature of 40°C, and 0.036417 mol/g at a temperature of 50°C. This behaviour may be counterproductive with high temperatures as a result of the release of more secondary metabolites compounds. For other operating conditions, increasing the concentration of the pollutant also improves the efficiency of the process, while this efficiency decreases with the increasing weight of the adsorbent material. For example, the removal capacity was (0.000275, 0.00675 mol/g) with 1 and 0.1 g of the adsorbent weight, respectively. Finally, the present study concluded that the adoption of thermal pre-treatment technology for bio-mass waste is a necessary step in improving the adsorption processes.
Аннотация
Взгляд на пол как на комплексное социальное отношение означает,что роль женщины в истории следует рассматривать не просто как новый для исторической науки предмет исследования, а как обойденный вниманием ученых вопрос об отношениях между людьми или группами людей.
Женщина играет особую и важную роль в обществе , даже скажут ,что она половина нашего общества ,поэтому она яв
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(2)
The effect of thickness variation on some physical properties of hematite α-Fe2O3 thin films was investigated. An Fe2O3 bulk in the form of pellet was prepared by cold pressing of Fe2O3 powder with subsequent sintering at 800 . Thin films with various thicknesses were obtained on glass substrates by pulsed laser deposition technique. The films properties were characterized by XRD, and FT-IR. The deposited iron oxide thin films showed a single hematite phase with polycrystalline rhombohedral crystal structure .The thickness of films were estimated by using spectrometer to be (185-232) nm. Using Debye Scherrerś formula, the average grain size for the samples was found to be (18-32) nm. Atomic force microscopy indicated that the films had
... Show MoreThe reaction oisolated and characterized by elemental analysis (C,H,N) , 1H-NMR, mass spectra and Fourier transform (Ft-IR). The reaction of the (L-AZD) with: [VO(II), Cr(III), Mn(II), Co(II), Ni(II), Cu(II), Zn(II), Cd(II) and Hg(II)], has been investigated and was isolated as tri nuclear cluster and characterized by: Ft-IR, U. v- Visible, electrical conductivity, magnetic susceptibilities at 25 Co, atomic absorption and molar ratio. Spectroscopic evidence showed that the binding of metal ions were through azide and carbonyl moieties resulting in a six- coordinating metal ions in [Cr (III), Mn (II), Co (II) and Ni (II)]. The Vo (II), Cu (II), Zn (II), Cd (II) and Hg (II) were coordinated through azide group only forming square pyramidal
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