doi:10.1088/1742-6596/1234/1/012046

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Publication Date

Mon Jul 01 2019

Journal Name

Journal Of Physics: Conference Series

Volume

1234

DOI

10.1088/1742-6596/1234/1/012046

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Determination of Radionuclides and Heavy Elements in the Rising Dust in the Small Side of Diwaniyah City due to the Movement of Wheels and Cars

K.H.

Raad Mahmoud Nasif

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AbstractThis research aims to determine the concentration of radionuclides in dust samples on the public streets of the small side of Diwaniyah city in Iraq as a result of movements of wheels and cars using the gamma spectra and high purity germanium detector (HPGe) with resolution of (2.3 keV) for energy (1.332 MeV) of cobalt 60Co. Dust samples were collected from the streets Diwaniyah city with (26) samples prepared for measurement. The results of the specific activity concentration of Uranium-238, Thorium-232, Potassium-40 and Cesium-137 were (14.66 ± 0.950, 26.29 ± 2.431, 219.04 ± 15.150 and 11.49 ± 0.876) Bq/kg respectively. The radiation parameters Raeq, absorbed dose rate, annual effective external exposure rate and annual effective dose rate of internal exposure were (69.122 Bq/kg, 31.787 nGy/h, 0.0389 mSv/y,0.155 mSv/y) respectively. The value of the external risk index (Hex), the internal risk index (HIn) and the risk index for gamma radiation was (0.186,0.226 and 0.506) respectively. The results obtained from granular volumetric analysis of dust patterns as a result of movement of cars and vehicles indicate that most of dust for some samples of the study area was sandy-silt with a little clay (Sandy Silt Clayey). These components of dust depend on the energy and speed of the transport wind, Volumetric granules.

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Publication Date

Sun Jan 26 2020

Journal Name

Journal Of Global Pharma Technology

Synthesis, Characterization of 2-azido-4-(azido (2-azido-2-( azido carbonyl)-1,3-dioxoian-4-yl)methyl)– 5-((R-azido (hydroxyl) methyl- 1,3-dioxole-2-carbonyl azide. ethanol. hydrate (L-AZD) with Some Metal Complexes

Synthesis

Tri nuclear cluster

Azide

Waleed Khalid Mahdi

Ala H. Hassn

Falih H. Musa

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The reaction oisolated and characterized by elemental analysis (C,H,N) , 1H-NMR, mass spectra and Fourier transform (Ft-IR). The reaction of the (L-AZD) with: [VO(II), Cr(III), Mn(II), Co(II), Ni(II), Cu(II), Zn(II), Cd(II) and Hg(II)], has been investigated and was isolated as tri nuclear cluster and characterized by: Ft-IR, U. v- Visible, electrical conductivity, magnetic susceptibilities at 25 Co, atomic absorption and molar ratio. Spectroscopic evidence showed that the binding of metal ions were through azide and carbonyl moieties resulting in a six- coordinating metal ions in [Cr (III), Mn (II), Co (II) and Ni (II)]. The Vo (II), Cu (II), Zn (II), Cd (II) and Hg (II) were coordinated through azide group only forming square pyramidal

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