The studies on unbonded post-tensioned concrete members strengthened with Carbon Fiber Reinforced Polymers (CFRPs) are limited and the effect of strengthening on the strain of unbonded pre-stressed steel is not well characterized. Estimating the flexural capacity of unbound post-tensioned members using the design methodology specified in the design guidelines for FRP strengthening techniques of bonded post-tensioned members does not provide a reliable evaluation. This study investigates the behavior of unbonded post-tensioned concrete members with partial strand damage (14.3% and 28.6% damage) and strengthened with CFRP laminates using a near-surface mounted technique with and without U-wrap anchorages. The experimental results showed that the use of CFRP laminates significantly affects strand strain, especially with the use of anchors. The CFRP reinforcement affected flexural strength, crack width, and midspan deflection. However, the flexural stiffness of strengthened members during the serviceability phases is critical as strand damage ratios increase. In comparison with the nondamaged girder, the NSM-CFRP laminates enhanced the flexural capacity by 11% and 7.7% corresponding to strand damage of 14.3% and 28.6% respectively. Additionally, semiempirical equations were proposed to predict the actual strain of unbonded strands whilst considering the effects of FRP laminates. The suggested equations are simple to apply and provide accurate predictions with little variance.
Two simple methods for the determination of eugenol were developed. The first depends on the oxidative coupling of eugenol with p-amino-N,N-dimethylaniline (PADA) in the presence of K3[Fe(CN)6]. A linear regression calibration plot for eugenol was constructed at 600 nm, within a concentration range of 0.25-2.50 μg.mL–1 and a correlation coefficient (r) value of 0.9988. The limits of detection (LOD) and quantitation (LOQ) were 0.086 and 0.284 μg.mL–1, respectively. The second method is based on the dispersive liquid-liquid microextraction of the derivatized oxidative coupling product of eugenol with PADA. Under the optimized extraction procedure, the extracted colored product was determined spectrophotometrically at 618 nm. A l
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