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Graphite-Catalyzed Electro-Oxidation of Hydrazine Derivatives Using Sodium Chloride under Green and Sustainable Chemistry

The development of efficient and environmentally friendly catalysts for the electro-oxidation of hydrazine derivatives is of great importance in various industrial applications. In this study, we report the utilization of graphitebased catalysts for the electro-oxidation of hydrazine derivatives, using sodium chloride as a green and sustainable chemical approach. Graphite, a two-dimensional carbon material with exceptional properties, offers numerous advantages as a catalyst, including its high surface area, excellent electrical conductivity, and chemical stability. These characteristics make graphite an ideal candidate for promoting electrochemical reactions. Sodium chloride (NaCl), a readily available and cost-effective salt, serves as a green alternative to traditional oxidants used in hydrazine oxidation processes. By replacing conventional oxidizing agents with NaCl, we aim to reduce the environmental impact associated with the production and disposal of hazardous chemicals. This process enables the transformation of the HN-NH bond within hydrazines, leading to the formation of azo compounds (N¼N). Azo compounds are important organic molecules with diverse applications in organic synthesis. This novel approach has successfully showcased the efficacy of utilizing various azo compounds in 13 different examples, yielding excellent or moderate to good results. The method capitalizes on electricity as the final oxidizing agent, providing an environmentally friendly oxidation strategy. Its high efficiency and gentle reaction conditions make this technique valuable for synthesizing azo derivatives, even when working with hydrazines containing diverse functional groups, resulting in yields ranging from moderate to excellent. Through systematic experiments, we evaluated the catalytic performance of graphite-based catalysts in the electro-oxidation of hydrazine derivatives. The catalysts demonstrated remarkable catalytic activity due to their efficient conversion of hydrazine derivatives into desired products. Moreover, the system exhibited good stability and recyclability, suggesting its suitability for practical applications.

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Publication Date
Thu Apr 27 2017
Journal Name
Ibn Al-haitham Journal For Pure And Applied Sciences
A Study of Structure and Optical Properties of ZnO Thin Films Deposited by Using Thermal Evaporation Technique under Different Flow Rate of Oxygen O2

 Zinc oxide (ZnO) transparent thin films with different oxygen flow rates (0.5, 1.0, and 1.5)Litter/min. were prepared by thermal evaporation technique on glass substrate at a temperature of 200℃ with rate (10±2)nm sec-1,  The crystallinity and structure of these films were analyzed  by X-ray diffraction (XRD). It exhibits a polycrystalline hexagonal wurtzite structure and the preferred orientation along (002) plane. The Optical properties of ZnO were determined through the optical transmission method using ulta violet–Visible spectrophotometer with in wave length (300-1100)nm. The optical transmittance of the ZnO films increases from 75% to 85% with increase flow rate of O2, and the optical band gap of ZnO

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Publication Date
Sat Jan 05 2019
Journal Name
Iraqi Journal Of Physics
Study the effect of sodium hydroxide solution on the thermal conductivity of nanocomposites

In this research, hand lay- up technique is used to prepare samples from epoxy resin reinforced with multi- walled carbon nanotubes in different weight fractions (0, 2, 3, 4, 5) wt%. The immersion effect by sodium hydroxide solution (NaOH) at normality (0.3N) for a period of (15 days) on the thermal conductivity of nanocomposites was studied, and compared to natural condition (before immersion). The thermal conductivity of epoxy nanocomposites specimens were carried out using Lee’s disk method. The experimental results showed that thermal conductivity increased with increase weight fraction before and after immersion for all specimens, while the immersion effect leads to decrease thermal conductive values compared to thermal conductivi

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Publication Date
Thu Dec 23 2021
Journal Name
Iraqi Journal Of Science
Green Synthesis of Nickel Nanoparticles and their Application of Removal of Aliphatic Hydrocarbons from Crude Oil

     Nickel nanoparticles (Ni-nanoparticles) were incorporated as an antecedent utilizing nickel acetate and as a reducing agent, extraction plantApiumgraveolens.  The reason  fo choosing  this plant over many other is because it is easily accessible, carries many antioxidants,  non-toxic, and there are no dangerous residues and stabilizing agent at 60℃ under stirrer. The progress of the reaction was monitored  by observing a change in color of the obtained solution. The UV–Vis utilized to screen the development of Ni-nanoparticles inside a surface  plasmon band (SPB) at 275 nm gives a phantom mark appropriate to the arrangement of nanoparticles. Examining th

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Publication Date
Wed Jul 05 2017
Journal Name
International Journal Of Science And Research (ijsr)
Assessing BIM Integration with Sustainable Requirement for Buildings Construction

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Publication Date
Thu Dec 28 2023
Journal Name
Al–bahith Al–a'alami
Empowering Public Relations’ Practitioners to Achieve Sustainable Development Goals

The research aims to outline a governmental and societal communicative vision grounded in the principles of sustainable development within Iraqi governmental institutions. This is achieved by public relations practitioners incorporating these concepts and enhancing public awareness of them. Iraqi governmental institutions cannot deviate from the international pattern and societal mood that encompass the goals of sustainable development. The growing international and local interest in environmental issues has influenced governmental stances and actions towards the public.
The research's main problem revolves around addressing a pivotal question: What are the levels of empowerment of public relations practition

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Publication Date
Fri Jan 01 2021
Journal Name
Chemical Science
Stalling chromophore synthesis of the fluorescent protein Venus reveals the molecular basis of the final oxidation step

Fluorescent proteins (FPs) have revolutionised the life sciences, but the chromophore maturation mechanism is still not fully understood. Here we photochemically trap maturation at a crucial stage and structurally characterise the intermediate.

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Publication Date
Sat Dec 01 2012
Journal Name
Journal Of Engineering
Buckling Analysis of Composite Plates under Thermal and Mechanical Loading

Buckling analysis of composite laminates for critical thermal (uniform and linear) and mechanical loads is reported here. The objective of this work is to carry out theoretical investigation of buckling analysis of composite plates under thermomechanical loads, and experimental investigation under mechanical loads. The analytical investigation involved certain mathematical preliminaries, a study of equations of orthotropic elasticity for classical laminated plate theory (CLPT), higher order shear deformation plate theory (HSDT) , and numerical analysis (Finite element method), then the equation of motion are derived and solved using Navier method and Levy method for symmetric and anti-symmetric cross-ply and angle-ply laminated plates t

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Publication Date
Fri Feb 01 2019
Journal Name
Journal Of Economics And Administrative Sciences
A Comparison of Parameters Estimation Methods for the Negative Binomial Regression Model under Multicollinearity Problem by Using Simulation

This study discussed a biased estimator of the Negative Binomial Regression model known as (Liu Estimator), This estimate was used to reduce variance and overcome the problem Multicollinearity between explanatory variables, Some estimates were used such as Ridge Regression and Maximum Likelihood Estimators, This research aims at the theoretical comparisons between the new estimator (Liu Estimator) and the estimators

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Publication Date
Sat Oct 02 2021
Journal Name
International Journal Of Research In Social Sciences And Humanities
The Role of Green Quality Management and Product Life Cycle Costing in Achieving Competitive Advantage

The principal objective of this study is to demonstrate how green quality management and product life cycle costing may help an organization gain a competitive advantage. Green quality management's influence on increasing product quality and meeting environmental criteria, as well as tracking the activities of product life cycle before, during, and after production, is demonstrated. Orienting these activities toward the production of eco-friendly products that fulfill the needs of customers, hence increasing organization's market share. We found from our study that proposed framework can help organizations improve their competitiveness. Green quality management contributes to environmental protection and the provision of high-qualit

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Publication Date
Sat May 30 2020
Journal Name
Neuroquantology
Synthesis and Study NiO Charactrization of Extract from Green Tea Plant Prepared by Chemical Method

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