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Graphite-Catalyzed Electro-Oxidation of Hydrazine Derivatives Using Sodium Chloride under Green and Sustainable Chemistry

The development of efficient and environmentally friendly catalysts for the electro-oxidation of hydrazine derivatives is of great importance in various industrial applications. In this study, we report the utilization of graphitebased catalysts for the electro-oxidation of hydrazine derivatives, using sodium chloride as a green and sustainable chemical approach. Graphite, a two-dimensional carbon material with exceptional properties, offers numerous advantages as a catalyst, including its high surface area, excellent electrical conductivity, and chemical stability. These characteristics make graphite an ideal candidate for promoting electrochemical reactions. Sodium chloride (NaCl), a readily available and cost-effective salt, serves as a green alternative to traditional oxidants used in hydrazine oxidation processes. By replacing conventional oxidizing agents with NaCl, we aim to reduce the environmental impact associated with the production and disposal of hazardous chemicals. This process enables the transformation of the HN-NH bond within hydrazines, leading to the formation of azo compounds (N¼N). Azo compounds are important organic molecules with diverse applications in organic synthesis. This novel approach has successfully showcased the efficacy of utilizing various azo compounds in 13 different examples, yielding excellent or moderate to good results. The method capitalizes on electricity as the final oxidizing agent, providing an environmentally friendly oxidation strategy. Its high efficiency and gentle reaction conditions make this technique valuable for synthesizing azo derivatives, even when working with hydrazines containing diverse functional groups, resulting in yields ranging from moderate to excellent. Through systematic experiments, we evaluated the catalytic performance of graphite-based catalysts in the electro-oxidation of hydrazine derivatives. The catalysts demonstrated remarkable catalytic activity due to their efficient conversion of hydrazine derivatives into desired products. Moreover, the system exhibited good stability and recyclability, suggesting its suitability for practical applications.

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Publication Date
Sun Sep 01 2013
Journal Name
Baghdad Science Journal
Synthesis and Characterization of New Thioxanthone Derivatives

This work comprises the synthesis of new thioxanthone derivatives containing C-substituted thioxanthone. To obtain these derivatives, the o-mercapto benzoic acid was chosen as the starting material, which was reacted with dry benzene in sulfuric acid (98 %) to produce the thioxanthone (1). The 2,7-(disulfonyl phosphine imine) thioxanthone (4-8) were prepared from reaction of compound (1) with chlorosulfonic acid gave 2,7-(disulfonyl chloride) thioxanthone (2). Treatment of (2) with sodium azide to produce 2,7-(disulfonyl azide) thioxanthone (3). Condensation of (3) with phosphorus compounds afforded compounds (4-8). The 2,7-(disulfonamide) thioxanthone (9-21) was obtained when co

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Publication Date
Sat Apr 03 2021
Journal Name
Lubricants
UV-Visible Spectrophotometer for Distinguishing Oxidation Time of Engine Oil

Samples of gasoline engine oil (SAE 5W20) that had been exposed to various oxidation times were inspected with a UV-Visible (UV-Vis) spectrophotometer to select the best wavelengths and wavelength ranges for distinguishing oxidation times. Engine oil samples were subjected to different thermal oxidation periods of 0, 24, 48, 72, 96, 120, and 144 hours, resulting in a range of total base number (TBN) levels. Each wavelength (190.5 – 849.5 nm) and selected wavelength ranges were evaluated to determine the wavelength or wavelength ranges that could best distinguish among all oxidation times. The best wavelengths and wavelength ranges were analyzed with linear regression to determine the best wavelength or range to predict oxidation t

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Publication Date
Wed May 29 2019
Journal Name
Journal Of Legal Sciences
Sustainable development and nuclear energy -The dialectical relation –

 Today, development is the dominant idea at the international and national levels, while energy is at the heart of development as the engine and vital element of modern civilization, which can’t be achieved without the participation of an energy policy that takes into account this concern. At the same time, we can’t make any development in the margins of human rights, in other words, if we are to move to development, it would be wise to do so taking into account the rights of present and future generations, whereas they provide the greatest amount of development and less environmental damage. This may not be possible for all energy options, including nuclear, because of its intersection with the rights of future generations.

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Publication Date
Sat Aug 20 2022
Journal Name
Journal Of Legal Sciences
Generational rights and its relationship to sustainable development

The environment, in its various aspects, is the center of international concern, as it constitutes a common heritage of all humanity, as it has become a common denominator in relation to various issues and problems of an economic, social and cultural nature, and due to the development of public international law, new concepts have emerged that were not previously noticed as the concept of the rights of future generations, As this concept is closely related to the protection of the environment and reality in the field of environmental law, the idea of ​​the rights of future generations has been explicitly defined, especially in international law that is formed with the idea of ​​a common heritage of humanity that must be preserved

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Publication Date
Tue Jun 30 2020
Journal Name
Journal Of Economics And Administrative Sciences
The role of green strategy formulation in green behavior for municipal corporations – Analytical study

The research shows the importance of orientation towards the formulation of the green strategy and its effect in determining the behavior of the green municipal institution in Babel governorate. The research highlighted the formulation of the green strategy as an important variable, especially today, the trend towards protecting the environment and minimizing the damage resulting from the delivery of services, and through it also the type of green behavior or performance adopted by the municipal institution and the emergence of the need for a strategy that is not harmful to the environment. The research took the sample intentionally comprehensive size of 222 personnel of municipal institutions and some formations concerned with t

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Publication Date
Fri Dec 01 2023
Journal Name
Iraqi Journal Of Physics
Assessment of Sustainable Urban Expansion with Land Use and Land Cover Changes for Al-Hillah City Using Remote Sensing and GIS Techniques

In the current study, remote sensing techniques and geographic information systems were used to detect changes in land use / land cover (LULC) in the city of Al Hillah, central Iraq for the period from 1990 - 2022. Landsat 5 TM and Landsat 8 OLI visualizations, correction and georeferencing of satellite visuals were used. And then make the necessary classifications to show the changes in LULC in the city of Al Hillah. Through the study, the results showed that there is a clear expansion in the urban area from 20.5 km2 in 1990 to about 57 km2 in 2022. On the other hand, the results showed that there is a slight increase in agricultural areas and water. While the arid (empty) area decreased from 168.7 km 2 to 122 km 2 in 2022. Long-term ur

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Publication Date
Wed Sep 21 2022
Journal Name
Journal Of Thermoplastic Composite Materials
Enhancement of thermal characteristics of flexible poly(vinyl chloride) for automotive applications by using environmentally friendly heavy metal-free modifier

This work intends to develop an effective heavy metal-free modifier having properties comparable to traditional stabilizers and flame retardants, simultaneously being environmentally friendly and may be superior in many aspects. The important requirement focused on is: how to increase thermal stability and flame retardancy of flexible poly(vinyl chloride). Due to the typical materials now used with poly(vinyl chloride), which increases health and environmental concerns, utilizing a novel heavy metal-free additive will make poly(vinyl chloride) substantially safer. We have used an artificial silicate for this aim, which proved to be an efficient flame retardant and surprisingly showed excellent heat stabilizing effect. Thermal stabi

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Publication Date
Wed May 01 2019
Journal Name
Iraqi Journal Of Science
Investigation of nanostructured and gas sensing of tin dioxide films prepared by oxidation of Sn

Publication Date
Wed Dec 01 2021
Journal Name
مجلة الدراسات التربويو والعلمية
Effective reading skills in chemistry for middle school students

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Publication Date
Sat Dec 03 2022
Journal Name
Al-kut University College Of Humanities
Deep understanding skills in chemistry among middle school students

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