Preferred Language
Articles
/
2BboAIsBVTCNdQwCaMb0
New Polymeric Coii, Niii And Cdii Complexes With Tetrazole Schiff-Base Ligands; Synthesis, Spectral Characterisation And Biological Activity
...Show More Authors

New Schiff-base ligands bearing tetrazole moiety and their polymeric metal complexes with Co(II), Ni(II) and Cd(II) ions are reported. Ligands were prepared in a multiple-step reaction. The reaction of sodium 2,6- diformylphenolate and cyclohexane-1,3-dione with 5-amino-2-fluorobenzonitrile resulted in the isolation of two precursors sodium 2,6-bis((E)-(3-cyano-4-fluorophenylimino)methyl)-4-methylphenolate 1 and 5,5'- (1E,1'E)-cyclohexane-1,3-diylidenebis- (azan-1-yl-1-ylidene)bis(2-fluorobenzonitrile) 2, respectively. The reaction of precursors with azide gave the required ligands; sodium 2,6-bis((E)-(4-fluoro-3-(1H-tetrazol-5- yl)phenylimino)methyl)-4-methylphenolate (NaL) and (N, N'E, N, N'E)-N, N'-(cyclohexane-1,3-diylidene)bis(4- fluoro-3-(1H-tetrazol-5-yl)aniline) (L1). The reaction of these ligands with the appropriate metal ions gave polymeric metal complexes of the formulae {[M2(L)]Cl}n and [M(L1)Cl2]n (where M = Co(II), Ni(II) and Cd(II)). A range of techniques were used to confirm the entity of ligands and their complexes. The formation of ligands and mode of complexation and geometrical structure of the title polymeric complexes were verified using FTIR, electronic spectra, NMR, ESMS, magnetic susceptibility, micro-elemental analysis, metal content, chloride content and conductance. The analytical and spectroscopic data indicated the formation of four-coordinate complexes, with a tetrahedral geometry for Co(II) and Cd(II), and square planer for Ni(II) in L- and L1 complexes. Biological evaluation of ligands and their polymeric complexes against gram-positive bacteria (G+), Bacillus stubtili, Staphylococcus aureus, and gram-negative bacteria (G-), Escherichia coli and Pseudomonas aeruginosa, showed ligands and their polymeric metal complexes have a good effect on the screened bacteria.

Publication Date
Fri Dec 01 2023
Journal Name
Ieee Antennas And Wireless Propagation Letters
Stabilized and Fast Method for Compressive-Sensing-Based Method of Moments
...Show More Authors

View Publication
Scopus (9)
Crossref (4)
Scopus Clarivate Crossref
Publication Date
Sun Oct 30 2022
Journal Name
Iraqi Journal Of Science
Optical and Structural Properties of Cobalt Nanoparticles Synthesized by Laser Ablation
...Show More Authors

    Pulsed laser ablation in liquid (PLAL) technique can produce high purity nanoparticles, it is a top-down physical method based on the principle of dividing metal ion bulk precursors into metal atoms, this method was used in this work to synthesis cobalt nanoparticals (CoPNs) with the use of Nd: YAG laser with two wavelengths (355 nm) and (532 nm) at energies (500 mJ) and (600 mJ) respectively, with number of pulses (1000,1100, 1200, 1300, and 1400) for each wavelength. The properties of the prepared nanoparticles were studied by UV-Vis, XRD, SEM with EDX, AFM, and FTIR analysis and then its antibacterial activity was studied by applying it on two types of bacteria with gram-positive (Staphylococcus aureus, Streptococc

... Show More
View Publication Preview PDF
Scopus (1)
Scopus Crossref
Publication Date
Sat Feb 01 2020
Journal Name
Iop Conference Series: Materials Science And Engineering
The Compact city and urban image of the traditional city center
...Show More Authors
Abstract<p>The traditional city suffers from the decline of the urban image due to urban development and homogeneity with the urban context of the city, and because of the lack of determinants governing the urban image, it is that the center of the city of traditional Kadhimiya suffers from a break in the urban image, Therefore, the research included how to build a distinctive urban image of the center of the traditional city of Kadhimiya and achieve the visual pleasure and comfort of the recipient and the urban image here means is an image not picture which are related to several aspects, including physical, social and psychological as well as the collective memory of individuals and their rela</p> ... Show More
View Publication
Scopus (4)
Scopus Clarivate Crossref
Publication Date
Wed Jan 01 2020
Journal Name
Journal Of Information Hiding And Multimedia Signal Processing
Enhancement of lsb audio steganography based on carrier and message characteristics
...Show More Authors

Data steganography is a technique used to hide data, secret message, within another data, cover carrier. It is considered as a part of information security. Audio steganography is a type of data steganography, where the secret message is hidden in audio carrier. This paper proposes an efficient audio steganography method that uses LSB technique. The proposed method enhances steganography performance by exploiting all carrier samples and balancing between hiding capacity and distortion ratio. It suggests an adaptive number of hiding bits for each audio sample depending on the secret message size, the cover carrier size, and the signal to noise ratio (SNR). Comparison results show that the proposed method outperforms state of the art methods

... Show More
Scopus (10)
Scopus
Publication Date
Thu Jul 01 2021
Journal Name
Iraqi Journal Of Science
Improvement of Chacha20 Algorithm based on Tent and Chebyshev Chaotic Maps
...Show More Authors

Chacha 20 is a stream cypher that is used as lightweight on many CPUs that ‎do not have dedicated AES instructions. As stated by Google, that is the reason why they use it on many ‎devices, such as mobile devices, for authentication in TLS protocol. This paper ‎proposes an improvement of chaha20 stream cypher algorithm based on tent and ‎Chebyshev functions (IChacha20). The main objectives of the proposed IChacha20 ‎algorithm are increasing security layer, designing a robust structure of the IChacha20 ‎to be enabled to resist various types of attacks, implementing the proposed ‎algorithm for encryption of colour images, and transiting it in a secure manner. The ‎ test results proved that the MSE, PSNR, UQI and NCC metrics

... Show More
View Publication Preview PDF
Scopus (5)
Crossref (1)
Scopus Crossref
Publication Date
Mon Aug 01 2022
Journal Name
Baghdad Science Journal
Subgroups and Orbits by Companion Matrix in Three Dimensional Projective Space
...Show More Authors

The aim of this paper is to construct cyclic subgroups of the projective general linear group over  from the companion matrix, and then form caps of various degrees in . Geometric properties of these caps as secant distributions and index distributions are given and determined if they are complete. Also, partitioned of  into disjoint lines is discussed.

View Publication Preview PDF
Scopus (8)
Crossref (3)
Scopus Clarivate Crossref
Publication Date
Sat Oct 30 2021
Journal Name
Iraqi Journal Of Science
Forest Change Detection in Mosul Province using RS and GIS Techniques
...Show More Authors

    There are many events that took place in Al Mosul province between 2013 and 2018. These events led to many changes in the area under study. These changes involved a decrease in agricultural crops and water due to the population leaving the area. Therefore, it is imperative that planners, decision-makers, and development officials intervene in order to restore the region's activity in terms of environment and agriculture. The aim of this research is to use remote sensing (RS) technique and geographic information system (GIS) to detect the change that occurred in the mentioned period. This was achieved through the use of the ArcGIS software package for the purpose of assessing the state of lands of agricultural crops and

... Show More
View Publication Preview PDF
Scopus (6)
Crossref (1)
Scopus Crossref
Publication Date
Sun Feb 27 2022
Journal Name
Iraqi Journal Of Science
Digital Speech Files Encryption based on Hénon and Gingerbread Chaotic Maps
...Show More Authors

Speech encryption approaches are used to prevent eavesdropping, tracking, and other security concerns in speech communication. In this paper, a new cryptography algorithm is proposed to encrypt digital speech files. Initially, the digital speech files are rearranged as a cubic model with six sides to scatter speech data. Furthermore, each side is encrypted by random keys that are created by using two chaotic maps (Hénon and Gingerbread chaotic maps). Encryption for each side of the cube is achieved, using the based map vector that is generated randomly by using a simple random function. Map vector that consists of six bits, each bit refers to one of the specific chaotic maps that generate a random key to encrypt each face of the cube. R

... Show More
View Publication Preview PDF
Scopus (12)
Crossref (6)
Scopus Crossref
Publication Date
Sun May 26 2019
Journal Name
Iraqi Journal Of Science
Microfacies Architecture and Stratigraphic Development of the Yamama Formation, Southern Iraq
...Show More Authors

The Yamama Formation belongs to the late Berriasian-Aptian succession, which was deposited during the Lower Cretaceous period within the main shallow marine depositional environment.

Petrographic study and microfacies analysis enabled the recognition of six main microfacies for three association facies. These are the Semi-restricted, Shallow open marine and Shoal environments. The study succession represents deposition of three third order cycles, these cycles where deposited during successive episodes of relative sea level rises and still stand.

The presence of shoal association facies (oolitic packstone microfaces) between the Sulaiy and Yamama formations refer to continue the deposition during the same stage, and may s

... Show More
View Publication Preview PDF
Scopus (7)
Crossref (2)
Scopus Crossref
Publication Date
Wed Nov 30 2022
Journal Name
Iraqi Journal Of Science
Breast Cancer Detection using Decision Tree and K-Nearest Neighbour Classifiers
...Show More Authors

      Data mining has the most important role in healthcare for discovering hidden relationships in big datasets, especially in breast cancer diagnostics, which is the most popular cause of death in the world. In this paper two algorithms are applied that are decision tree and K-Nearest Neighbour for diagnosing Breast Cancer Grad in order to reduce its risk on patients. In decision tree with feature selection, the Gini index gives an accuracy of %87.83, while with entropy, the feature selection gives an accuracy of %86.77. In both cases, Age appeared as the  most effective parameter, particularly when Age<49.5. Whereas  Ki67  appeared as a second effective parameter. Furthermore, K- Nearest Neighbor is based on the minimum err

... Show More
View Publication Preview PDF
Scopus (9)
Crossref (6)
Scopus Crossref