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A new Schiff base ligand Bis-1,4-di[N-3-(2-hydroxy-1-amino)- acetophenonylidene]
benzylidene [L] and its complexes with (Mn(II)
,Co(II)
,Ni(II and Cu(II)) were synthesized .
The ligand was prepared in two steps. In the first step a solution of (terphthalaldehyde) in
methanol reacts under reflux with (p-aminoacetophenone) to give an intermediate
compound [1-[3-({4-[(3-Acetyl-phenylimino)-methyl]-benzylidene}-amino)-phenyl]-
ethanone which reacts in the second step with (2-Amino-phenol) giving the mentioned
ligand. The complexes were synthesized by addition the corresponding metal salt
solution to the solution of the ligand in methanol under reflux in (1:1) metal to ligand
ratio. On the basis of, molar conductance, I.R., UV-Vis, HPLC, chlorid
...
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