...Show More Authors
A new Macrocyclic Schiff base ligand Bis[4-hydroxy(1,2-ethylene-dioxidebenzylidene)
pheylenediamine] [H2L] and its complexes with (Co(II) , Ni(II) , Cu(II) , Zn(II) and Cd(II)) are reported .
The ligand was prepared in two steps,in the first step a solution of (o-phenylene diamine) in methanol
react under reflux with (2,4-dihydroxybenzylaldeyed) to give an (intermediatecompound) [Bis-1,2
(2,4-dihydroxybenzylediene)pheylinediamine] which react in the second step with (1,2- dichloro
ethane) giving the mentioned ligand.Then the complexes were synthesis of adding of corresponding
metal salts to the solution of the ligand in methanol under reflux with 1:1 metal to ligand ratio. On the
basis of, molar conductance, I.R., UV-Vis, chloride content a
...
Show More