Spectroscopic characterization for new model from Schiff base and its complexes

Vian Yamin Jirjees; Noor Mohamed Wannas; Farqad A. R; Adnan Dib; Wail Al Zoubi

doi:10.1002/poc.4169

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Publication Date

Fri Nov 20 2020

Journal Name

Journal Of Physical Organic Chemistry

Volume

34

DOI

10.1002/poc.4169

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Spectroscopic characterization for new model from Schiff base and its complexes

Vian Yamin Jirjees

Abbas Ali Salih Al–Hamdani

Noor Mohamed Wannas

Farqad A. R

Adnan Dib

Wail Al Zoubi

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AbstractNew complexes have been prepared from the new ligand [2,2′‐(5,5‐dimethylcyclohexane‐1,3‐diylidene)bis(azan‐1‐yl‐1‐ylidene)dibenzoic acid] derived from 5,5‐dimethylcyclohexane‐1,3‐dione and 2‐aminobenzoic acid. Accordingly, its mono and binuclear Mn(II), Co(II), Cu(II), Zn(II), and Cd(II) complexes were prepared. The prepared components have been characterized by various spectroscopic techniques and elemental analysis. The thermal stability of the ligand and its complexes were performed by TGA. It was found that all the complexes have excellent thermal stability and do not contain water molecules within their structure, but the ligand has little stability. Additionally, theoretical chemical calculation was performed of both electronic structure and spectroscopic properties of prepared Schiff base and its complexes. Moreover, the consequences predicted that the structure will be played a critical role in biological, liquid–liquid extraction, active transport applications.

Publication Date

Thu Apr 06 2023

Journal Name

Materials Science Forum

Study of the Effect of Ce 3+ on the Gas Sensitivity and Magnetic Properties of CuxCe0.3-XNi0.7Fe2O4 Ferrite Nanoparticles

Tagreed M.

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This study includes the preparation of the ferrite nanoparticles Cu_xCe_0.3-XNi_0.7Fe₂O₄ (where: x = 0, 0.05, 0.1, 0.15, 0.2, 0.25, 0.3) using the sol-gel (auto combustion) method, and citric acid was used as a fuel for combustion. The results of the tests conducted by X-ray diffraction (XRD), emitting-field scanning electron microscopy (FE-SEM), energy-dispersive X-ray analyzer (EDX), and Vibration Sample Magnetic Device (VSM) showed that the compound has a face-centered cubic structure, and the lattice constant is increased with increasing Cu ion. On the other hand, the compound has apparent porosity and spherical particles, and t

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