The largest use of x-ray in medical by dentists, employers or persons that needed by patients with specific conditions, lead to higher exposure of x-ray that may cause many diseases. In the present work radiography films have been used in evaluating the efficiency of using unsaturated polyester polymer reinforced with lead oxide (PbO) as shield material for medical x-ray devices, many parameters studied like concentration and thickness that they are increasing the attenuation of x-ray in them. The results show that the attenuation of X-ray increasing with concentration of reinforced material and with thickness, and the optical density decreases with increasing concentration from 0% to 50%, we chose 30% as suitable concentration to increase thickness from 1-6 cm that shows 3cm is suitable to manufacture shield for medical devices, that we have concluded that these materials very effective in attenuated x-ray, which can fabricate in any shape we needed in multi-situations and for this purpose radiography film method was used to appear these effects and suitable more than electric equipment that cannot use in these measurements.