An application of neural network technique was introduced in modeling extraction efficiency in RDC column, based on a data bank of around 352 data points collected in the open literature. Three models were made, using back-propagation algorithm, the extraction efficiency was found to be a function of seven dimensionless groups: Weber number (we), (Vd Vc), (c d), (Ds Dt), (Dr Dt), (Zc Dt) and(Zt Zc). Statistical analysis showed that the proposed models have an average absolute error (AARE) and standard deviation (SD) of 12.23% and 10.61% for the first model, 5.35% and 6.21% for the second model, 8.34% and 7.59% for the third model. The developed correlations also show better prediction over a wide range of operating conditions, physical properties and column geometry.